Applications & Pathways
Study of the Permeation Flowrate of an Innovative Way to Store Hydrogen in Vehicles
Oct 2021
Publication
With the global warming of the planet new forms of energy are being sought as an alternative to fossil fuels. Currently hydrogen (H2) is seen as a strong alternative for fueling vehicles. However the major challenge in the use of H2 arises from its physical properties. An earlier study was conducted on the storage of H2 used as fuel in road vehicles powered by spark ignition engines or stacks of fuel cells stored under high pressure inside small spheres randomly packed in an envelope tank. Additionally the study evaluated the performance of this new storage system and compared it with other storage systems already applied by automakers in their vehicles. The current study aims to evaluate the H2 leaks from the same storage system when inserted in any road vehicle parked in conventional garages and to show the compliance of these leaks with European Standards provided that an appropriate choice of materials is made. The system’s compliance with safety standards was proved. Regarding the materials of each component of the storage system the best option from the pool of materials chosen consists of aluminum for the liner of the spheres and the envelope tank CFEP for the structural layer of the spheres and Si for the microchip.
Varying Load Distribution Impacts on the Operation of a Hydrogen Generator Plant
Oct 2021
Publication
This study advances several methods to evaluate the operation of a hydrogen generator plant. The model developed helps customize plants that contain multiple generators of varying powers using a decision module which determines the most efficient plant load distribution. Evaluation indices to assess individual devices within the plant are proposed and system flexibility maximizes the amount of renewable energy stored. Three case studies examined the variable load distribution of an electrolysis system connected to a 40 MW wind farm for energy storage purposes and incorporated a “night-valley” operational strategy. These methods facilitate the selection of the proper plant configuration and provide estimates for individual device effectiveness within the system.
Combustion Characteristics of Diesel-hydrogen Dual Fuel Engine at Low Load
May 2013
Publication
In the present study hydrogen utilization as diesel engine fuel at low load operation was investigated. Hydrogen cannot be used directly in a diesel engine due to its auto ignition temperature higher than that of diesel fuel. One alternative method is to use hydrogen in enrichment or induction. To investigate the combustion characteristics of this dual fuel engine a single cylinder diesel research engine was converted to utilize hydrogen as fuel. Hydrogen was introduced to the intake manifold using a mixer before entering the combustion chamber. The engine was run at a constant speed of 2000 rpm and 10 Nm load. Hydrogen was introduced at the flow rate of 21.4 36.2 and 49.6 liter/minute. Specific energy consumption indicated efficiency and cylinder pressure were investigated. At this low load the hydrogen enrichment reduced the cylinder peak pressure and the engine efficiency. The reaction progress variable and combustion rate of reaction were slower as shown by the CFD calculation.
Hydrogen as an Energy Vector to Optimize the Energy Exploitation of a Self-consumption Solar Photovoltaic Facility in a Dwelling House
Nov 2019
Publication
Solar photovoltaic (PV) plants coupled with storage for domestic self-consumption purposes seem to be a promising technology in the next years as PV costs have decreased significantly and national regulations in many countries promote their installation in order to relax the energy requirements of power distribution grids. However electrochemical storage systems are still unaffordable for many domestic users and thus the advantages of self-consumption PV systems are reduced. Thus in this work the adoption of hydrogen systems as energy vectors between a PV plant and the energy user is proposed. As a preliminary study in this work the design of a PV and hydrogen-production self-consumption plant for a single dwelling is described. Then a technical and economic feasibility study conducted by modeling the facility within the Homer Energy Pro energy systems analysis tool is reported. The proposed system will be able to provide back not only electrical energy but also thermal energy through a fuel cell or refined water covering the fundamental needs of the householders (electricity heat or cooling and water). Results show that although the proposed system effectively increases the energy local use of the PV production and reduces significantly the energy injections or demands into/from the power grid avoiding power grid congestions and increasing the nano-grid resilience operation and maintenance costs may reduce its economic attractiveness for a single dwelling.
The Implications of Ambitious Decarbonisation of Heat and Road Transport for Britain’s Net Zero Carbon Energy Systems
Oct 2021
Publication
Decarbonisation of heating and road transport are regarded as necessary but very challenging steps on the pathway to net zero carbon emissions. Assessing the most efficient routes to decarbonise these sectors requires an integrated view of energy and road transport systems. Here we describe how a national gas and electricity transmission network model was extended to represent multiple local energy systems and coupled with a national energy demand and road transport model. The integrated models were applied to assess a range of technologies and policies for heating and transport where the UK’s 2050 net zero carbon emissions target is met. Overall annual primary energy use is projected to reduce by between 25% and 50% by 2050 compared to 2015 due to ambitious efficiency improvements within homes and vehicles. However both annual and peak electricity demands in 2050 are more than double compared with 2015. Managed electric vehicle charging could save 14TWh/year in gas-fired power generation at peak times and associated emissions whilst vehicle-to-grid services could provide 10GW of electricity supply during peak hours. Together managed vehicle charging and vehicle-to-grid supplies could result in a 16% reduction in total annual energy costs. The provision of fast public charging facilities could reduce peak electricity demand by 17GW and save an estimated £650 million annually. Although using hydrogen for heating and transport spreads the hydrogen network costs between homeowners and motorists it is still estimated to be more costly overall compared to an all-electric scenario. Bio-energy electricity generation plants with carbon capture and storage are required to drive overall energy system emissions to net zero utilisation of which is lowest when heating is electrified and road transport consists of a mix of electric and hydrogen fuel-cell vehicles. The analysis demonstrates the need for an integrated systems approach to energy and transport policies and for coordination between national and local governments.
A Review of Hydrogen Direct Injection for Internal Combustion Engines: Towards Carbon-Free Combustion
Nov 2018
Publication
A paradigm shift towards the utilization of carbon-neutral and low emission fuels is necessary in the internal combustion engine industry to fulfil the carbon emission goals and future legislation requirements in many countries. Hydrogen as an energy carrier and main fuel is a promising option due to its carbon-free content wide flammability limits and fast flame speeds. For spark-ignited internal combustion engines utilizing hydrogen direct injection has been proven to achieve high engine power output and efficiency with low emissions. This review provides an overview of the current development and understanding of hydrogen use in internal combustion engines that are usually spark ignited under various engine operation modes and strategies. This paper then proceeds to outline the gaps in current knowledge along with better potential strategies and technologies that could be adopted for hydrogen direct injection in the context of compression-ignition engine applications—topics that have not yet been extensively explored to date with hydrogen but have shown advantages with compressed natural gas.
Experimental Investigation of the Effect of Hydrogen Addition on Combustion Performance and Emissions Characteristics of a Spark Ignition High Speed Gasoline Engine
Sep 2014
Publication
Considering energy crises and pollution problems today much work has been done for alternative fuels for fossil fuels and lowering the toxic components in the combustion products. Expert studies proved that hydrogen one of the prominent alternative energy source which has many excellent combustion properties that can be used for improving combustion and emissions performance of gasoline-fuelled spark ignition (SI) engines. This article experimentally investigated the performance and emission characteristics of a high speed single cylinder SI engine operating with different hydrogen gasoline blends. For this purpose the conventional carburetted high speed SI engine was modified into an electronically controllable engine with help of electronic control unit (ECU) which dedicatedly used to control the injection timings and injection durations of gasoline. Various hydrogen enrichment levels were selected to investigate the effect of hydrogen addition on engine brake mean effective pressure (Bmep) brake thermal efficiency volumetric efficiency and emission characteristics. The test results demonstrated that combustion performances fuel consumption and brake mean effective pressure were eased with hydrogen enrichment. The experimental results also showed that the brake thermal efficiency was higher than that for the pure gasoline operation. Moreover HC and CO emissions were all reduced after hydrogen enrichment.
Assessment of the Economic Efficiency of the Operation of Low-Emission and Zero-Emission Vehicles in Public Transport in the Countries of the Visegrad Group
Nov 2021
Publication
Transport is one of the key sectors of the European economy. However the intensive development of transport caused negative effects in the form of an increase in the emission of harmful substances. The particularly dramatic situation took place in the V4 countries. This made it necessary to implement solutions reducing emissions in transport including passenger transport. Such activities can be implemented in the field of implementation of low-emission and zero-emission vehicles for use. That is why the European Union and the governments of the Visegrad Group countries have developed numerous recommendations communications laws and strategies that order carriers to implement low- and zero-emission mobility. Therefore transport organizers and communication operators faced the choice of the type of buses. From an economic point of view each entrepreneur is guided by the economic efficiency of the vehicles used. Hence the main aim of the article was to conduct an economic evaluation of the operational efficiency of ecological vehicles. As more than 70% of vehicles in use in the European Union are still diesel driven the economic efficiency assessment was also made for vehicles with traditional diesel drive. To conduct the research the method of calculating the total cost of ownership of vehicles in operation was used. As a result of the research it was found that electric buses are the cheapest in the entire period of use (15 years) and then those powered by CNG. On the other hand the cost of using hydrogen buses is the highest. This is due to the high purchase prices of these vehicles. However the EU as well as the governments of individual countries support enterprises and communication operators by offering them financing for investments. The impact of the forecasted fuel and energy prices and the planned inflation on operating costs was also examined. In this case the analyses showed that the forecasted changes in fuel and energy prices as well as the expected inflation will significantly affect the costs of vehicle operation and the economic efficiency of using various types of drives. These changes will have a positive impact on the implementation of zero-emission vehicles into exploitation. Based on the analyses it was found that in 2035 hydrogen buses will have the lowest operating costs.
Preliminary Design of a Self-Sufficient Electrical Storage System Based on Electrolytic Hydrogen for Power Supply in a Residential Application
Oct 2021
Publication
The use of renewable energy and hydrogen technology is a sustainable solution for the intermittent feature of renewable energies. Hence the aim of the present work is to design a self-sufficient system for a one-family house by coupling a solar photovoltaic array and an anion exchange membrane water electrolyzer (AEMWE). The first step is the selection of the photovoltaic panel by using PV-SYST 7.0 software. Then the hydrogen production system is calculated by coupling the electrolyzer and photovoltaic panel current–potential curves. A fuel cell is selected to use the hydrogen produced when solar energy is not available. Finally the hydrogen storage tank is also estimated to store hydrogen for a design basis of four consecutive cloudy days according to the hydrogen consumption of the fuel cell. The whole system is designed by a simple procedure for a specific location in Ciudad Real (Spain) for January which is known as the coldest month of the year. The simple procedure described in this work could be used elsewhere and demonstrated that the hydrogen production at low scale is a suitable technology to use renewable energy for self-energy supporting in a residential application without any connection to the grid.
Integration Design and Operation Strategy of Multi-Energy Hybrid System Including Renewable Energies, Batteries and Hydrogen
Oct 2020
Publication
In some areas the problem of wind and solar power curtailment is prominent. Hydrogen energy has the advantage of high storage density and a long storage time. Multi-energy hybrid systems including renewable energies batteries and hydrogen are designed to solve this problem. In order to reduce the power loss of the converter an AC-DC hybrid bus is proposed. A multi-energy experiment platform is established including a wind turbine photovoltaic panels a battery an electrolyzer a hydrogen storage tank a fuel cell and a load. The working characteristics of each subsystem are tested and analyzed. The multi-energy operation strategy is based on state monitoring and designed to enhance hydrogen utilization energy efficiency and reliability of the system. The hydrogen production is guaranteed preferentially and the load is reliably supplied. The system states are monitored such as the state of charge (SOC) and the hydrogen storage level. The rated and ramp powers of the battery and fuel cell and the pressure limit of the hydrogen storage tank are set as safety constraints. Eight different operation scenarios comprehensively evaluate the system’s performance and via physical experiments the proposed operation strategy of the multi-energy system is verified as effective and stable.
The Role of Renewable Hydrogen and Inter-seasonal Storage in Decarbonising Heat – Comprehensive Optimisation of Future Renewable Energy Value Chains
Nov 2018
Publication
Demands for space and water heating constitute a significant proportion of the total energy demands in Great Britain and are predominantly satisfied through natural gas which makes the heat sector a large emitter of carbon dioxide. Renewable hydrogen which can be injected into the gas grid or used directly in processes for generating heat and/or electricity is being considered as a low-carbon alternative energy carrier to natural gas because of its suitability for large-scale long- and short-term storage and low transportation losses all of which help to overcome the intermittency and seasonal variations in renewables. This requires new infrastructures for production storage transport and utilisation of renewable hydrogen – a hydrogen value chain – the design of which involves many interdependent decisions such as: where to locate wind turbines; where to locate electrolysers close to wind generation or close to demands; whether to transport energy as electricity or hydrogen and how; where to locate storage facilities; etc. This paper presents the Value Web Model a novel and comprehensive spatio-temporal mixed-integer linear programming model that can simultaneously optimise the design planning and operation of integrated energy value chains accounting for short-term dynamics inter-seasonal storage and investments out to 2050. It was coupled with GIS modelling to identify candidate sites for wind generation and used to optimise a number of scenarios for the production of hydrogen from onshore and offshore wind turbines in order to satisfy heat demands. The results show that over a wide range of scenarios the optimal pathway to heat is roughly 20% hydrogen and 80% electricity. Hydrogen storage both in underground caverns and pressurised tanks is a key enabling technology.
Optimization of Hydrogen Cost and Transport Technology in France and Germany for Various Production and Demand Scenarios
Jan 2021
Publication
Green hydrogen for mobility represents an alternative to conventional fuel to decarbonize the transportation sector. Nevertheless the thermodynamic properties make the transport and the storage of this energy carrier at standard conditions inefficient. Therefore this study deploys a georeferenced optimal transport infrastructure for four base case scenarios in France and Germany that differs by production distribution based on wind power potential and demand capacities for the mobility sector at different penetration shares for 2030 and 2050. The restrained transport network to the road infrastructure allows focusing on the optimum combination of trucks operating at different states of aggregations and storage technologies and its impact on the annual cost and hydrogen flow using linear programming. Furthermore four other scenarios with production cost investigate the impact of upstream supply chain cost and eight scenarios with daily transport and storage optimization analyse the modeling method sensitivity. The results show that compressed hydrogen gas at a high presser level around 500 bar was on average a better option. However at an early stage of hydrogen fuel penetration substituting compressed gas at low to medium pressure levels by liquid organic hydrogen carrier minimizes the transport and storage costs. Finally in France hydrogen production matches population distribution in contrast to Germany which suffers from supply and demand disparity.
Comprehensive Analysis of the Combustion of Low Carbon Fuels (Hydrogen, Methane and Coke Oven Gas) in a Spark Ignition Engine through CFD Modeling
Nov 2021
Publication
The use of low carbon fuels (LCFs) in internal combustion engines is a promising alternative to reduce pollution while achieving high performance through the conversion of the high energy content of the fuels into mechanical energy. However optimizing the engine design requires deep knowledge of the complex phenomena involved in combustion that depend on the operating conditions and the fuel employed. In this work computational fluid dynamics (CFD) simulation tools have been used to get insight into the performance of a Volkswagen Polo 1.4L port-fuel injection spark ignition engine that has been fueled with three different LCFs coke oven gas (COG) a gaseous by-product of coke manufacture H2 and CH4. The comparison is made in terms of power pressure temperature heat release flame growth speed emissions and volumetric efficiency. Simulations in Ansys® Forte® were validated with experiments at the same operating conditions with optimal spark advance wide open throttle a wide range of engine speed (2000–5000 rpm) and air-fuel ratio (λ) between 1 and 2. A sensitivity analysis of spark timing has been added to assess its impact on combustion variables. COG with intermediate flame growth speed produced the greatest power values but with lower pressure and temperature values at λ = 1.5 reducing the emissions of NO and the wall heat transfer. The useful energy released with COG was up to 16.5% and 5.1% higher than CH4 and H2 respectively. At richer and leaner mixtures (λ = 1 and λ = 2) similar performances were obtained compared to CH4 and H2 combining advantages of both pure fuels and widening the λ operation range without abnormal combustion. Therefore suitable management of the operating conditions maximizes the conversion of the waste stream fuel energy into useful energy while limiting emissions.
Challenges and Prospects of Renewable Hydrogen-based Strategies for Full Decarbonization of Stationary Power Applications
Oct 2021
Publication
The exponentially growing contribution of renewable energy sources in the electricity mix requires large systems for energy storage to tackle resources intermittency. In this context the technologies for hydrogen production offer a clean and versatile alternative to boost renewables penetration and energy security. Hydrogen production as a strategy for the decarbonization of the energy sources mix has been investigated since the beginning of the 1990s. The stationary sector i.e. all parts of the economy excluding the transportation sector accounts for almost three-quarters of greenhouse gases (GHG) emissions (mass of CO2-eq) in the world associated with power generation. While several publications focus on the hybridization of renewables with traditional energy storage systems or in different pathways of hydrogen use (mainly power-to-gas) this study provides an insightful analysis of the state of art and evolution of renewable hydrogen-based systems (RHS) to power the stationary sector. The analysis started with a thorough review of RHS deployments for power-to-power stationary applications such as in power generation industry residence commercial building and critical infrastructure. Then a detailed evaluation of relevant techno-economic parameters such as levelized cost of energy (LCOE) hydrogen roundtrip efficiency (HRE) loss of power supply probability (LPSP) self-sufficiency ratio (SSR) or renewable fraction (fRES) is provided. Subsequently lab-scale plants and pilot projects together with current market trends and commercial uptake of RHS and fuel cell systems are examined. Finally the future techno-economic barriers and challenges for short and medium-term deployment of RHS are identified and discussed.
Energy Management Strategies for a Zero-emission Hybrid Domestic Ferry
Oct 2021
Publication
The paper presents three approaches for the sizing and control of a maritime hybrid power-plant equipped with proton exchange membrane fuel cells and batteries. The study focuses on three different power-plant configurations including the energy management strategy and the power-plant component sizing. The components sizing is performed following the definition of the energy management strategy using the sequential optimization approach. These configurations are tested using a dynamic model developed in Simulink. The simulations are carried out to validate the technical feasibility of each configuration for maritime use. Each energy management strategy is developed to allow for the optimization of a chosen set of parameters such as hydrogen consumption and fuel cell degradation. It is observed that in the hybrid power-plant optimization there are always trade-offs and the optimization should be carried out by prioritizing primary factors the ship owner considers most important for day-to-day operations.
What Will Fuel Transport Systems of the Future?
Nov 2011
Publication
This paper seeks to decry the notion of a single solution or “silver bullet” to replace petroleum products with renewable transport fuel. At different times different technological developments have been in vogue as the panacea for future transport needs: for quite some time hydrogen has been perceived as a transport fuel that would be all encompassing when the technology was mature. Liquid biofuels have gone from exalted to unsustainable in the last ten years. The present flavor of the month is the electric vehicle. This paper examines renewable transport fuels through a review of the literature and attempts to place an analytical perspective on a number of technologies.
Well to Wheel Analysis of Low Carbon Alternatives for Road Traffic
Sep 2015
Publication
Several alternative fuel–vehicle combinations are being considered for replacement of the internal combustion engine (ICE) vehicles to reduce greenhouse gas (GHG) emissions and the dependence on fossil fuels. The International Energy Agency has proposed the inclusion of low carbon alternatives such as electricity hydrogen and biofuels in the transport sector for reducing the GHG emissions and providing a sustainable future. This paper compares the use of these alternative fuels viz. electricity hydrogen and bio-ethanol in combination with battery electric vehicle (BEV) and fuel cell electric vehicle (FCEV) technologies on the basis of their overall efficiency and GHG emissions involved in the conversion of the primary energy source to the actual energy required at wheels through a well-to-wheel analysis. The source of energy for electricity production plays a major role in determining the overall efficiency and the GHG emissions of a BEV. Hence electricity production mix of Germany (60% fossil fuel energy) France (76% nuclear energy) Sweden and Austria (60 and 76% renewable energy respectively) the European Union mix (48% fossil fuel energy) and the United States of America (68% fossil fuel energy) are considered for the BEV analysis. In addition to the standard hydrogen based FCEVs CNG and bio-ethanol based FCEVs are analysed. The influence of a direct ethanol fuel cell (DEFC) on GHG emissions and overall chain efficiency is discussed. In addition to the standard sources of bio-ethanol (like sugarcane corn etc.) sources like wood waste and wheat straw are included in the analysis. The results of this study suggest that a BEV powered by an electricity production mix dominated by renewable energy and bio-ethanol based DEFC electric vehicles offer the best solution in terms of GHG emissions efficiency and fossil fuel dependency. Bio-ethanol as a fuel has the additional advantage to be implemented readily in ICE vehicles followed by advancements through reformer based FCEVs and DEFC electric vehicles. Although important this analysis does not include the health effects of the alternative vehicles. Bio-ethanol used in an ICE may lead to increased emission of acetaldehydes which however might not be the case if it is used in fuel cells.
Hydrogen Fuel Cell Vehicles; Current Status and Future Prospect
Jun 2019
Publication
The hazardous effects of pollutants from conventional fuel vehicles have caused the scientific world to move towards environmentally friendly energy sources. Though we have various renewable energy sources the perfect one to use as an energy source for vehicles is hydrogen. Like electricity hydrogen is an energy carrier that has the ability to deliver incredible amounts of energy. Onboard hydrogen storage in vehicles is an important factor that should be considered when designing fuel cell vehicles. In this study a recent development in hydrogen fuel cell engines is reviewed to scrutinize the feasibility of using hydrogen as a major fuel in transportation systems. A fuel cell is an electrochemical device that can produce electricity by allowing chemical gases and oxidants as reactants. With anodes and electrolytes the fuel cell splits the cation and the anion in the reactant to produce electricity. Fuel cells use reactants which are not harmful to the environment and produce water as a product of the chemical reaction. As hydrogen is one of the most efficient energy carriers the fuel cell can produce direct current (DC) power to run the electric car. By integrating a hydrogen fuel cell with batteries and the control system with strategies one can produce a sustainable hybrid car
Comparison of Hydrogen Powertrains with the Battery Powered Electric Vehicle and Investigation of Small-Scale Local Hydrogen Production Using Renewable Energy
Jan 2021
Publication
Climate change is one of the major problems that people face in this century with fossil fuel combustion engines being huge contributors. Currently the battery powered electric vehicle is considered the predecessor while hydrogen vehicles only have an insignificant market share. To evaluate if this is justified different hydrogen power train technologies are analyzed and compared to the battery powered electric vehicle. Even though most research focuses on the hydrogen fuel cells it is shown that despite the lower efficiency the often-neglected hydrogen combustion engine could be the right solution for transitioning away from fossil fuels. This is mainly due to the lower costs and possibility of the use of existing manufacturing infrastructure. To achieve a similar level of refueling comfort as with the battery powered electric vehicle the economic and technological aspects of the local small-scale hydrogen production are being investigated. Due to the low efficiency and high prices for the required components this domestically produced hydrogen cannot compete with hydrogen produced from fossil fuels on a larger scale
H2 Green Hydrogen Discussion Paper: Victorian Hydrogen Investment Program
Nov 2019
Publication
This discussion paper is for stakeholders who would like to shape the development of Victoria’s emerging green hydrogen sector identifying competitive advantages and priority focus areas for industry and the Victorian Government.<br/>The Victorian Government is using this paper to focus on the economic growth and sector development opportunities emerging for a Victorian hydrogen industry powered by renewable energy also known as ‘green’ hydrogen. In addition this paper seeks input from all stakeholders on how where and when the Victorian Government can act to establish a thriving green hydrogen economy.<br/>Although green hydrogen is the only type of hydrogen production within the scope of this discussion paper the development of the VHIP aligns with the policies projects and initiatives which support these other forms of hydrogen production. The VHIP is considering the broad policy landscape and actively coordinating with related hydrogen programs policies and strategies under development including the Council of Australian Governments (COAG) Energy Council’s National Hydrogen Strategy to ensure a complementary approach. In Victoria there are several programs and strategies in development and underway that have linkages with hydrogen and the VHIP.
Emerging, Hydrogen-driven Electrochemical Water Purification
Jan 2022
Publication
Energy-efficient technologies for the remediation of water and generation of drinking water is a key towards sustainable technologies. Electrochemical desalination technologies are promising alternatives towards established methods such as reverse osmosis or ultrafiltration. In the last few years hydrogen-driven electrochemical water purification has emerged. This review article explores the concept of desalination fuel cells and capacitive-Faradaic fuel cells for ion separation.
Innovating Transport Across Australia: Inquiry into Automated Mass Transit
Mar 2019
Publication
Automated and electric mass transit will play a significant role in the connectivity of our cities and regions. But automated mass transit must be placed within the wider context of the optimum transport needs of those cities and regions— transport networks based on shared and multi-modal mobility. Realising the full potential of these networks will require sustained policy development and investment.<br/>This report examines current and future developments in the use of automation and new energy sources in land-based mass transit including rail and road mass transit point-to-point transport using automated vehicles and the role and responsibilities of the Commonwealth in the development of these technologies. It will analyse the opportunities and challenges presented by automation and new energy sources and the role the Australian Government has to play in managing this transport revolution.
Industrial Energy Use and Carbon Emissions Reduction in the Chemicals Sector: A UK Perspective
Aug 2017
Publication
The opportunities and challenges to reducing industrial energy demand and carbon dioxide (CO2 ) emissions in the Chemicals sector are evaluated with a focus on the situation in the United Kingdom (UK) although the lessons learned are applicable across much of the industrialised world. This sector can be characterised as being heterogeneous; embracing a diverse range of products (including advanced materials cleaning fluids composites dyes paints pharmaceuticals plastics and surfactants). It sits on the boundary between energy-intensive (EI) and non-energy-intensive (NEI) industrial sectors. The improvement potential of various technological interventions has been identified in terms of their energy use and greenhouse gas (GHG) emissions. Currently-available best practice technologies (BPTs) will lead to further short-term energy and CO2 emissions savings in chemicals processing but the prospects for the commercial exploitation of innovative technologies by mid-21st century are far more speculative. A set of industrial decarbonisation ‘technology roadmaps’ out to the mid-21st Century are also reported based on various alternative scenarios. These yield low-carbon transition pathways that represent future projections which match short-term and long-term (2050) targets with specific technological solutions to help meet the key energy saving and decarbonisation goals. The roadmaps’ contents were built up on the basis of the improvement potentials associated with various processes employed in the chemicals industry. They help identify the steps needed to be undertaken by developers policy makers and other stakeholders in order to ensure the decarbonisation of the UK chemicals industry. The attainment of significant falls in carbon emissions over this period will depends critically on the adoption of a small number of key technologies [e.g. carbon capture and storage (CCS) energy efficiency techniques and bioenergy] alongside a decarbonisation of the electricity supply.
An Integrated Hydrogen Fuel Cell to Distribution Network System: Challenging and Opportunity for D-STATCOM
Oct 2021
Publication
The electric power industry sector has become increasingly aware of how counterproductive voltage sag affects distribution network systems (DNS). The voltage sag backfires disastrously at the demand load side and affects equipment in DNS. To settle the voltage sag issue this paper achieved its primary purpose to mitigate the voltage sag based on integrating a hydrogen fuel cell (HFC) with the DNS using a distribution static synchronous compensator (D-STATCOM) system. Besides this paper discusses the challenges and opportunities of D-STATCOM in DNS. In this paper using HFC is well-designed modeled and simulated to mitigate the voltage sag in DNS with a positive impact on the environment and an immediate response to the issue of the injection of voltage. Furthermore this modeling and controller are particularly suitable in terms of cost-effectiveness as well as reliability based on the adaptive network fuzzy inference system (ANFIS) fuzzy logic system (FLC) and proportional–integral (P-I). The effectiveness of the MATLAB simulation is confirmed by implementing the system and carrying out a DNS connection obtaining efficiencies over 94.5% at three-phase fault for values of injection voltage in HFC D-STATCOM using a P-I controller. Moreover the HFC D-STATCOM using FLC proved capable of supporting the network by 97.00%. The HFC D-STATCOM based ANFIS proved capable of supporting the network by 98.00% in the DNS.
Decarbonization of Australia’s Energy System: Integrated Modelling of the Transformation of Electricity, Transportation, and Industrial Sectors
Jul 2020
Publication
To achieve the Paris Agreement’s long-term temperature goal current energy systems must be transformed. Australia represents an interesting case for energy system transformation modelling: with a power system dominated by fossil fuels and specifically with a heavy coal component there is at the same time a vast potential for expansion and use of renewables. We used the multi-sectoral Australian Energy Modelling System (AUSeMOSYS) to perform an integrated analysis of implications for the electricity transport and selected industry sectors to the mid-century. The state-level resolution allows representation of regional discrepancies in renewable supply and the quantification of inter-regional grid extensions necessary for the physical integration of variable renewables. We investigated the impacts of different CO2 budgets and selected key factors on energy system transformation. Results indicate that coal-fired generation has to be phased out completely by 2030 and a fully renewable electricity supply achieved in the 2030s according to the cost-optimal pathway implied by the 1.5 °C Paris Agreement-compatible carbon budget. Wind and solar PV can play a dominant role in decarbonizing Australia’s energy system with continuous growth of demand due to the strong electrification of linked energy sectors.
A Review of Synthetic Fuels for Passenger Vehicles
May 2019
Publication
Synthetic fuels produced with renewable surplus electricity depict an interesting solution for the decarbonization of mobility and transportation applications which are not suited for electrification. With the objective to compare various synthetic fuels an analysis of all the energy conversion steps is conducted from the electricity source i.e. wind- solar- or hydro-power to the final application i.e. a vehicle driving a certain number of miles. The investigated fuels are hydrogen methane methanol dimethyl ether and Diesel. While their production process is analyzed based on literature the usage of these fuels is analyzed based on chassis dynanometer measurement data of various EURO-6b passenger vehicles. Conventional and hybrid power-trains as well as various carbon dioxide sources are investigated in two scenarios. The first reference scenario considers market-ready technology only while the second future scenario considers technology which is currently being developed in industry and assumed to be market-ready in near future. With the results derived in this study and with consideration of boundary conditions i.e. availability of infrastructure storage technology of gaseous fuels energy density requirements etc. the most energy efficient of the corresponding suitable synthetic fuels can be chosen.
A General Vision for Reduction of Energy Consumption and CO2 Emissions from the Steel Industry
Aug 2020
Publication
The 2018 IPCC (The Intergovernmental Panel on Climate Change’s) report defined the goal to limit global warming to 1.5 ◦C by 2050. This will require “rapid and far-reaching transitions in land energy industry buildings transport and cities”. The challenge falls on all sectors especially energy production and industry. In this regard the recent progress and future challenges of greenhouse gas emissions and energy supply are first briefly introduced. Then the current situation of the steel industry is presented. Steel production is predicted to grow by 25–30% by 2050. The dominant iron-making route blast furnace (BF) especially is an energy-intensive process based on fossil fuel consumption; the steel sector is thus responsible for about 7% of all anthropogenic CO2 emissions. In order to take up the 2050 challenge emissions should see significant cuts. Correspondingly specific emissions (t CO2/t steel) should be radically decreased. Several large research programs in big steelmaking countries and the EU have been carried out over the last 10–15 years or are ongoing. All plausible measures to decrease CO2 emissions were explored here based on the published literature. The essential results are discussed and concluded. The specific emissions of “world steel” are currently at 1.8 t CO2/t steel. Improved energy efficiency by modernizing plants and adopting best available technologies in all process stages could decrease the emissions by 15–20%. Further reductions towards 1.0 t CO2/t steel level are achievable via novel technologies like top gas recycling in BF oxygen BF and maximal replacement of coke by biomass. These processes are however waiting for substantive industrialization. Generally substituting hydrogen for carbon in reductants and fuels like natural gas and coke gas can decrease CO2 emissions remarkably. The same holds for direct reduction processes (DR) which have spread recently exceeding 100 Mt annual capacity. More radical cut is possible via CO2 capture and storage (CCS). The technology is well-known in the oil industry; and potential applications in other sectors including the steel industry are being explored. While this might be a real solution in propitious circumstances it is hardly universally applicable in the long run. More auspicious is the concept that aims at utilizing captured carbon in the production of chemicals food or fuels e.g. methanol (CCU CCUS). The basic idea is smart but in the early phase of its application the high energy-consumption and costs are disincentives. The potential of hydrogen as a fuel and reductant is well-known but it has a supporting role in iron metallurgy. In the current fight against climate warming H2 has come into the “limelight” as a reductant fuel and energy storage. The hydrogen economy concept contains both production storage distribution and uses. In ironmaking several research programs have been launched for hydrogen production and reduction of iron oxides. Another global trend is the transfer from fossil fuel to electricity. “Green” electricity generation and hydrogen will be firmly linked together. The electrification of steel production is emphasized upon in this paper as the recycled scrap is estimated to grow from the 30% level to 50% by 2050. Finally in this review all means to reduce specific CO2 emissions have been summarized. By thorough modernization of production facilities and energy systems and by adopting new pioneering methods “world steel” could reach the level of 0.4–0.5 t CO2/t steel and thus reduce two-thirds of current annual emissions.
An Overview of the Classification, Production and Utilization of Biofuels for Internal Combustion Engine Applications
Sep 2021
Publication
Biofuel a cost-effective safe and environmentally benign fuel produced from renewable sources has been accepted as a sustainable replacement and a panacea for the damaging effects of the exploration for and consumption of fossil-based fuels. The current work examines the classification generation and utilization of biofuels particularly in internal combustion engine (ICE) applications. Biofuels are classified according to their physical state technology maturity the generation of feedstock and the generation of products. The methods of production and the advantages of the application of biogas bioalcohol and hydrogen in spark ignition engines as well as biodiesel Fischer– Tropsch fuel and dimethyl ether in compression ignition engines in terms of engine performance and emission are highlighted. The generation of biofuels from waste helps in waste minimization proper waste disposal and sanitation. The utilization of biofuels in ICEs improves engine performance and mitigates the emission of poisonous gases. There is a need for appropriate policy frameworks to promote commercial production and seamless deployment of these biofuels for transportation applications with a view to guaranteeing energy security.
Fuel Cell Cars in a Microgrid for Synergies Between Hydrogen and Electricity Networks
Nov 2016
Publication
Fuel cell electric vehicles convert chemical energy of hydrogen into electricity to power their motor. Since cars are used for transport only during a small part of the time energy stored in the on-board hydrogen tanks of fuel cell vehicles can be used to provide power when cars are parked. In this paper we present a community microgrid with photovoltaic systems wind turbines and fuel cell electric vehicles that are used to provide vehicle-to-grid power when renewable power generation is scarce. Excess renewable power generation is used to produce hydrogen which is stored in a refilling station. A central control system is designed to operate the system in such a way that the operational costs are minimized. To this end a hybrid model for the system is derived in which both the characteristics of the fuel cell vehicles and their traveling schedules are considered. The operational costs of the system are formulated considering the presence of uncertainty in the prediction of the load and renewable energy generation. A robust minmax model predictive control scheme is developed and finally a case study illustrates the performance of the designed system.
Design Challenges in Hydrogen-Fueled Rotary Engine-A Review
Jan 2023
Publication
The rotary engine (RE) is a potential power plant for unmanned aerial vehicles (UAVs) and automobiles because of its structural and design merits. However it has some serious drawbacks such as frequent maintenance requirements and excessive fuel consumption. This review paper presents the current status of hydrogen-fueled rotary engine (HRE) technology and identifies the existing research and development gaps in combustion efficiency and performance of this engine that might benefit transportation sector. Focusing primarily on the research from past ten years the crucial challenges encountered in hydrogen-powered rotary engines have been reviewed in terms of knock hydrocarbon (HC) emissions and seal leakages. The paper identifies the recent advances in design concepts and production approaches used in hydrogen-fueled rotary engines such as geometric models of trochoid profiles port configurations fuel utilization systems and currently available computational fluid dynamics (CFD) tools. This review article is an attempt to collect and organize literature on existing design methods up to date and provide recommendations for further improvements in RE technology.
Hydrogen for Australia’s Future
Aug 2018
Publication
The Hydrogen Strategy Group chaired by Australia’s Chief Scientist Dr Alan Finkel has today released a briefing paper on the potential domestic and export opportunities of a hydrogen industry in Australia.
Like natural gas hydrogen can be used to heat buildings and power vehicles. Unlike natural gas or petrol when hydrogen is burned there are no CO2 emissions. The only by-products are water vapour and heat.
Hydrogen is the most abundant element in the universe not freely available as a gas on Earth but bound into many common substances including water and fossil fuels.
Hydrogen was first formally presented as a credible alternative energy source in the early 1970s but never proved competitive at scale as an energy source – until now. We find that the worldwide demand for hydrogen is set to increase substantially over coming decades driven by Japan’s decision to put imported hydrogen at the heart of its economy. Production costs are falling technologies are progressing and the push for non-nuclear low-emissions fuels is building momentum. We conclude that Australia is remarkably well-positioned to benefit from the growth of hydrogen industries and markets.
Like natural gas hydrogen can be used to heat buildings and power vehicles. Unlike natural gas or petrol when hydrogen is burned there are no CO2 emissions. The only by-products are water vapour and heat.
Hydrogen is the most abundant element in the universe not freely available as a gas on Earth but bound into many common substances including water and fossil fuels.
Hydrogen was first formally presented as a credible alternative energy source in the early 1970s but never proved competitive at scale as an energy source – until now. We find that the worldwide demand for hydrogen is set to increase substantially over coming decades driven by Japan’s decision to put imported hydrogen at the heart of its economy. Production costs are falling technologies are progressing and the push for non-nuclear low-emissions fuels is building momentum. We conclude that Australia is remarkably well-positioned to benefit from the growth of hydrogen industries and markets.
Healthy Power: Reimagining Hospitals as Sustainable Energy Hubs
Oct 2020
Publication
Human health is a key pillar of modern conceptions of sustainability. Humanity pays a considerable price for its dependence on fossil-fueled energy systems which must be addressed for sustainable urban development. Public hospitals are focal points for communities and have an opportunity to lead the transition to renewable energy. We have reimagined the healthcare energy ecosystem with sustainable technologies to transform hospitals into networked clean energy hubs. In this concept design hydrogen is used to couple energy with other on-site medical resource demands and vanadium flow battery technology is used to engage the public with energy systems. This multi-generation system would reduce harmful emissions while providing reliable services tackling the linked issues of human and environmental health.
Life Cycle Assessment Integration into Energy System Models: An Application for Power-to-Methane in the EU
Nov 2019
Publication
As the EU energy system transitions to low carbon the technology choices should consider a broader set of criteria. The use of Life Cycle Assessment (LCA) prevents burden shift across life cycle stages or impact categories while the use of Energy System Models (ESM) allows evaluating alternative policies capacity evolution and covering all the sectors. This study does an ex-post LCA analysis of results from JRC-EU-TIMES and estimates the environmental impact indicators across 18 categories in scenarios that achieve 80–95% CO2 emission reduction by 2050. Results indicate that indirect CO2 emissions can be as large as direct ones for an 80% CO2 reduction target and up to three times as large for 95% CO2 reduction. Impact across most categories decreases by 20–40% as the CO2 emission target becomes stricter. However toxicity related impacts can become 35–100% higher. The integrated framework was also used to evaluate the Power-to-Methane (PtM) system to relate the electricity mix and various CO2 sources to the PtM environmental impact. To be more attractive than natural gas the climate change impact of the electricity used for PtM should be 123–181 gCO2eq/kWh when the CO2 comes from air or biogenic sources and 4–62 gCO2eq/kWh if the CO2 is from fossil fuels. PtM can have an impact up to 10 times larger for impact categories other than climate change. A system without PtM results in ~4% higher climate change impact and 9% higher fossil depletion while having 5–15% lower impact for most of the other categories. This is based on a scenario where 9 parameters favor PtM deployment and establishes the upper bound of the environmental impact PtM can have. Further studies should work towards integrating LCA feedback into ESM and standardizing the methodology.
Problems of Hydrogen Doping in the Methane Fermentation Process and of Energetic Use of the Gas Mixture
Jul 2021
Publication
This article discusses the technology for doping hydrogen into the fermenter to increase methane production and the amount of energy in the mixture. Hydrogen doping is anticipated to enable more carbon to be applied to produce methane. Hydrogen is proposed to be produced by using excess electricity from for example off-peak electricity hours at night. The possibilities of using a mixture of hydrogen and biogas for combustion in boilers and internal combustion engines have been determined. It has been proven that the volumetric addition of hydrogen reduces the heat of combustion of the mixture. Problems arising from hydrogen doping during the methane fermentation process have been identified.
A Modeling Study of Lifetime and Performance Improvements of Solid Oxide Fuel Cell by Reversed Pulse Operation
Jan 2022
Publication
Chromium poisoning of the air electrode is a primary degradation mechanism for solid oxide cells (SOCs) operating under fuel cell mode. Recent experimental findings show that reversed pulse operation for SOCs operated as electrolyser cells can reverse this degradation and extend the lifetime. Here we use a multiphysics model of an SOC to investigate the effects of reversed pulse operation for alleviating chromium poisoning of the air electrode. We study the effects of time fraction of the operation under fuel cell and electrolysis modes cyclic operation starting after a certain duration and fuel cell and electrolysis current densities on the cell lifetime total power and hydrogen production. Our modeling shows that reversed pulse operation enhances cell lifetime and total power for all different cases considered in this study. Moreover results suggest that the cell lifetime total power and hydrogen production can be increased by reversed pulse operation at longer operation times under electrolysis mode cyclic operation starting from the beginning and lower electrolysis current densities. All in all this paper documents and establishes a computational framework that can serve as a platform to assess and quantify the increased profitability of SOCs operating under a co-production operation through reversed pulse operation.
Assessment of a Fuel Cell Based-hybrid Energy System to Generate and Store Electrical Energy
Jan 2022
Publication
Solid oxide fuel cells (SOFC) have significant applications and performance and their integration into coupled and cascading energy systems can improve the overall performance of the process. Furthermore due to the constant time performance of the fuel cell the problem of fuel starvation may arise by changing the amount of load which can adversely affect the overall performance of the process. In the present study the excess heat of the SOFC is converted into electrical energy in two stages using different heat generators. The coupled energy system in the present article has a new configuration in which the relationship of its components is different from the systems reported in the literature. Furthermore since the use of an energy storage system can improve the overall reliability the energy produced by the coupled energy cycle is stored by a storage technology for peak consumption times. The introduced system can generate approximately 580 W of electrical power with an efficiency of 80%. The highest and lowest share in power generation is related to fuel cell with 82% and thermoelectric generator with 5%. The rest of the system power (i.e. 13%) is produced by thermionic generator. In addition the system requires 0.025 kg per hour of hydrogen fuel. It was also found that to operate the system for 5 h a day requires a storage system with a size of 3.3 m3 . Moreover two key issues to enhance the storage system performance are: adjusting the initial pressure of the system to values close to the peak (optimal) value and using turbines and/or pumps with higher efficiencies. With the aim of supplying 5 kWh of electrical energy five different scenarios based on the design of various effective parameters have been presented.
Development of a Pneumatic Actuated Low-pressure Direct Injection Gas Injector for Hydrogen-fueled Internal Combustion Engines
Dec 2022
Publication
Mixture formation is one of the greatest challenges for the development of robust and efficient hydrogen-fueled internal combustion engines. In many reviews and research papers authors pointed out that direct injection (DI) has noteworthy advantages over a port fuel injection (PFI) such as higher power output higher efficiency the possibility of mixture stratification to control NOx-formation and reduce heat losses and above all to mitigate combustion abnormalities such as back-firing and pre-ignitions. When considering pressurized gas tanks for on-vehicle hydrogen storage a low-pressure (LP) injection system is advantageous since the tank capacity can be better exploited accordingly. The low gas density upstream of the injector requires cross-sectional areas far larger than any other injectors for direct injection in today's gasoline or diesel engines. The injector design proposed in this work consists of a flat valve seat to enable the achievement of lifetime requirements in heavy-duty applications. The gas supply pressure is used as the energy source for the actuation of the valve plate by means of a pneumatic actuator. This article describes the design and the performed tests carried out to prove the concept readiness of the new LP-DI-injector.
Optimal Scheduling of a Hydrogen-Based Energy Hub Considering a Stochastic Multi-Attribute Decision-Making Approach
Jan 2023
Publication
Nowadays the integration of multi-energy carriers is one of the most critical matters in smart energy systems with the aim of meeting sustainable energy development indicators. Hydrogen is referred to as one of the main energy carriers in the future energy industry but its integration into the energy system faces different open challenges which have not yet been comprehensively studied. In this paper a novel day-ahead scheduling is presented to reach the optimal operation of a hydrogen-based energy hub based on a stochastic multi-attribute decision-making approach. In this way the energy hub model is first developed by providing a detailed model of Power-to-Hydrogen (P2H) facilities. Then a new multi-objective problem is given by considering the prosumer’s role in the proposed energy hub model as well as the integrated demand response program (IDRP). The proposed model introduces a comprehensive approach from the analysis of the historical data to the final decision-making with the aim of minimizing the system operation cost and carbon emission. Moreover to deal with system uncertainty the scenario-based method is applied to model the renewable energy resources fluctuation. The proposed problem is defined as mixed-integer non-linear programming (MINLP) and to solve this problem a simple augmented e-constrained (SAUGMECON) method is employed. Finally the simulation of the proposed model is performed on a case study and the obtained results show the effectiveness and benefits of the proposed scheme.
Alternative Fuels for Internal Combustion Engines
Aug 2020
Publication
The recent transport electrification trend is pushing governments to limit the future use of Internal Combustion Engines (ICEs). However the rationale for this strong limitation is frequently not sufficiently addressed or justified. The problem does not seem to lie within the engines nor with the combustion by themselves but seemingly rather with the rise in greenhouse gases (GHG) namely CO2 rejected to the atmosphere. However it is frequent that the distinction between fossil CO2 and renewable CO2 production is not made or even between CO2 emissions and pollutant emissions. The present revision paper discusses and introduces different alternative fuels that can be burned in IC Engines and would eliminate or substantially reduce the emission of fossil CO2 into the atmosphere. These may be non-carbon fuels such as hydrogen or ammonia or biofuels such as alcohols ethers or esters including synthetic fuels. There are also other types of fuels that may be used such as those based on turpentine or even glycerin which could maintain ICEs as a valuable option for transportation.
Methanol Synthesis Using Captured CO2 as Raw Material: Techno-economic and Environmental Assessment
Aug 2015
Publication
The purpose of this paper is to assess via techno-economic and environmental metrics the production of methanol (MeOH) using H2 and captured CO2 as raw materials. It evaluates the potential of this type of carbon capture and utilisation (CCU) plant on (i) the net reduction of CO2 emissions and (ii) the cost of production in comparison with the conventional synthesis process of MeOH Europe. Process flow modelling is used to estimate the operational performance and the total purchased equipment cost; the flowsheet is implemented in CHEMCAD and the obtained mass and energy flows are utilised as input to calculate the selected key performance indicators (KPIs). CO2 -based metrics are used to assess the environmental impact. The evaluated MeOH plant produces 440 ktMeOH/yr and its configuration is the result of a heat integration process. Its specific capital cost is lower than for conventional plants. However raw materials prices i.e. H2 and captured CO2 do not allow such a project to be financially viable. In order to make the CCU plant financially attractive the price of MeOH should increase in a factor of almost 2 or H2 costs should decrease almost 2.5 times or CO2 should have a value of around 222 €/t under the assumptions of this work. The MeOH CCU-plant studied can utilise about 21.5% of the CO2 emissions of a pulverised coal (PC) power plant that produces 550MWnet of electricity. The net CO2 emissions savings represent 8% of the emissions of the PC plant (mainly due to the avoidance of consuming fossil fuels as in the conventional MeOH synthesis process). The results demonstrate that there is a net but small potential for CO2 emissions reduction; assuming that such CCU plants are constructed in Europe to meet the MeOH demand growth and the quantities that are currently imported the net CO2 emissions reduction could be of 2.71 MtCO2/yr.
Photovoltaic and Hydrogen Plant Integrated with a Gas Heat Pump for Greenhouse Heating: A Mathematical Study
Feb 2018
Publication
Nowadays the traditional energy sources used for greenhouse heating are fossil fuels such as LPG diesel and natural gas. The global energy demand will continue to grow and alternative technologies need to be developed in order to improve the sustainability of crop production in protected environments. Innovative solutions are represented by renewable energy plants such as photovoltaic wind and geothermal integrated systems however these technologies need to be connected to the power grid in order to store the energy produced. On agricultural land power grids are not widespread and stand-alone renewable energy systems should be investigated especially for greenhouse applications. The aim of this research is to analyze by means of a mathematical model the energy efficiency of a photovoltaic (8.2 kW) hydrogen (2.5 kW) and ground source gas heat pump (2.2 kW) integrated in a stand-alone system used for heating an experimental greenhouse tunnel (48 m2 ) during the winter season. A yearlong energy performance analysis was conducted for three different types of greenhouse cover materials a single layer polyethylene film an air inflated-double layer polyethylene film and a double acrylic or polycarbonate. The results of one year showed that the integrated system had a total energy efficiency of 14.6%. Starting from the electric energy supplied by the photovoltaic array the total efficiency of the hydrogen and ground source gas heat pump system was 112% if the coefficient of the performance of the heat pump is equal to 5. The heating system increased the greenhouse air temperatures by 3–9 ◦C with respect to the external air temperatures depending on the greenhouse cover material used.
The Effect of the Temperature and Moisture to the Permeation Properties of PEO-Based Membranes for Carbon-Dioxide Separation
Jun 2021
Publication
An increased demand for energy in recent decades has caused an increase in the emissions of combustion products among which carbon-dioxide is the most harmful. As carbon-dioxide induces negative environmental effects like global warming and the greenhouse effect a decrease of the carbon-dioxide emission has emerged as one of the most urgent tasks in engineering. In this work the possibility for the application of the polymer-based dense mixed matrix membranes for flue gas treatment was tested. The task was to test a potential decrease in the permeability and selectivity of a mixed-matrix membrane in the presence of moisture and at elevated temperature. Membranes are based on two different poly(ethylene oxide)-based polymers filled with two different zeolite powders (ITR and IWS). An additive of detergent type was added to improve the contact properties between the zeolite and polymer matrix. The measurements were performed at three different temperatures (30 60 and 90 °C) under wet conditions with partial pressure of the water equal to the vapor pressure of the water at the given temperature. The permeability of carbon-dioxide hydrogen nitrogen and oxygen was measured and the selectivity of the carbon-dioxide versus other gases was determined. Obtained results have shown that an increase of temperature and partial pressure of the vapor slightly increase both the selectivity and permeability of the synthesized membranes. It was also shown that the addition of the zeolite powder increases the permeability of carbon-dioxide while maintaining the selectivity compared to hydrogen oxygen and nitrogen.
A Review of Fuel Cell Systems for Maritime Applications
Jul 2016
Publication
Progressing limits on pollutant emissions oblige ship owners to reduce the environmental impact of their operations. Fuel cells may provide a suitable solution since they are fuel efficient while they emit few hazardous compounds. Various choices can be made with regard to the type of fuel cell system and logistic fuel and it is unclear which have the best prospects for maritime application. An overview of fuel cell types and fuel processing equipment is presented and maritime fuel cell application is reviewed with regard to efficiency gravimetric and volumetric density dynamic behaviour environmental impact safety and economics. It is shown that low temperature fuel cells using liquefied hydrogen provide a compact solution for ships with a refuelling interval up to a tens of hours but may result in total system sizes up to five times larger than high temperature fuel cells and more energy dense fuels for vessels with longer mission requirements. The expanding infrastructure of liquefied natural gas and development state of natural gas-fuelled fuel cell systems can facilitate the introduction of gaseous fuels and fuel cells on ships. Fuel cell combined cycles hybridisation with auxiliary electricity storage systems and redundancy improvements are identified as topics for further study
Numerical Evaluation of the Effect of Fuel Blending with CO2 and H2 on the Very Early Corona‐Discharge Behavior in Spark Ignited Engines
Feb 2022
Publication
Reducing green‐house gases emission from light‐duty vehicles is compulsory in order to slow down the climate change. The application of High Frequency Ignition systems based on the Corona discharge effect has shown the potential to extend the dilution limit of engine operating conditions promoting lower temperatures and faster combustion events thus higher thermal and indicating efficiency. Furthermore predicting the behavior of Corona ignition devices against new sustainable fuel blends including renewable hydrogen and biogas is crucial in order to deal with the short‐intermediate term fleet electric transition. The numerical evaluation of Corona‐induced discharge radius and radical species under those conditions can be helpful in order to capture local effects that could be reached only with complex and expensive optical investigations. Using an ex‐ tended version of the Corona one‐dimensional code previously published by the present authors the simulation of pure methane and different methane–hydrogen blends and biogas–hydrogen blends mixed with air was performed. Each mixture was simulated both for 10% recirculated exhaust gas dilution and for its corresponding dilute upper limit which was estimated by means of chemical kinetics simulations integrated with a custom misfire detection criterion.
Optimization of Component Sizing for a Fuel Cell-Powered Truck to Minimize Ownership Cost
Mar 2019
Publication
In this study we consider fuel cell-powered electric trucks (FCETs) as an alternative to conventional medium- and heavy-duty vehicles. FCETs use a battery combined with onboard hydrogen storage for energy storage. The additional battery provides regenerative braking and better fuel economy but it will also increase the initial cost of the vehicle. Heavier reliance on stored hydrogen might be cheaper initially but operational costs will be higher because hydrogen is more expensive than electricity. Achieving the right tradeoff between these power and energy choices is necessary to reduce the ownership cost of the vehicle. This paper develops an optimum component sizing algorithm for FCETs. The truck vehicle model was developed in Autonomie a platform for modelling vehicle energy consumption and performance. The algorithm optimizes component sizes to minimize overall ownership cost while ensuring that the FCET matches or exceeds the performance and cargo capacity of a conventional vehicle. Class 4 delivery truck and class 8 linehaul trucks are shown as examples. We estimate the ownership cost for various hydrogen costs powertrain components ownership periods and annual vehicle miles travelled.
A Hydrogen Fuelled LH2 Tanker Ship Design
May 2021
Publication
This study provides a detailed philosophical view and evaluation of a viable design for a large liquid hydrogen tanker fuelled by liquid hydrogen. Established methods for determining tank sizing ship stability and ship characteristics were used to evaluate the preliminary design and performance of the liquefied hydrogen tanker named ‘JAMILA’ designed specifically to transport liquid hydrogen. JAMILA is designed around four large liquid hydrogen tanks with a total capacity of ∼280000 m3 and uses the boil-off gas for propulsion for the loaded leg of the journey. The ship is 370 m long 75 m wide and draws 10.012 m at full load. It has a fully loaded displacement tonnage of 232000 tonnes to carry 20000 tonnes of hydrogen. Its propulsion system contains a combined-cycle gas turbine of approximately 50 MW. The volume of the hydrogen cargo pressurised to 0.5 MPa primarily determines the size and displacement of the ship.
A 1000 MWth Boiler for Chemical-looping Combustion of Solid Fuels – Discussion of Design and Costs
May 2015
Publication
More than 2000 h of solid-fuel CLC operation in a number of smaller pilot units clearly indicate that the concept works. A scale-up of the technology to 1000 MWth is investigated in terms of mass and heat balances flows solids inventories boiler dimensions and the major differences between a full-scale Circulating Fluidized-Bed (CFB) boiler and a Chemical-Looping Combustion CFB (CLC–CFB). Furthermore the additional cost of CLC–CFB relative to CFB technology is analysed and found to be 20 €/tonne CO2. The largest cost is made up of compression of CO2 which is common to all capture technologies. Although the need for oxygen to manage incomplete conversion is estimated to be only a tenth of that of oxy-fuel combustion oxygen production is nonetheless the second largest cost. Other significant costs include oxygen-carrier material increased boiler cost and steam for fluidization of the fuel reactor.
A Hot Syngas Purification System Integrated with Downdraft Gasification of Municipal Solid Waste
Jan 2019
Publication
Gasification of municipal solid waste (MSW) with subsequent utilization of syngas in gas engines/turbines and solid oxide fuel cells can substantially increase the power generation of waste-to-energy facilities and optimize the utilization of wastes as a sustainable energy resources. However purification of syngas to remove multiple impurities such as particulates tar HCl alkali chlorides and sulfur species is required. This study investigates the feasibility of high temperature purification of syngas from MSW gasification with the focus on catalytic tar reforming and desulfurization. Syngas produced from a downdraft fixed-bed gasifier is purified by a multi-stage system. The system comprises of a fluidized-bed catalytic tar reformer a filter for particulates and a fixed-bed reactor for dechlorination and then desulfurization with overall downward cascading of the operating temperatures throughout the system. Novel nano-structured nickel catalyst supported on alumina and regenerable Ni-Zn desulfurization sorbent loaded on honeycomb are synthesized. Complementary sampling and analysis methods are applied to quantify the impurities and determine their distribution at different stages. Experimental and thermodynamic modeling results are compared to determine the kinetic constraints in the integrated system. The hot purification system demonstrates up to 90% of tar and sulfur removal efficiency increased total syngas yield (14%) and improved cold gas efficiency (12%). The treated syngas is potentially applicable in gas engines/turbines and solid oxide fuel cells based on the dew points and concentration limits of the remaining tar compounds. Reforming of raw syngas by nickel catalyst for over 20 h on stream shows strong resistance to deactivation. Desulfurization of syngas from MSW gasification containing significantly higher proportion of carbonyl sulfide than hydrogen sulfide traces of tar and hydrogen chloride demonstrates high performance of Ni-Zn sorbents.
Optimal Sizing of Storage Elements for a Vehicle Based on Fuel Cells, Supercapacitors, and Batteries
Mar 2019
Publication
To achieve a vehicle-efficient energy management system an architecture composed of a PEM fuel cell as the main energy source and a hybrid storage system based on battery banks and supercapacitors is proposed. This paper introduces a methodology for the optimal component sizing aiming at minimizing the total cost achieving a cheaper system that can achieve the requirements of the speed profiles. The chosen vehicle is an urban transport bus which must meet the Buenos Aires Driving Cycle and the Manhattan Driving Cycle. The combination of batteries and supercapacitors allows a better response to the vehicle’s power demand since it combines the high energy density of the batteries with the high power density of the supercapacitors allowing the best absorption of energy coming from braking. In this way we address the rapid changes in power without reducing the global efficiency of the system. Optimum use of storage systems and fuel cell is analyzed through dynamic programming.
Strategies for Hydrogen-Enriched Methane Flameless Combustion in a Quasi-Industrial Furnace
Jan 2020
Publication
In this present work simulations of 20 kW furnace were carried out with hydrogenenriched methane mixtures to identify optimal geometrical configurations and operating conditions to operate in flameless combustion regime. The objective of this work is to show the advantages of flameless combustion for hydrogen-enriched fuels and the limits of current typical industrial designs for these mixtures. The performances of a semi-industrial combustion chamber equipped with a self-recuperative flameless burner are evaluated with increasing H2 concentrations. For highly H2-enriched mixtures typical burners employed for methane appear to be inadequate to reach flameless conditions. In particular for a typical coaxial injector configuration an equimolar mixture of hydrogen and methane represents the limit for hydrogen enrichment. To achieve flameless conditions different injector geometries and configuration were tested. Fuel dilution with CO2 and H2O was also investigated. Dilution slows the mixing process consequently helping the transition to flameless conditions. CO2 and H2O are typical products of hydrogen generation processes therefore their use in fuel dilution is convenient for industrial applications. Dilution thus allows the use of greater hydrogen percentages in the mixture.
A Comparative Study of Energy Consumption and Recovery of Autonomous Fuel-Cell Hydrogen–Electric Vehicles Using Different Powertrains Based on Regenerative Braking and Electronic Stability Control System
Mar 2021
Publication
Today with the increasing transition to electric vehicles (EVs) the design of highly energy-efficient vehicle architectures has taken precedence for many car manufacturers. To this end the energy consumption and recovery rates of different powertrain vehicle architectures need to be investigated comprehensively. In this study six different powertrain architectures—four independent in-wheel motors with regenerative electronic stability control (RESC) and without an RESC one-stage gear (1G) transmission two-stage gear (2G) transmission continuously variable transmission (CVT) and downsized electric motor with CVT—were mathematically modeled and analyzed under real road conditions using nonlinear models of an autonomous hydrogen fuel-cell electric vehicle (HFCEV). The aims of this paper were twofold: first to compare the energy consumption performance of powertrain architectures by analyzing the effects of the regenerative electronic stability control (RESC) system and secondly to investigate the usability of a downsized electrical motor for an HFCEV. For this purpose all the numerical simulations were conducted for the well-known FTP75 and NEDC urban drive cycles. The obtained results demonstrate that the minimum energy consumption can be achieved by a 2G-based powertrain using the same motor; however when an RESC system is used the energy recovery/consumption rate can be increased. Moreover the results of the article show that it is possible to use a downsized electric motor due to the CVT and this powertrain significantly reduces the energy consumption of the HFCEV as compared to all the other systems. The results of this paper present highly significant implications for automotive manufacturers for designing and developing a cleaner electrical vehicle energy consumption and recovery system.
Fuel Cell Electrical Vehicles as Mobile Coupled Heat and Power Backup-Plant in Neighbourhoods
Apr 2022
Publication
Fuel cell electric vehicles (FCEVs) can be used during idle times to convert hydrogen into electricity in a decentralised manner thus ensuring a completely renewable energy supply. In addition to the electric power waste heat is generated in the fuel cell stack that can also be used. This paper investigates how the energy demand of a compiled German neighbourhood can be met by FCEVs and identifies potential technical problems. For this purpose energy scenarios are modelled in the Open Energy System Modelling Framework (oemof). An optimisation simulation finds the most energetically favourable solution for the 10-day period under consideration. Up to 49% of the heat demand for heating and hot water can be covered directly by the waste heat of the FCEVs. As the number of battery electric vehicles (BEVs) to be charged increases so does this share. 5 of the 252 residents must permanently provide an FCEV to supply the neighbourhood. The amount of hydrogen required was identified as a problem. If the vehicles cannot be supplied with hydrogen in a stationary way 15 times more vehicles are needed than required in terms of performance due to the energy demand.
Performance Analysis of a Zero-Energy Building Using Photovoltaics and Hydrogen Storage
Mar 2023
Publication
The exploitation of renewable energy sources in the building sector is a challenging aspect of achieving sustainability. The incorporation of a proper storage unit is a vital issue for managing properly renewable electricity production and so to avoid the use of grid electricity. The present investigation examines a zero-energy residential building that uses photovoltaics for covering all its energy needs (heating cooling domestic hot water and appliances-lighting needs). The building uses a reversible heat pump and an electrical heater so there is not any need for fuel. The novel aspect of the present analysis lies in the utilization of hydrogen as the storage technology in a power-to-hydrogen-to-power design. The residual electricity production from the photovoltaics feeds an electrolyzer for hydrogen production which is stored in the proper tank under high pressure. When there is a need for electricity and the photovoltaics are not enough the hydrogen is used in a fuel cell for producing the needed electricity. The present work examines a building of 400 m2 floor area in Athens with total yearly electrical demand of 23656 kWh. It was found that the use of 203 m2 of photovoltaics with a hydrogen storage capacity of 34 m3 can make the building autonomous for the year period.
Optimal Energy Management for Hydrogen Economy in a Hybrid Electric Vehicle
Feb 2023
Publication
Fuel cell hybrid electric vehicles (FCEVs) are mainly electrified by the fuel cell (FC) system. As a supplementary power source a battery or supercapacitor (SC) is employed (besides the FC) to enhance the power response due to the slow dynamics of the FC. Indeed the performance of the hybrid power system mainly depends on the required power distribution manner among the sources which is managed by the energy management strategy (EMS). This paper considers an FCEV based on the proton exchange membrane FC (PEMFC)/battery/SC. The energy management strategy is designed to ensure optimum power distribution between the sources considering hydrogen consumption. Its main objective is to meet the electric motor’s required power with economic hydrogen consumption and better electrical efficiency. The proposed EMS combines the external energy maximization strategy (EEMS) and the bald eagle search algorithm (BES). Simulation tests for the Extra-Urban Driving Cycle (EUDC) and New European Driving Cycle (NEDC) profiles were performed. The test is supposed to be performed in typical conditions t = 25 ◦C on a flat road without no wind effect. In addition this strategy was compared with the state machine control strategy classic PI and equivalent consumption minimization strategy. In terms of optimization the proposed approach was compared with the original EEMS particle swarm optimization (PSO)-based EEMS and equilibrium optimizer (EO)-based EEMS. The results confirm the ability of the proposed strategy to reduce fuel consumption and enhance system efficiency. This strategy provides 26.36% for NEDC and 11.35% for EUDC fuel-saving and efficiency enhancement by 6.74% for NEDC and 36.19% for EUDC.
A Review of The Methanol Economy: The Fuel Cell Route
Jan 2020
Publication
This review presents methanol as a potential renewable alternative to fossil fuels in the fight against climate change. It explores the renewable ways of obtaining methanol and its use in efficient energy systems for a net zero-emission carbon cycle with a special focus on fuel cells. It investigates the different parts of the carbon cycle from a methanol and fuel cell perspective. In recent years the potential for a methanol economy has been shown and there has been significant technological advancement of its renewable production and utilization. Even though its full adoption will require further development it can be produced from renewable electricity and biomass or CO2 capture and can be used in several industrial sectors which make it an excellent liquid electrofuel for the transition to a sustainable economy. By converting CO2 into liquid fuels the harmful effects of CO2 emissions from existing industries that still rely on fossil fuels are reduced. The methanol can then be used both in the energy sector and the chemical industry and become an all-around substitute for petroleum. The scope of this review is to put together the different aspects of methanol as an energy carrier of the future with particular focus on its renewable production and its use in high-temperature polymer electrolyte fuel cells (HT-PEMFCs) via methanol steam reforming.
Review of Life Cycle Assessments for Steel and Environmental Analysis of Future Steel Production Scenarios
Oct 2022
Publication
The steel industry is focused on reducing its environmental impact. Using the life cycle assessment (LCA) methodology the impacts of the primary steel production via the blast furnace route and the scrap-based secondary steel production via the EAF route are assessed. In order to achieve environmentally friendly steel production breakthrough technologies have to be implemented. With a shift from primary to secondary steel production the increasing steel demand is not met due to insufficient scrap availability. In this paper special focus is given on recycling methodologies for metals and steel. The decarbonization of the steel industry requires a shift from a coal-based metallurgy towards a hydrogen and electricity-based metallurgy. Interim scenarios like the injection of hydrogen and the use of pre-reduced iron ores in a blast furnace can already reduce the greenhouse gas (GHG) emissions up to 200 kg CO2/t hot metal. Direct reduction plants combined with electrical melting units/furnaces offer the opportunity to minimize GHG emissions. The results presented give guidance to the steel industry and policy makers on how much renewable electric energy is required for the decarbonization of the steel industry
A Study on Green Hydrogen-based Isolated Microgrid
Oct 2022
Publication
This paper assesses the techno-economic feasibility of a green hydrogen-based microgrid for a remote Australian island. Hydrogen can be used to provide clean energy in areas where large-scale renewable energy sources are not feasible owing to geography government regulations or regulatory difficulties. This study not only identifies the appropriate component size for a hydrogen-based microgrid but also provides an economic perspective of decarbonising Thursday Island in Torres Straits Queensland Australia. Due to geographical constraints the green hydrogen production system needs to be distinct from the electrical network. This research shows how to produce green hydrogen transport it and generate power at a low cost. The study was performed utilising the HOMER simulation platform to find the least cost solution. The simulation results demonstrate an AU$0.01 reduction in Levelised Cost of Energy compared to the present electricity generation cost which is AU$0.56. The inclusion of a green hydrogen system will potentially minimise CO2 emissions by 99.6% while ensuring almost 100% renewable penetration. The results of this study will also serve as a guide for the placement of hydrogen-based microgrids in similar remote locations around the world where numerous remote energy systems are located close to each other.
Carbon Capture and Biomass in Industry: A Techno-economic Analysis and Comparison of Negative Emission Options
Apr 2021
Publication
Meeting the Paris Agreement will most likely require the combination of CO2 capture and biomass in the industrial sector resulting in net negative emissions. CO2 capture within the industry has been extensively investigated. However biomass options have been poorly explored with literature alluding to technical and economic barriers. In addition a lack of consistency among studies makes comparing the performance of CO2 capture and/or biomass use between studies and sectors difficult. These inconsistencies include differences in methodology system boundaries level of integration costs greenhouse gas intensity of feedstock and energy carriers and capital cost estimations. Therefore an integrated evaluation of the techno-economic performance regarding CO2 capture and biomass use was performed for five energy-intensive industrial sub-sectors. Harmonization results indicate that CO2 mitigation potentials vary for each sub-sector resulting in reductions of 1.4–2.7 t CO2/t steel (77%–149%) 0.7 t CO2/t cement (92%) 0.2 t CO2/t crude oil (68%) 1.9 t CO2/t pulp (1663%–2548%) and 34.9 t CO2/t H2 (313%). Negative emissions can be reached in the steel paper and H2 sectors. Novel bio-based production routes might enable net negative emissions in the cement and (petro) chemical sectors as well. All the above-mentioned potentials can be reached for 100 €/t CO2 or less. Implementing mitigation options could reduce industrial CO2 emissions by 10 Gt CO2/y by 2050 easily meeting the targets of the 2 ◦C scenario by the International Energy Agency (1.8 Gt CO2/y reduction) for the industrial sector and even the Beyond 2 ◦C scenario (4.2 Gt CO2/y reduction).
The Role of LNG in the Transition Toward Low- and Zero-carbon Shipping
Apr 2021
Publication
Due to its much lower air pollution and potential greenhouse gas (GHG) emissions benefits liquefied natural gas (LNG) is frequently discussed as a fuel pathway towards greener maritime transport. While LNG’s air quality improvements are undeniable there is debate within the sector as to what extent LNG may be able to contribute to decarbonizing shipping. This report “The Role of LNG in the Transition Toward Low- and Zero-Carbon Shipping” considers the potential of LNG to play either a transitional role in which existing LNG infrastructure and vessels could continue to be used with compatible zero-carbon bunker fuels after 2030 or a temporary one in which LNG would be rapidly supplanted by zero-carbon alternatives from 2030. Over concerns about methane leakage which could diminish or even offset any GHG benefits associated with LNG and additional capital expenditures the risk of stranded assets as well as a technology lock-in the report concludes that LNG is unlikely to play a significant role in decarbonizing maritime transport. Instead the research finds that LNG is likely to only be used in niche shipping applications or in its non-liquefied form as a feedstock to kickstart the production of zero-carbon bunker fuels when used in conjunction with carbon capture and storage technology. The research further suggests that new public policy in support of LNG as a bunker fuel should be avoided existing policy support should be reconsidered and methane emissions should be regulated.
Numerical Predictions of a Swirl Combustor Using Complex Chemistry Fueled with Ammonia/Hydrogen Blends
Jan 2020
Publication
Ammonia a chemical that contains high hydrogen quantities has been presented as a candidate for the production of clean power generation and aerospace propulsion. Although ammonia can deliver more hydrogen per unit volume than liquid hydrogen itself the use of ammonia in combustion systems comes with the detrimental production of nitrogen oxides which are emissions that have up to 300 times the greenhouse potential of carbon dioxide. This factor combined with the lower energy density of ammonia makes new studies crucial to enable the use of the molecule through methods that reduce emissions whilst ensuring that enough power is produced to support high-energy intensive applications. Thus this paper presents a numerical study based on the use of novel reaction models employed to characterize ammonia combustion systems. The models are used to obtain Reynolds Averaged Navier-Stokes (RANS) simulations via Star-CCM+ with complex chemistry of a 70%–30% (mol) ammonia–hydrogen blend that is currently under investigations elsewhere. A fixed equivalence ratio (1.2) medium swirl (0.8) and confined conditions are employed to determine the flame and species propagation at various operating atmospheres and temperature inlet values. The study is then expanded to high inlet temperatures high pressures and high flowrates at different confinement boundary conditions. The results denote how the production of NOx emissions remains stable and under 400 ppm whilst higher concentrations of both hydrogen and unreacted ammonia are found in the flue gases under high power conditions. The reduction of heat losses (thus higher temperature boundary conditions) has a crucial impact on further destruction of ammonia post-flame with a raise in hydrogen water and nitrogen through the system thus presenting an opportunity of combustion efficiency improvement of this blend by reducing heat losses. Final discussions are presented as a method to raise power whilst employing ammonia for gas turbine systems.
The Trajectory of Hybrid and Hydrogen Technologies in North American Heavy Haul Operations
Jul 2021
Publication
The central aim of this paper is to provide an up-to-date snapshot of hybrid and hydrogen technology-related developments and activities in the North American heavy haul railway setting placed in the context of the transportation industry more broadly. An overview of relevant alternative propulsion technologies is provided including a discussion of applicability to the transportation sector in general and heavy haul freight rail specifically. This is followed by a discussion of current developments and research in alternative and blended fuels discussed again in both general and specific settings. Key factors and technical considerations for heavy haul applications are reviewed followed by a discussion of non-technical and human factors that motivate a move toward clean energy in North American Heavy Haul systems. Finally current project activities are described to provide a clear understanding of both the status and trajectory of hybrid and hydrogen technologies in the established context.
Numerical Modeling of Energy Systems Based on Micro Gas Turbine: A Review
Jan 2022
Publication
In the context of the great research pulse on clean energy transition distributed energy systems have a key role especially in the case of integration of both renewable and traditional energy sources. The stable interest in small-scale gas turbines can further increase owing to their flexibility in both operation and fuel supply. Since their not-excellent electrical efficiency research activities on micro gas turbine (MGT) are focused on the performance improvements that are achievable in several ways like modifying the Brayton cycle integrating two or more plants using cleaner fuels. Hence during the last decades the growing interest in MGT-based energy systems encouraged the development of many numerical approaches aimed to provide a reliable and effective prediction of the energy systems’ behavior. Indeed numerical modeling can help to individuate potentialities and issues of each enhanced layout or hybrid energy system and this review aims to discuss the various layout solutions proposed by researchers with particular attention to recent publications highlighting the adopted modeling approaches and methods.
Fuel Flexibility of Solid Oxide Fuel Cells
Aug 2021
Publication
One of the major advantages of SOFCs is their high fuel flexibility. Next to natural gas and hydrogen which are today’s most common fuels for SOFC-systems and cell-/stack-testing respectively various other fuels are applicable as well. In the literature a number of promising results show that available fuels as propane butane ammonia gasoline diesel etc. can be applied. Here the performance of an anode supported cell operated in specialized single cell test benches with different gaseous and liquid fuels and reformates thereof is presented. Fuels as ammonia dissolved urea (AddBlueTM) methane/steam and ethanol/water mixtures can directly be fed to the cell whereas propane and diesel require external reforming. It is shown that in case of a stable fuel supply the cell performance with such fuels is similar to that of appropriate mixtures of H2 N2 CO CO2 and steam if the impact of endothermic reforming or decomposition reactions is considered. Even though a stable fuel cell operation with such fuels is possible in a single cell test bench it should be pointed out that an appropriate fuel processing will be mandatory on the system level.
Comparison of Alternative Marine Fuels
Sep 2019
Publication
The overall ambition of the study has been to assess the commercial and operational viability of alternative marine fuels based on review existing academic and industry literature. The approach assesses how well six alternative fuels perform compared to LNG fuel on a set of 11 key parameters. Conventional fuels are not covered in this study however 2020 compliant fuels (HFO+scrubber and low sulphur fuels are included in the conclusion for comparative purposes.
Risks and Opportunities Associated with Decarbonising Rotterdam’s Industrial Cluster
Jun 2019
Publication
The Port of Rotterdam is an important industrial cluster comprising mainly oil refining chemical production and power generation. In 2016 the port’s industry accounted for 19% of the Netherlands’ total CO2 emissions. The Port of Rotterdam Authority is aware that the cluster is heavily exposed to future decarbonisation policies as most of its activities focus on trading handling converting and using fossil fuels. Based on a study for the Port Authority using a mixture of qualitative and quantitative methods our article explores three pathways whereby the port’s industry can maintain its strong position while significantly reducing its CO2 emissions and related risks by 2050. The pathways differ in terms of the EU’s assumed climate change mitigation ambitions and the key technological choices made by the cluster’s companies. The focus of the paper is on identifying key risks associated with each scenario and ways in which these could be mitigated.
Optimal Design for a Hybrid Microgrid-hydrogen Storage Facility in Saudi Arabia
May 2022
Publication
Background: Sustainable development requires access to afordable reliable and efcient energy to lift billions of people out of poverty and improve their standard of living. The development of new and renewable forms of energy that emit less CO2 may not materialize quickly enough or at a price point that allows people to attain the standard of living they desire and deserve. As a result a parallel path to sustainability must be developed that uses both renewable and clean carbon-based methods. Hybrid microgrids are promoted to solve various electrical and energy-related issues that incorporate renewable energy sources such as photovoltaics wind diesel generation or a combination of these sources. Utilizing microgrids in electric power generation has several benefts including clean energy increased grid stability and reduced congestion. Despite these advantages microgrids are not frequently deployed because of economic concerns. To address these fnancial concerns it is necessary to explore the ideal confguration of micro-grids based on the quantity quality and availability of sustainable energy sources used to install the microgrid and the optimal design of microgrid components. These considerations are refected in net present value and levelized energy cost. Methods: HOMER was used to simulate numerous system confgurations and select the most feasible solution according to the net present value levelizied cost of energy and hydrogen operating cost and renewable fraction. HOMER performed a repeated algorithm process to determine the most feasible system configuration and parameters with the least economic costs and highest benefits to achieve a practically feasible system configuration. Results: This article aimed to construct a cost-effective microgrid system for Saudi Arabia’s Yanbu city using five configurations using excess energy to generate hydrogen. The obtained results indicate that the optimal configuration for the specified area is a hybrid photovoltaic/wind/battery/generator/fuel cell/hydrogen electrolyzer microgrid with a net present value and levelized energy cost of $10.6 billion and $0.15/kWh. Conclusion: With solar photovoltaic and wind generation costs declining building electrolyzers in locations with excellent renewable resource conditions such as Saudi Arabia could become a low-cost hydrogen supply option even when accounting for the transmission and distribution costs of transporting hydrogen from renewable resource locations to end-users. The optimum confguration can generate up to 32132 tons of hydrogen per year (tH2/year) and 380824 tons per year of CO2 emissions can be avoided.
Integration of Battery and Hydrogen Energy Storage Systems with Small-scale Hydropower Plants in Off-grid Local Energy Communities
Apr 2024
Publication
The energy transition is pushing towards a considerable diffusion of local energy communities based on renewable energy systems and coupled with energy storage systems or energy vectors to provide independence from fossil fuels and limit carbon emissions. Indeed the variable and intermittent nature of renewables make them inadequate to satisfy the end-users’ electricity demand throughout the whole day; thus the study of energy storage systems considering their seasonal storage behaviour (e.g. energy-power coupling selfdischarge loss and minimum state of charge) is fundamental to guarantee the proper energy coverage. This work aims at identifying the off-grid operation of a local energy community powered by a 220 kW small-scale hydropower plant in the center of Italy using either a battery energy storage system or a hydrogen one with the Calliope framework. Results show that whereas the hydrogen storage system is composed of a 137 kW electrolyser a 41 kW fuel cell and a storage of 5247 kgH2 a battery system storage system would have a capacity of 280 MWh. Even though the battery storage has a better round-trip efficiency its self-discharge loss and minimum state of charge limitation involve a discharging phase with a steeper slope thus requiring considerable economic investments because of the high energy-to-power ratio.
Performance Analysis of a Stand-alone Integrated Solar Hydrogen Energy System for Zero Energy Buildings
Oct 2022
Publication
This study analyzes the optimal sizing design of a stand-alone solar hydrogen hybrid energy system for a house in Afyon Turkey. The house is not connected to the grid and the proposed hybrid system meets all its energy demands; therefore it is considered a zero-energy building. The designed system guarantees uninterrupted and reliable power throughout the year. Since the reliability of the power supply is crucial for the house optimal sizing of the components photovoltaic (PV) panels electrolyzer storage tank and fuel cell stack is critical. Determining the sufficient number of PV panels suitable electrolyzer model and size number of fuel cell stacks and the minimum storage tank volume to use in the proposed system can guarantee an uninterrupted energy supply to the house. In this study a stand-alone hybrid energy system is proposed. The system consists of PV panels a proton exchange membrane (PEM) electrolyzer a storage tank and a PEM fuel cell stack. It can meet the continuous energy demand of the house is sized by using 10 min of averaged solar irradiation and temperature data of the site and consumption data of the house. Present results show that the size of each component in a solar hydrogen hybrid energy system in terms of power depends on the size of each other components to meet the efficiency requirement of the whole system. Choosing the nominal electrolyzer power is critical in such energy systems
The Use of Hydrogen for Traction in Freight Transport: Estimating the Reduction in Fuel Consumption and Emissions in a Regional Context
Jan 2023
Publication
The Italian National Recovery and Resilience Plan (NRRP) includes among other measures investments in hydrogen vehicle refuelling stations intending to promote the use of fuel cell electric vehicles (FCEVs) for long-haul freight transport. This paper evaluates the impact that this action could have on CO2 emissions and fuel consumption focusing on a case study of the Campania region. The proposed approach which can also be transferred to other geographical contexts requires the implementation of a freight road transport simulation model; this model is based on the construction of a supply model the estimation of road freight demand and an assignment procedure for computing traffic flows. This study covers the period from 2025 to 2040 according to the forecasts of the NRRP and some assumptions on the action effects; moreover it is assumed that hydrogen is entirely produced from renewable sources (green hydrogen). The key findings from three different scenarios show that savings between 423832 and 778538 tonnes of CO2 and between 144 and 264 million litres of diesel could be obtained.
A Prompt Decarbonization Pathway for Shipping: Green Hydrogen, Ammonia, and Methanol Production and Utilization in Marine Engines
Mar 2023
Publication
The shipping industry has reached a higher level of maturity in terms of its knowledge and awareness of decarbonization challenges. Carbon-free or carbon-neutralized green fuel such as green hydrogen green ammonia and green methanol are being widely discussed. However little attention has paid to the green fuel pathway from renewable energy to shipping. This paper therefore provides a review of the production methods for green power (green hydrogen green ammonia and green methanol) and analyzes the potential of green fuel for application to shipping. The review shows that the potential production methods for green hydrogen green ammonia and green methanol for the shipping industry are (1) hydrogen production from seawater electrolysis using green power; (2) ammonia production from green hydrogen + Haber–Bosch process; and (3) methanol production from CO2 using green power. While the future of green fuel is bright in the short term the costs are expected to be higher than conventional fuel. Our recommendations are therefore as follows: improve green power production technology to reduce the production cost; develop electrochemical fuel production technology to increase the efficiency of green fuel production; and explore new technology. Strengthening the research and development of renewable energy and green fuel production technology and expanding fuel production capacity to ensure an adequate supply of low- and zero-emission marine fuel are important factors to achieve carbon reduction in shipping.
The Direct Reduction of Iron Ore with Hydrogen
Aug 2022
Publication
The steel industry represents about 7% of the world’s anthropogenic CO2 emissions due to the high use of fossil fuels. The CO2 -lean direct reduction of iron ore with hydrogen is considered to offer a high potential to reduce CO2 emissions and this direct reduction of Fe2O3 powder is investigated in this research. The H2 reduction reaction kinetics and fluidization characteristics of fine and cohesive Fe2O3 particles were examined in a vibrated fluidized bed reactor. A smooth bubbling fluidization was achieved. An increase in external force due to vibration slightly increased the pressure drop. The minimum fluidization velocity was nearly independent of the operating temperature. The yield of the direct H2 -driven reduction was examined and found to exceed 90% with a maximum of 98% under the vibration of ~47 Hz with an amplitude of 0.6 mm and operating temperatures close to 500 ◦C. Towards the future of direct steel ore reduction cheap and “green” hydrogen sources need to be developed. H2 can be formed through various techniques with the catalytic decomposition of NH3 (and CH4 ) methanol and ethanol offering an important potential towards production cost yield and environmental CO2 emission reductions.
Solar–Hydrogen Storage System: Architecture and Integration Design of University Energy Management Systems
May 2024
Publication
As a case study on sustainable energy use in educational institutions this study examines the design and integration of a solar–hydrogen storage system within the energy management framework of Kangwon National University’s Samcheok Campus. This paper provides an extensive analysis of the architecture and integrated design of such a system which is necessary given the increasing focus on renewable energy sources and the requirement for effective energy management. This study starts with a survey of the literature on hydrogen storage techniques solar energy storage technologies and current university energy management systems. In order to pinpoint areas in need of improvement and chances for progress it also looks at earlier research on solar–hydrogen storage systems. This study’s methodology describes the system architecture which includes fuel cell integration electrolysis for hydrogen production solar energy harvesting hydrogen storage and an energy management system customized for the needs of the university. This research explores the energy consumption characteristics of the Samcheok Campus of Kangwon National University and provides recommendations for the scalability and scale of the suggested system by designing three architecture systems of microgrids with EMS Optimization for solar–hydrogen hybrid solar–hydrogen and energy storage. To guarantee effective and safe functioning control strategies and safety considerations are also covered. Prototype creation testing and validation are all part of the implementation process which ends with a thorough case study of the solar–hydrogen storage system’s integration into the university’s energy grid. The effectiveness of the system its effect on campus energy consumption patterns its financial sustainability and comparisons with conventional energy management systems are all assessed in the findings and discussion section. Problems that arise during implementation are addressed along with suggested fixes and directions for further research—such as scalability issues and technology developments—are indicated. This study sheds important light on the viability and efficiency of solar–hydrogen storage systems in academic environments particularly with regard to accomplishing sustainable energy objectives.
Hydrogen-Powered Aviation—Design of a Hybrid-Electric Regional Aircraft for Entry into Service in 2040
Mar 2023
Publication
Over the past few years the rapid growth of air traffic and the associated increase in emissions have created a need for sustainable aviation. Motivated by these challenges this paper explores how a 50-passenger regional aircraft can be hybridized to fly with the lowest possible emissions in 2040. In particular the use of liquid hydrogen in this aircraft is an innovative power source that promises to reduce CO2 and NOx emissions to zero. Combined with a fuel-cell system the energy obtained from the liquid hydrogen can be used efficiently. To realize a feasible concept in the near future considering the aspects of performance and security the system must be hybridized. In terms of maximized aircraft sustainability this paper analyses the flight phases and ground phases resulting in an aircraft design with a significant reduction in operating costs. Promising technologies such as a wingtip propeller and electric green taxiing are discussed in this paper and their potential impacts on the future of aviation are highlighted. In essence the hybridization of regional aircraft is promising and feasible by 2040; however more research is needed in the areas of fuel-cell technology thermal management and hydrogen production and storage.
Comparative TCO Analysis of Battery Electric and Hydrogen Fuel Cell Buses for Public Transport System in Small to Midsize Cities
Jul 2021
Publication
This paper shows the results of an in-depth techno-economic analysis of the public transport sector in a small to midsize city and its surrounding area. Public battery-electric and hydrogen fuel cell buses are comparatively evaluated by means of a total cost of ownership (TCO) model building on historical data and a projection of market prices. Additionally a structural analysis of the public transport system of a specific city is performed assessing best fitting bus lines for the use of electric or hydrogen busses which is supported by a brief acceptance evaluation of the local citizens. The TCO results for electric buses show a strong cost decrease until the year 2030 reaching 23.5% lower TCOs compared to the conventional diesel bus. The optimal electric bus charging system will be the opportunity (pantograph) charging infrastructure. However the opportunity charging method is applicable under the assumption that several buses share the same station and there is a “hotspot” where as many as possible bus lines converge. In the case of electric buses for the year 2020 the parameter which influenced the most on the TCO was the battery cost opposite to the year 2030 in where the bus body cost and fuel cost parameters are the ones that dominate the TCO due to the learning rate of the batteries. For H2 buses finding a hotspot is not crucial because they have a similar range to the diesel ones as well as a similar refueling time. H2 buses until 2030 still have 15.4% higher TCO than the diesel bus system. Considering the benefits of a hypothetical scaling-up effect of hydrogen infrastructures in the region the hydrogen cost could drop to 5 €/kg. In this case the overall TCO of the hydrogen solution would drop to a slightly lower TCO than the diesel solution in 2030. Therefore hydrogen buses can be competitive in small to midsize cities even with limited routes. For hydrogen buses the bus body and fuel cost make up a large part of the TCO. Reducing the fuel cost will be an important aspect to reduce the total TCO of the hydrogen bus.
Economic Evaluation of Low-carbon Steelmaking via Coupling of Electrolysis and Direct Reduction
Oct 2021
Publication
The transition from fossil-based primary steel production to a low-emission alternative has gained increasing attention in recent years. Various schemes including Carbon Capture and Utilization (CCU) and Carbon Direct Avoidance (CDA) via hydrogen-based as well as electrochemical routes have been proposed. With multiple technical analyses being available and technical feasibility being proven by first pilot plants pathways towards commercial market entry are of increasing interest. While multiple publications on the economic feasibility of CCU are available data on CDA approaches is scarce. In this work an economic model for the quantification of production cost as well as CO2 emission mitigation cost is presented. The approach is characterized by a seamless integration with a flowsheet-based process model of a direct reduction-based crude steel production plant detailed in a previous work and allows for the investigation of multiple economic aspects. Firstly the gradual transition from the natural gas-based state-of-the-art direct reduction towards a fossil-free hydrogen-based reduction is analyzed. Furthermore a comparison between the more mature technology of low-temperature electrolysis and a potentially more efficient solid oxide electrolysis (SOEL) is given highlighting the potential of SOEL technology. The conducted forecast to 2050 shows that SOEL-based CDA offers lower production cost when technological maturity is reached. Based on the results of the economic assessment possible legislative support mechanisms are studied showing that legislative actions are necessary to allow for market entry as well as for sustainable and economically feasible operation of fossil-free direct reduction plants.
A Critical Review of Polymer Electrolyte Membrane Fuel Cell Systems for Automotive Applications: Components, Materials, and Comparative Assessment
Mar 2023
Publication
The development of innovative technologies based on employing green energy carriers such as hydrogen is becoming high in demand especially in the automotive sector as a result of the challenges associated with sustainable mobility. In the present review a detailed overview of the entire hydrogen supply chain is proposed spanning from its production to storage and final use in cars. Notably the main focus is on Polymer Electrolyte Membrane Fuel Cells (PEMFC) as the fuel-cell type most typically used in fuel cell electric vehicles. The analysis also includes a cost assessment of the various systems involved; specifically the materials commonly employed to manufacture fuel cells stacks and hydrogen storage systems are considered emphasizing the strengths and weaknesses of the selected strategies together with assessing the solutions to current problems. Moreover as a sought-after parallelism a comparison is also proposed and discussed between traditional diesel or gasoline cars battery-powered electric cars and fuel cell electric cars thus highlighting the advantages and main drawbacks of the propulsion systems currently available on the market.
Hydrogen-Fuel Cell Hybrid Powertrain: Conceptual Layouts and Current Applications
Nov 2022
Publication
Transportation is one of the largest sources of CO2 emissions accounting for more than 20% of worldwide emissions. However it is one of the areas where decarbonization presents the greatest hurdles owing to its capillarity and the benefits that are associated with the use of fossil fuels in terms of energy density storage and transportation. In order to accomplish comprehensive decarbonization in the transport sector it will be required to encourage a genuine transition to low-carbon fuels and the widespread deployment of the necessary infrastructures to allow for a large-scale innovation. Renewable hydrogen shows potential for sustainable transportation applications whether in fuel cell electric vehicles (FCEVs) such as automobiles trucks and trains or as a raw material for ship and airplane synthetic fuels. The present paper aims to present how hydrogen-fuel cell hybrid powertrains for road vehicles work in terms of conceptual layouts and operating strategies. A comprehensive overview of real and current applications is presented concerning existing prototypes and commercially available vehicles with a focus on the main key performance indicators such as efficiency mileage and energy consumption.
Analysis and Design of Fuel Cell Systems for Aviation
Feb 2018
Publication
In this paper the design of fuel cells for the main energy supply of passenger transportation aircraft is discussed. Using a physical model of a fuel cell general design considerations are derived. Considering different possible design objectives the trade-off between power density and efficiency is discussed. A universal cost–benefit curve is derived to aid the design process. A weight factor wP is introduced which allows incorporating technical (e.g. system mass and efficiency) as well as non-technical design objectives (e.g. operating cost emission goals social acceptance or technology affinity political factors). The optimal fuel cell design is not determined by the characteristics of the fuel cell alone but also by the characteristics of the other system components. The fuel cell needs to be designed in the context of the whole energy system. This is demonstrated by combining the fuel cell model with simple and detailed design models of a liquid hydrogen tank. The presented methodology and models allows assessing the potential of fuel cell systems for mass reduction of future passenger aircraft.
A Review on CO2 Mitigation in the Iron and Steel Industry through Power to X Processes
Feb 2021
Publication
In this paper we present the first systematic review of Power to X processes applied to the iron and steel industry. These processes convert renewable electricity into valuable chemicals through an electrolysis stage that produces the final product or a necessary intermediate. We have classified them in five categories (Power to Iron Power to Hydrogen Power to Syngas Power to Methane and Power to Methanol) to compare the results of the different studies published so far gathering specific energy consumption electrolysis power capacity CO2 emissions and technology readiness level. We also present for the first time novel concepts that integrate oxy-fuel ironmaking and Power to Gas. Lastly we round the review off with a summary of the most important research projects on the topic including relevant data on the largest pilot facilities (2–6 MW).
Hydrogen-powered Aviation in Germany: A Macroeconomic Perspective and Methodological Approach of Fuel Supply Chain Integration into an Economy-wide Dataset
Oct 2022
Publication
The hydrogen (H2) momentum affects the aviation sector. However a macroeconomic consideration is currently missing. To address this research gap the paper derives a methodology for evaluating macroeconomic effects of H2 in aviation and applies this approach to Germany. Three goals are addressed: (1) Construction of a German macroeconomic database. (2) Translation of H2 supply chains to the system of national accounts. (3) Implementation of H2-powered aviation into the macroeconomic data framework. The article presents an economy-wide database for analyzing H2-powered aviation. Subsequently the paper highlights three H2 supply pathways provides an exemplary techno-economic cost break-down for ten H2 components and translates them into the data framework. Eight relevant macroeconomic sectors for H2-powered aviation are identified and quantified. Overall the paper contributes on a suitable foundation to apply the macroeconomic dataset to and conduct macroeconomic analyses on H2-powered aviation. Finally the article highlights further research potential on job effects related to future H2 demand.
Propulsion System Integration for a First-generation Hydrogen Civil Airliner?
May 2021
Publication
An unusual philosophical approach is proposed here to decarbonise larger civil aircraft that fly long ranges and consume a large fraction of civil aviation fuel. These inject an important amount of carbon emissions into the atmosphere and holistic decarbonising solutions must consider this sector. A philosophical–analytical investigation is reported here on the feasibility of an airliner family to fly over long ranges and assist in the elimination of carbon dioxide emissions from civil aviation. Backed by state-of-the-art correlations and engine performance integration analytical tools a family of large airliners is proposed based on the development and integration of the body of a very large two-deck four-engine airliner with the engines wings and flight control surfaces of a very long-range twin widebody jet. The proposal is for a derivative design and not a retrofit. This derivative design may enable a swifter entry to service. The main contribution of this study is a philosophical one: a carefully evaluated aircraft family that appears to have very good potential for first-generation hydrogen-fuelled airliners using gas turbine engines for propulsion. This family offers three variants: a 380-passenger aircraft with a range of 3300nm a 330-passenger aircraft with a range of 4800nm and a 230- passenger aircraft with a range of 5500nm. The latter range is crucially important because it permits travel from anywhere in the globe to anywhere else with only one stop. The jet engine of choice is a 450kN high-bypass turbofan.
Centralized and Decentralized Electrolysis-based Hydrogen Supply Systems for Road Transportation - A Modeling Study of Current and Future Costs
Oct 2022
Publication
This work compares the costs of three electrolysis-based hydrogen supply systems for heavy road transportation: a decentralized off-grid system for hydrogen production from wind and solar power (Dec-Sa); a decentralized system connected to the electricity grid (Dec-Gc); and a centralized grid-connected electrolyzer with hydrogen transported to refueling stations (Cen-Gc). A cost-minimizing optimization model was developed in which the hydrogen production is designed to meet the demand at refueling stations at the lowest total cost for two timeframes: one with current electricity prices and one with estimated future prices. The results show that: For most of the studied geographical regions Dec-Gc gives the lowest costs of hydrogen delivery (2.2e3.3V/kgH2) while Dec-Sa entails higher hydrogen production costs (2.5e6.7V/kgH2). In addition the centralized system (Cen-Gc) involves lower costs for production and storage than the grid-connected decentralized system (Dec-Gc) although the additional costs for hydrogen transport increase the total cost (3.5e4.8V/kgH2).
Environmental Economical Dispatching of Electric–Gas Integrated Energy System Considering Hydrogen Compressed-Natural Gas
Dec 2022
Publication
As a high-quality secondary energy hydrogen energy has great potential in energy storage and utilization. The development of power-to-hydrogen (P2H) technology has alleviated the problem of wind curtailment and improved the coupling between the power grid and the natural gas grid. Under the premise of ensuring safety using P2H technology to mix the produced hydrogen into the natural gas network for long-distance transmission and power generation can not only promote the development of hydrogen energy but also reduce carbon emissions. This paper presents a new model for incorporating hydrogen into natural gas pipelines. To minimize the sum of wind curtailment cost operation cost and carbon emission cost an electric–gas integrated energy system (EGIES) model of hydrogen-compressed natural gas (HCNG) containing P2H for power generation is constructed. Aiming at the problem of global warming caused by a lot of abandoned wind and carbon emissions the economy and environmental protection of the system model are analyzed. The results show that the model of EGIES considering HCNG can not only absorb excess wind power but also reduce carbon emission costs and system costs which can reduce the total cost of the environmental economic dispatch of the EGIES by about 34.1%. In the context of the EGIES the proposal of this model is of great significance to the economical and environmentally friendly operation of the system.
Hydrogenerally - Episode 7: Hydrogen for Heat
Dec 2022
Publication
In this seventh episode Steffan Eldred Hydrogen Innovation Network Knowledge Transfer Manager and Jenni McDonnell MBE Heating and Cooling Knowledge Transfer Manager from Innovate UK KTN discuss why using hydrogen to generate heat is so important and explore the hydrogen economy opportunities and challenges within this sector alongside their special guest Jeff House Head of External Affairs Baxi Boilers.
The podcast can be found on their website.
The podcast can be found on their website.
Hydrogen Fuel Cells for Sustainable Energy: Development and Progress in Selected Developed Countries
Jan 2021
Publication
The sustainable development goals concept towards zero carbon emission set forth by the Paris Agreement is the foundation of decarbonisation implemented in most developed countries worldwide. One of the efforts in the decarbonisation of the environment is through hydrogen fuel cell technology. A fuel cell is an energy converter device that produces electricity via the electrochemical reaction with water as the by-product. The application of fuel cells is strongly related to the economic aspect including local and infrastructure costs making it more relevant to be implemented in a developed country. This work presents a short review of the development and progress of hydrogen fuel cells in a developed country such as Japan Germany USA Denmark and China (in transition between developing to developed status); which championed hydrogen fuel cell technology in their region.
Prioritization and Optimal Location of Hydrogen Fueling Stations in Seoul: Using Multi-Standard Decision-Making and ILP Optimization
Mar 2023
Publication
Thus far the adoption of hydrogen fuel cell vehicles (HCEVs) has been hampered by the lack of hydrogen fueling infrastructure. This study aimed to determine the optimal location and prioritization of hydrogen fueling stations (HFSs) in Seoul by utilizing a multi-standard decision making approach and optimization method. HFS candidate sites were evaluated with respect to relevant laws and regulations. Key factors such as safety economy convenience and demand for HCEVs were considered. Data were obtained through a survey of experts in the fields of HCEV and fuel cells and the Analytic Hierarchy Process method was applied to prioritize candidate sites. The optimal quantity and placement of HFSs was then obtained using optimization software based on the acceptable travel time from intersections of popular roads in Seoul. Our findings suggest that compliance with legal safety regulations is the most important factor when constructing HFSs. Furthermore sensitivity analysis revealed that the hydrogen supply cost currently holds the same weight as other elements. The study highlights the importance of utilizing a multi-standard decision-making approach and optimization methods when determining the optimal location and prioritization of HFSs and can help develop a systematic plan for the nationwide construction of HFSs in South Korea.
Design and Optimization of Coal to Hydrogen System Coupled with Non-Nominal Operation of Thermal Power Unit
Dec 2022
Publication
In an actual thermal power plant deep peak shaving will cause thermal power units to run under non-nominal conditions for an extended period resulting in serious problems such as increased equipment wearing low equipment utilization efficiency and decreased benefits. To this end in this work both the design and optimization method for a coal to hydrogen system which is coupled with the expected non-nominal operation of thermal power units are proposed. Aiming towards maximum profit in the context of thermal power plants a mathematical optimization model for a coal to hydrogen system based on the multi-period operating conditions of thermal power plants is established. The corresponding optimal design scheme of the coal to hydrogen system is determined using variable operating conditions. The superiority of the integrated system compared with an independent system is explored and the feasibility of the proposed method is verified by using the case study of an actual thermal power plant. The results show that compared with the independent system the economic benefits of the integrated system can increase by 13.56% where the sale of hydrogen in the coal to hydrogen system accounts for 60.3% of the total benefit. The main expenditure associated with the system is the purchase cost of feedstock coal accounting for 91.8%. Since the required power and medium-pressure steam in the coal to hydrogen process are provided by thermal power units the minimum operating load of the thermal power plant in the integrated system increases from 40% to 60.1% which significantly improves the utilization efficiency and service life of the generator units. In addition the proposed integration scheme of the system is simple and controllable which can contribute to the maintenance of the safe and stable operation of power generation and hydrogen production processes. These results are expected to provide the necessary methodological guidance for the integration and optimization of coal-fired power plants and coal to hydrogen systems.
Renewable Energy Transport via Hydrogen Pipelines and HVDC Transmission Lines
May 2021
Publication
The majority penetration of Variable Renewable Energy (VRE) will challenge the stability of electrical transmission grids due to unpredictable peaks and troughs of VRE generation. With renewable generation located further from high demand urban cores there will be a need to develop new transmission pathways to deliver the power. This paper compares the transport and storage of VRE through a hydrogen pipeline to the transport of VRE through a High Voltage Direct Current (HVDC) transmission line. The analysis found a hydrogen pipeline can offer a cost-competitive method for VRE transmission compared to a HVDC transmission line on a life-cycle cost basis normalized by energy flows for distances at 1000 miles with 2030 technology. This finding has implications for policy makers project developers and system operators for the future development of transmission infrastructure projects given the additionality which hydrogen pipelines can provide in terms of energy storage.
Life Cycle Greenhouse Gas Emission Assessment for Using Alternative Marine Fuels: A Very Large Crude Carrier (VLCC) Case Study
Dec 2022
Publication
The International Maritime Organization (IMO) has set decarbonisation goals for the shipping industry. As a result shipowners and operators are preparing to use low- or zero-carbon alternative fuels. The greenhouse gas (GHG) emission performances are fundamental for choosing suitable marine fuels. However the current regulations adopt tank-to-wake (TTW) emission assessment methods that could misrepresent the total climate impacts of fuels. To better understand the well-to-wake (WTW) GHG emission performances this work applied the life cycle assessment (LCA) method to a very large crude carrier (VLCC) sailing between the Middle East and China to investigate the emissions. The life cycle GHG emission impacts of using alternative fuels including liquified natural gas (LNG) methanol and ammonia were evaluated and compared with using marine gas oil (MGO). The bunkering site of the VLCC was in Zhoushan port China. The MGO and LNG were imported from overseas while methanol and ammonia were produced in China. Four production pathways for methanol and three production pathways for ammonia were examined. The results showed that compared with MGO using fossil energy-based methanol and ammonia has no positive effect in terms of annual WTW GHG emissions. The emission reduction effects of fuels ranking from highest to lowest were full solar and battery-based methanol full solar and battery-based ammonia and LNG. Because marine ammonia-fuelled engines have not been commercialised laboratory data were used to evaluate the nitrous oxide (N2O) emissions. The GHG emission reduction potential of ammonia can be exploited more effectively if the N2O emitted from engines is captured and disposed of through after-treatment technologies. This paper discussed three scenarios of N2O emission abatement ratios of 30% 50% and 90%. The resulting emission reduction effects showed that using full solar and battery-based ammonia with 90% N2O abatement performs better than using full solar and battery-based methanol. The main innovation of this work is realising the LCA GHG emission assessment for a deep-sea ship.
Optimal Design of a Hydrogen-powered Fuel Cell System for Aircraft Applications
Mar 2024
Publication
Recently hydrogen and fuel cells have gained interest as an emerging technology to mitigate the effects of climate change caused by the aviation sector. The aim of this work is to evaluate the applicability of this technology to an existing regional aircraft in order to assess its electrification with the aim of reducing greenhouse gas emissions and achieving sustainability goals. The design of a proton-exchange membrane fuel cell system (PEMFC) with the inclusion of liquid hydrogen storage is carried out. Specifically a general mathematical model is developed which involves multiple scales ranging from individual cells to aircraft scale. First the fuel cell electrochemical model is developed and validated against published polarization curves. Then different sizing approaches are used to compute the overall weight of the hydrogen-based propulsion system in order to optimize the system and minimize its weight. Crucially this work underscores that the feasibility of hydrogenbased fuel cell systems relies not only on hydrogen storage but especially on the electrochemical cell performance which influences the size of the balance of plant and especially its thermal management section. In particular the strategic significance of working with fuel cells at partial loads is demonstrated. This entails achieving an optimal balance between the stacks oversizing and the weights of both hydrogen storage and balance of plant thereby minimizing the overall weight of the system. It is thus shown that an integrated approach is imperative to guide progress towards efficient and implementable hydrogen technology in regional aviation. Furthermore a high-performance PEMFC is analyzed resulting in an overall weight reduction up to nearly 10% compared to the baseline case study. In this way it is demonstrated as technological advancements in PEMFCs can offer further prospects for improving system efficiency.
Everything About Hydrogen Podcast: Plotting the Course for a Decarbonized Global Maritime Industry
Jan 2023
Publication
On this episode of EAH we sat down with Dr. Bo Cerup-Simonsen Chief Executive Officer of the Maersk Mc-Kinney Møller Center for Zero Carbon Shipping. Bo holds a PHD in Naval Architecture and Mechanical Engineering and spent seven years as a research engineer at MIT.
Bo explains the Center's work and we discuss decarbonization of shipping using hydrogen derived green fuels.
The podcast can be found on their website.
Bo explains the Center's work and we discuss decarbonization of shipping using hydrogen derived green fuels.
The podcast can be found on their website.
Hydrogenerally - Episode 8: Hydrogen for Combustion
Jan 2023
Publication
In this episode Steffan Eldred Hydrogen Knowledge Transfer Manager and Debra Jones Chemistry Knowledge Transfer Manager from Innovate UK KTN talk about hydrogen combustion with special guest Duncan Engeham European Research and Development Director at Cummins Inc.
The podcast can be found on their website.
The podcast can be found on their website.
New Control Strategy for Heating Portable Fuel Cell Power Systems for Energy-Efficient and Reliable Operation
Dec 2022
Publication
Using hydrogen fuel cells for power systems temperature conditions are important for efficient and reliable operations especially in low-temperature environments. A heating system with an electrical energy buffer is therefore required for reliable operation. There is a research gap in finding an appropriate control strategy regarding energy efficiency and reliable operations for different environmental conditions. This paper investigates heating strategies for the subfreezing start of a fuel cell for portable applications at an early development stage to enable frontloading in product engineering. The strategies were investigated by simulation and experiment. A prototype for such a system was built and tested for subfreezing start-ups and non-subfreezing start-ups. This was done by heating the fuel cell system with different control strategies to test their efficiency. It was found that operating strategies to heat up the fuel cell system can ensure a more reliable and energy efficient operation. The heating strategy needs to be adjusted according to the ambient conditions as this influences the required heating energy efficiency and reliable operation of the system. A differentiation in the control strategy between subfreezing and non-subfreezing temperatures is recommended due to reliability reasons.
Performance Evaluation of a Hydrogen-fired Combined Cycle with Water Recovery
Mar 2023
Publication
Hydrogen can alleviate the increasing environmental pollution and has good development prospects in power generation due to its high calorific value and low environmental impact. The previously designed hydrogen-fired combined cycle ignored water recycling which led to an inefficient application of hydrogen and the wastage of water. This paper proposes the concept of a hydrogen-fired combined cycle with water recovery to reuse the condensed water as an industrial heat supply. It was applied to an F-class combined cycle power plant. The results demonstrate that the efficiency of hydrogen-fired combined cycles with and without water recovery increased by 1.92% and 1.35% respectively compared to that of the natural-gas-fired combined cycle under full working conditions. In addition an economic comparison of the three cycles was conducted. The levelized cost of energy of the hydrogen-fired combined cycle with water recovery will be 52.22% lower than that of the natural-gas-fired combined cycle in 2050. This comparative study suggested that water recovery supplementation could improve the gas turbine efficiency. The proposed hydrogen-fired combined cycle with water recovery would provide both environmental and economic benefits.
Green Steel: Synergies between the Australian Iron Ore Industry and the Production of Green Industry
May 2023
Publication
Green steel produced using renewable energy and hydrogen presents a promising avenue to decarbonize steel manufacturing and expand the hydrogen industry. Australia endowed with abundant renewable resources and iron ore deposits is ideally placed to support this global effort. This paper's two-step analytical approach offers the first comprehensive assessment of Australia's potential to develop green steel as a value-added export commodity. The Economic Fairways modelling reveals a strong alignment between prospective hydrogen hubs and current and future iron ore operations enabling shared infrastructure development and first-mover advantages. By employing a site-based system optimization that integrates both wind and solar power sources the cost of producing green steel could decrease significantly to around AU$900 per tonne by 2030 and AU$750 per tonne by 2050. Moreover replacing 1% of global steel production would require 35 GW of well-optimized wind and solar photovoltaics 11 GW of hydrogen electrolysers and 1000 square kilometres of land. Sensitivity analysis further indicates that iron ore prices would exert a long-term influence on green steel prices. Overall this study highlights the opportunities and challenges facing the Australian iron ore industry in contributing to the decarbonization of the global steel sector underscoring the crucial role of government support in driving the growth and development of the green steel industry.
Evaluation of the Potential for Distributed Generation of Green Hydrogen Using Metal-hydride Storage Methods
May 2023
Publication
This study presents methodology for the evaluation of appropriateness of a hydrogen generator for gas production in multiple distributed plants based on renewable energy sources. The general idea is to form hydrogen clusters integrated with storage and transportation. The paper focuses on the financial viability of the plants presenting the results of economic evaluation together with sensitivity analysis for various economic factors. The analyzed case study proves that over a wide range of parameters alkaline electrolyzers show favorable economic characteristics however a PEM-based plant is more resilient to changes in the price of electricity which is the main cost component in hydrogen generation. The study is enriched with an experimental investigation of low-pressure storage methods based on porous metal hydride tanks. The effectiveness of the tanks (β) compared to pressurized hydrogen tanks in the same volume and pressure is equal to β = 10.2. A solution is proposed whereby these can be used in a distributed hydrogen generation concept due to their safe and simple operation without additional costly equipment e.g. compressors. A method for evaluation of the avoided energy consumption as a function of the effectiveness of the tanks is developed. Avoided energy consumption resulting from implementing MH tanks equals 1.33 – 1.37 kWh per kilogram of hydrogen depending on the number of stages of a compressor. The methods proposed in this paper are universal and can be used for various green hydrogen facilities.
Comparative Study of Spark-Ignited and Pre-Chamber Hydrogen-Fueled Engine: A Computational Approach
Nov 2022
Publication
Hydrogen is a promising future fuel to enable the transition of transportation sector toward carbon neutrality. The direct utilization of H2 in internal combustion engines (ICEs) faces three major challenges: high NOx emissions severe pressure rise rates and pre-ignition at mid to high loads. In this study the potential of H2 combustion in a truck-size engine operated in spark ignition (SI) and pre-chamber (PC) mode was investigated. To mitigate the high pressure rise rate with the SI configuration the effects of three primary parameters on the engine combustion performance and NOx emissions were evaluated including the compression ratio (CR) the air–fuel ratio and the spark timing. In the simulations the severity of the pressure rise was evaluated based on the maximum pressure rise rate (MPRR). Lower compression ratios were assessed as a means to mitigate the auto-ignition while enabling a wider range of engine operation. The study showed that by lowering CR from 16.5:1 to 12.5:1 an indicated thermal efficiency of 47.5% can be achieved at 9.4 bar indicated mean effective pressure (IMEP) conditions. Aiming to restrain the auto-ignition while maintaining good efficiency growth in λ was examined under different CRs. The simulated data suggested that higher CRs require a higher λ and due to practical limitations of the boosting system λ at 4.0 was set as the limit. At a fixed spark timing using a CR of 13.5 combined with λ at 3.33 resulted in an indicated thermal efficiency of 48.6%. It was found that under such lean conditions the exhaust losses were high. Thus advancing the spark time was assessed as a possible solution. The results demonstrated the advantages of advancing the spark time where an indicated thermal efficiency exceeding 50% was achieved while maintaining a very low NOx level. Finally the optimized case in the SI mode was used to investigate the effect of using the PC. For the current design of the PC the results indicated that even though the mixture is lean the flame speed of H2 is sufficiently high to burn the lean charge without using a PC. In addition the PC design used in the current work induced a high MPRR inside the PC and MC leading to an increased tendency to engine knock. The operation with PC also increased the heat transfer losses in the MC leading to lower thermal efficiency compared to the SI mode. Consequently the PC combustion mode needs further optimizations to be employed in hydrogen engine applications.
Assessment of Paper Industry Decarbonization Potential via Hydrogen in a Multi-energy System Scenario: A Case Study
Jul 2023
Publication
Green hydrogen is currently regarded as a key catalyst for the decarbonization of energy-intensive industries. In this context the pulp and paper industry stands out as one of the most demanding given the simultaneous need for large amounts of heat and electricity usually satisfied via cogeneration systems. Given the urgent need for cost-effective solutions in response to the climate crisis it is crucial to analyze the feasibility of retrofitting existing power plants to operate carbon-neutral. The aim of this work is to provide a techno-economic analysis for the conversion of a conventional cogeneration system to run on locally produced hydrogen. Building on the energy consumption of the paper mill the operation of a hydrogen-fuelled gas turbine is modelled in detail. Based on these results a multi-energy system model for the production of green fuel is presented considering production via solar-powered PEM electrolyzers storage in tanks and final use in the gas turbine. An optimal configuration for the system is defined leading to the definition of a solution that ensures a cost of 6.41 /kg for the production of green hydrogen. Finally a sensitivity analysis highlights the close dependence of the economic profitability of the Power-to-X system on the natural gas price. The results indicate that although positive performance is achieved the cost of investment remains still prohibitive for systems of this size and the high initial capital expenditure needs to be supported by incentive policies that facilitate the adoption of hydrogen in industrial applications making it competitive in the short term.
Multi-Objective Optimization-Based Health-Conscious Predictive Energy Management Strategy for Fuel Cell Hybrid Electric Vehicles
Feb 2022
Publication
The Energy Management Strategy (EMS) in Fuel Cell Hybrid Electric Vehicles (FCHEVs) is the key part to enhance optimal power distribution. Indeed the most recent works are focusing on optimizing hydrogen consumption without taking into consideration the degradation of embedded energy sources. In order to overcome this lack of knowledge this paper describes a new health-conscious EMS algorithm based on Model Predictive Control (MPC) which aims to minimize the battery degradation to extend its lifetime. In this proposed algorithm the health-conscious EMS is normalized in order to address its multi-objective optimization. Then weighting factors are assigned in the objective function to minimize the selected criteria. Compared to most EMSs based on optimization techniques this proposed approach does not require any information about the speed profile which allows it to be used for real-time control of FCHEV. The achieved simulation results show that the proposed approach reduces the economic cost up to 50% for some speed profile keeping the battery pack in a safe range and significantly reducing energy sources degradation. The proposed health-conscious EMS has been validated experimentally and its online operation ability clearly highlighted on a PEMFC delivery postal vehicle.
Fueling Tomorrow's Commute: Current Status and Prospects of Public Bus Transit Fleets Powered by Sustainable Hydrogen
Apr 2024
Publication
Transportation is an economic sector that contributes significantly to global warming due to its high consumption of fossil fuels and sustainably produced hydrogen is a major contender for an alternative clean energy source. Public transit is vital for environmental sustainability via reducing individual vehicle usage and traffic congestion and the prospect of powering buses using hydrogen fuel has been extensively studied lately. This paper seeks to comprehensively review the current status of research on hydrogen-powered buses considering triple bottom line sustainability perspectives. A brief technical overview of prospective environmentally benign hydrogen production processes has been presented. Technological economic and environmental findings and research trends seen in recent analyses on hydrogen-powered buses have been summarized along with the status quo of global hydrogen refuelling stations. Identified focal points for future studies include performance enhancements refuelling infrastructure propagation and policy formulation. The conclusions derived from this review will benefit the accelerated deployment of hydrogen-fuelled public transit fleets.
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