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Life-Cycle Greenhouse Gas Emissions Of Biomethane And Hydrogen Pathways In The European Union
Oct 2021
Publication
Gaseous fuels with low life-cycle emissions of greenhouse gases (GHG) play a prominent role in the European Union’s (EU) decarbonization plans. Renewable and low-GHG hydrogen are highlighted in the ambitious goals for a cross-sector hydrogen economy laid out in the European Commission’s Hydrogen Strategy. Renewable hydrogen and biomethane are given strong production incentives in the Commission’s proposed revision to the Renewable Energy Directive (REDII). The EU uses life-cycle analysis (LCA) to determine whether renewable gas pathways meet the GHG reduction thresholds for eligibility in the REDII. This study aims to support European policymakers with a better understanding of the uncertainties regarding gaseous fuels’ roles in meeting climate goals. Life-cycle GHG analysis is complex and differences in methodology as well as data inputs and assumptions can spell the difference between a renewable gas pathway qualifying or not for REDII eligibility at the 50% to 80% GHG reduction level. It is thus important for European policymakers to use robust LCA to ensure that policy only supports gas pathways consistent with a vision of deep decarbonization. For this purpose we conduct sensitivity analysis of the life-cycle GHG emissions of a number of low-GHG gas pathways including biomethane produced from four feedstocks: wastewater sludge manure landfill gas (LFG) and silage maize; and hydrogen produced from eight sources: natural gas combined with carbon capture and storage (CCS) coal with CCS biomass gasification renewable electricity 2030 EU grid electricity wastewater sludge biomethane manure biomethane and LFG biomethane. For each pathway we estimate the life-cycle GHG intensity using a default central case identify key parameters that strongly affect the fuel’s GHG intensity and conduct a sensitivity analysis by changing these key parameters according to the range of possible values collected from the literature. Figure ES1 summarizes the full range of possible GHG intensities for each gaseous pathway we analyzed in this study—biomethane is depicted in the top figure and hydrogen is shown in the bottom. The bars represent the GHG intensity of the central case and vertical error bars indicate the maximum and minimum GHG intensity of each pathway according to our sensitivity analysis. The dotted orange horizontal line illustrates the fossil comparator which is 94 grams of carbon dioxide equivalent per megajoule (gCO2e/MJ) for transport fuels in the REDII. The dotted yellow line represents the GHG intensity of a 65% GHG reduction goal for biomethane used in the transportation sector or 70% GHG reduction for hydrogen. Pathways are situated from left to right in increasing order of GHG intensity of the central case. Comparing the central cases of the four biomethane pathways the waste-based biomethane pathways generally have negative GHG intensity. However considering the uncertainty in these GHG intensities manure biomethane might have more limited carbon reduction potential in the 100-year timeframe if methane leakage from its production process is high. In contrast wastewater sludge biomethane and LFG biomethane even after accounting for uncertainties retain relatively low GHG emissions. On the other hand biomethane produced from silage maize can have much higher emissions; in the central case we find that silage maize biogas only reduces GHG emissions by 30% relative to the fossil comparator—the low carbon reduction potential is due to the significant emissions emerging from direct and indirect land use change involved in growing maize. Taking into account the variation in assumptions silage maize biomethane can be worse for the climate than fossil fuels.
Hydrogen Energy: a New Dimension for the Energy Cooperation in the Northeast Asian Region
Nov 2020
Publication
The Northeast Asian Region is a home for the major world’s energy importers and Russia – the top energy exporter. Due to the depletion of national fossil energy resources the industrialised East Asian economies are facing serious energy security issues. The snapshot of the intraregional energy trade in 2019 was analysed in terms of development potential. Japan Korea and China are at the frontline of hydrogen energy technologies commercialisation and hydrogen energy infrastructure development. The drivers for such endeavours are listed and national institutions for hydrogen energy development are characterised. The priorities related to regional cooperation on hydrogen energy in Northeast Asia were derived on the basis of hydrogen production cost estimations. These priorities include steady development of international natural gas and power infrastructure. The shared process will lead to the synergy of regional fossil and renewable resources within combined power and hydrogen infrastructure.
An Overview of Economic Analysis and Environmental Impacts of Natural Gas Conversion Technologies
Dec 2020
Publication
This study presents an overview of the economic analysis and environmental impact of natural gas conversion technologies. Published articles related to economic analysis and environmental impact of natural gas conversion technologies were reviewed and discussed. The economic analysis revealed that the capital and the operating expenditure of each of the conversion process is strongly dependent on the sophistication of the technical designs. The emerging technologies are yet to be economically viable compared to the well-established steam reforming process. However appropriate design modifications could significantly reduce the operating expenditure and enhance the economic feasibility of the process. The environmental analysis revealed that emerging technologies such as carbon dioxide (CO2) reforming and the thermal decomposition of natural gas offer advantages of lower CO2 emissions and total environmental impact compared to the well-established steam reforming process. Appropriate design modifications such as steam reforming with carbon capture storage and utilization the use of an optimized catalyst in thermal decomposition and the use of solar concentrators for heating instead of fossil fuel were found to significantly reduced the CO2 emissions of the processes. There was a dearth of literature on the economic analysis and environmental impact of photocatalytic and biochemical conversion processes which calls for increased research attention that could facilitate a comparative analysis with the thermochemical processes.
Significance of Hydrogen as Economic and Environmentally Friendly Fuel
Nov 2021
Publication
The major demand of energy in today’s world is fulfilled by the fossil fuels which are not renewable in nature and can no longer be used once exhausted. In the beginning of the 21st century the limitation of the fossil fuels continually growing energy demand and growing impact of greenhouse gas emissions on the environment were identified as the major challenges with current energy infrastructure all over the world. The energy obtained from fossil fuel is cheap due to its established infrastructure; however these possess serious issues as mentioned above and cause bad environmental impact. Therefore renewable energy resources are looked to as contenders which may fulfil most energy requirements. Among them hydrogen is considered as the most environmentally friendly fuel. Hydrogen is clean sustainable fuel and it has promise as a future energy carrier. It also has the ability to substitute the present energy infrastructure which is based on fossil fuel. This is seen and projected as a solution for the above-mentioned problems including rise in global temperature and environmental degradation. Environmental and economic aspects are the important factors to be considered to establish hydrogen infrastructure. This article describes the various aspects of hydrogen including production storage and applications with a focus on fuel cell based electric vehicles. Their environmental as well as economic aspects are also discussed herein.
Experimental Study on the Cycle Variation Characteristics of Direct Injection Hydrogen Engine
Jun 2022
Publication
Hydrogen energy is an important technical route to achieve carbon peak and carbon neutrality. Direct injection hydrogen engine is one of the ways of hydrogen energy application. It has the advantages of high thermal efficiency and limit/reduce abnormal combustion phenomena. In order to explore the cycle characteristics of direct injection hydrogen engine based on a 2.0L direct injection hydrogen engine an experimental study on the cycle characteristics of direct injection hydrogen engine was carried out. The experimental results show that cycle variation increases from 0.67% to 1.02% with the increasing of engine speed. The cycle variation decreases from 1.52% to 0.64% with the increasing of engine load. As the equivalence ratio increases the cycle variation first decreases significantly from 2.52% to 0.35% and then stabilizes. The ignition advance angle has a better angle to minimize the cycle variation. An experimental study on the influence of the start of injection on the cycle variation was carried out. As the engine speed/engine load is 2000rpm/4bar the cycle variation increases from 0.72% to 2.42% with the start of injection changing from -280°CA to -180°CA; then rapidly decreases to 0.99% and then increases to 2.26% with the start of injection changing from -180°CA to -100°CA. The experimental results show that SOI could cause significant influence on cycle variation because of intake valve closing and shortening mixing time and both the process of intake valve closing and lagging the SOI could cause the cycle variation to increase. The SOI remarkably affects the cycle variation at low engine load/equivalence ratio and high engine speed. This study lays the foundation for the follow-up research of hydrogen engine performance matching of the cycle variation.
Recent Developments on Hydrogen Production Technologies: State-of-the-Art Review with a Focus on Green-Electrolysis
Dec 2021
Publication
Growing human activity has led to a critical rise in global energy consumption; since the current main sources of energy production are still fossil fuels this is an industry linked to the generation of harmful byproducts that contribute to environmental deterioration and climate change. One pivotal element with the potential to take over fossil fuels as a global energy vector is renewable hydrogen; but for this to happen reliable solutions must be developed for its carbon-free production. The objective of this study was to perform a comprehensive review on several hydrogen production technologies mainly focusing on water splitting by green-electrolysis integrated on hydrogen’s value chain. The review further deepened into three leading electrolysis methods depending on the type of electrolyzer used—alkaline proton-exchange membrane and solid oxide—assessing their characteristics advantages and disadvantages. Based on the conclusions of this study further developments in applications like the efficient production of renewable hydrogen will require the consideration of other types of electrolysis (like microbial cells) other sets of materials such as in anion-exchange membrane water electrolysis and even the use of artificial intelligence and neural networks to help design plan and control the operation of these new types of systems.
The Effects of Perceived Barriers on Innovation Resistance of Hydrogen-Electric Motorcycles
Jun 2018
Publication
As environmental awareness among the public gradually improves it is predicted that the trend of green consumption will make green products enter the mainstream market. Hydrogen-electric motorcycles with eco-friendly and energy-efficient characteristics have great advantages for development. However as a type of innovative product hydrogen-electric motorcycles require further examination with regard to consumer acceptance and external variables of the products. In this study consumer behavioral intention (BI) for the use of hydrogen-electric motorcycles and its influencing factors are discussed using innovation resistance as the basis and environmental concern as the adjusting variable. Consumers’ willingness-to-pay (WTP) for hydrogen-electric motorcycles is estimated using the contingent valuation method (CVM). The results found that (1) perception barriers viz. usage barrier value barrier risk barrier tradition barrier and price barrier are statistically significant whereas image barrier is not; (2) a high degree of environmental concern will reduce the consumers’ innovation resistance to the hydrogen-electric motorcycles; (3) up to 94.79% of the respondents of the designed questionnaire suggested that the promotion of hydrogen-electric motorcycles requires a subsidy of 21.9% of the total price from the government. The mean WTP of consumers for the purchase of hydrogen-electric motorcycles is 10–15% higher than that of traditional motorcycles.
Socio-technical Barriers to Domestic Hydrogen Futures: Repurposing Pipelines, Policies, and Public Perceptions
Feb 2023
Publication
The feasibility of the global energy transition may rest on the ability of nations to harness hydrogen's potential for cross-sectoral decarbonization. In countries historically reliant on natural gas for domestic heating and cooking such as the UK hydrogen may prove critical to meeting net-zero targets and strengthening energy security. In response the UK government is targeting industrial decarbonization via hydrogen with parallel interest in deploying hydrogen-fueled appliances for businesses and homes. However prospective hydrogen futures and especially the domestic hydrogen transition face multiple barriers which reflect the cross-sectoral dynamics of achieving economies of scale and social acceptance. Addressing these challenges calls for a deep understanding of socio-technical factors across different scales of the hydrogen economy. In response this paper develops a socio-technical systems framework for overcoming barriers to the domestic transition which is applied to the UK context. The paper demonstrates that future strategies should account for interactions between political techno-economic technical market and social dimensions of the hydrogen transition. In parallel to techno-economic feasibility the right policies will be needed to create an even playing field for green hydrogen technologies while also supporting stakeholder symbiosis and consumer buy-in. Future studies should grapple with how an effective repurposing of pipelines policies and public perceptions can be aligned to accelerate the development of the hydrogen economy with maximum net benefits for society and the environment.
Hydrogen Europe Podcast: The Commision's Support to the Hydrogen Ecosystem
Jul 2022
Publication
In this episode titled "The Commission's support to the hydrogen ecosystem" our CEO Jorgo Chatzimarkakis discusses with Rosalinde van der Vlies Clean Planet Director DG RTD - European Commission. Starting off on how Rosalinde joined the Commission the two speakers discuss the Commission's support in developing a hydrogen ecosystem also in light of its participation in the Clean Hydrogen Partnership and the implications arising from the REPowerEU.
Blowout Prediction on a Salt Cavern Selected for a Hydrogen Storage Pilot
Oct 2022
Publication
To prevent climate change Europe and the world must shift to low-carbon and renewable energies. Hydrogen as an energy vector provides viable solutions for replacing polluting and carbon-emitting fossil fuels. Gaseous hydrogen can be stored underground and coupled with existing natural gas pipe networks. Salt cavern storage is the best suited technology to meet the challenges of new energy systems. Hydrogen storage caverns are currently operated in the UK and Texas. A preliminary risk analysis dedicated to underground hydrogen salt caverns highlighted the importance of containment losses (leaks) and the formation of gas clouds following blowouts whose ignition may generate dangerous phenomena such as jet fires unconfined vapor cloud explosions (UVCEs) or flashfires. A blowout is not a frequent accident in gas storage caverns. A safety valve is often set at a 30 m depth below ground level; it is automatically triggered following a pressure drop at the wellhead. Nevertheless a blowout remains to be one of the significant accidental scenarios likely to occur during hydrogen underground storage in salt caverns. In this paper we present modelling the subterraneous and aerial parts of a blowout on an EZ53 salt cavern fully filled with hydrogen.
Estimation of the Influence of Compressed Hydrogen on the Mechanical Properties of Pipeline Steels
Sep 2021
Publication
Consideration of the possibility of transporting compressed hydrogen through existing gas pipelines leads to the need to study the regularities of the effect of hydrogen on the mechanical properties of steels in relation to the conditions of their operation in pipelines (operating pressure range stress state of the pipe metal etc.). This article provides an overview of the types of influence of hydrogen on the mechanical properties of steels including those used for the manufacture of pipelines. The effect of elastic and plastic deformations on the intensity of hydrogen saturation of steels and changes in their strength and plastic deformations is analyzed. An assessment of the potential losses of transported hydrogen through the pipeline wall as a result of diffusion has been made. The main issues that need to be solved for the development of a scientifically grounded conclusion on the possibility of using existing gas pipelines for the transportation of compressed hydrogen are outlined.
NewGasMet - Flow Metering of Renewable Gases (Biogas, Biomethane, Hydrogen, Syngas and Mixtures with Natural Gas): Report on the Usable Technologies for Calibrating Gas Meters with Renewable Gases and Currently Available Flow Standards Suitable for Use with Methane, Crude Biogas, Hydrogen and Mixtures of these gases
Mar 2021
Publication
The main goal stated at the Paris agreement is to limit the global temperature rise well below 2 °C above pre-industrial levels. Limiting the increase of global average temperature to 1.5 °C is striven since risks and impacts of the climate change would be reduced drastically. To face these challenges the European Green Deal was invented by the European Commission. The “Green Deal” is a growth strategy which aims to transform the economy of the EU into a resource-efficient modern and competitive one [1-1 1-2]. Figure 1: The key elements of the European Green Deal [1-2] In this context the European Commission proposed that the amount of renewable energy within the EU’s overall energy mix should reach 20 % by 2020 and therefore producing energy by solar and wind plants become even more important. For example the cumulative installed wind farm capacity increased from 117.3 GW in 2013 to a total capacity of 182.163 GW in 2018 within the EU [1-4-1-6]. Due to the fluctuations in energy produced by wind farms storage of electricity is crucial. One possibility for storage is the production of hydrogen via electrolysis using renewable energy sources like wind farms. The hydrogen is then either directly added to the gas distribution grid or is converted to methane with external CO or CO2 which is then added to the gas distribution grid as a substitute [1-4]. Increasing the knowledge about the impact of renewable gases on available gas meters in terms of accuracy and durability is the main object of the EMPIR NEWGASMET project. Therefore in activity A3.1.1 a literature study was performed to provide information on which technologies can be used to calibrate gas meters when using renewable gases.
A Review of Energy Systems Models in the UK: Prevalent Usage and Categorisation
Feb 2016
Publication
In this paper a systematic review of academic literature and policy papers since 2008 is undertaken with an aim of identifying the prevalent energy systems models and tools in the UK. A list of all referenced models is presented and the literature is analysed with regards sectoral coverage and technological inclusion as well as mathematical structure of models. The paper compares available models using an appropriate classification schema the introduction of which is aimed at making the model landscape more accessible and perspicuous thereby enhancing the diversity of models within use. The distinct classification presented in this paper comprises three sections which specify the model purpose and structure technological detail and mathematical approach. The schema is not designed to be comprehensive but rather to be a broad classification with pertinent level of information required to differentiate between models. As an example the UK model landscape is considered and 22 models are classified in three tables as per the proposed schema.
A Review of the MSCA ITN ECOSTORE—Novel Complex Metal Hydrides for Efficient and Compact Storage of Renewable Energy as Hydrogen and Electricity
Mar 2020
Publication
Hydrogen as an energy carrier is very versatile in energy storage applications. Developments in novel sustainable technologies towards a CO2-free society are needed and the exploration of all-solid-state batteries (ASSBs) as well as solid-state hydrogen storage applications based on metal hydrides can provide solutions for such technologies. However there are still many technical challenges for both hydrogen storage material and ASSBs related to designing low-cost materials with low-environmental impact. The current materials considered for all-solid-state batteries should have high conductivities for Na+ Mg2+ and Ca2+ while Al3+-based compounds are often marginalised due to the lack of suitable electrode and electrolyte materials. In hydrogen storage materials the sluggish kinetic behaviour of solid-state hydride materials is one of the key constraints that limit their practical uses. Therefore it is necessary to overcome the kinetic issues of hydride materials before discussing and considering them on the system level. This review summarizes the achievements of the Marie Skłodowska-Curie Actions (MSCA) innovative training network (ITN) ECOSTORE the aim of which was the investigation of different aspects of (complex) metal hydride materials. Advances in battery and hydrogen storage materials for the efficient and compact storage of renewable energy production are discussed.
Novel Ways for Hydrogen Production Based on Methane Steam and Dry Reforming Integrated with Carbon Capture
Sep 2022
Publication
The combination of methane steam reforming technology and CCS (Carbon Capture and Storage) technology has great potential to reduce carbon emissions in the process of hydrogen production. Different from the traditional idea of capturing CO2 (Carbon Dioxide) in the exhaust gas with high work consumption this study simultaneously focuses on CO2 separation from fuel gas and recycling. A new hydrogen production system is developed by methane steam reforming coupled with carbon capture. Separated and captured high-purity carbon dioxide could be recycled for methane dry reforming; on this basis a new methane-dry-reforming-driven hydrogen production system with a carbon dioxide reinjection unit is innovatively proposed. In this study the energy flow and irreversible loss in the two newly developed systems are analyzed in detail through energy and exergy balance analysis. The advantages are explored from the perspective of hydrogen production rate natural gas consumption and work consumption. In addition in consideration of the integrated performance an optimal design analysis was conducted. In terms of hydrogen production the new system based on dry reforming is better with an advantage of 2.41%; however it is worth noting that the comprehensive thermal performance of the new steam reforming system is better reaching 10.95%. This study provides new ideas for hydrogen production from a low carbon emission perspective and also offers a new direction for future distributed energy system integration.
Everything About Hydrogen Podcast: Global Energy Majors in the Hydrogen Space
Jul 2022
Publication
On today’s episode of Everything About Hydrogen we are speaking with Paul Bogers Vice President for Hydrogen at Shell. As a company Shell needs no introduction but the company’s work and investments in the hydrogen space make it a global leader in the energy transition especially when it comes to the hydrogen component. Paul is amongst the executives at Shell that are working to bring their hydrogen vision to fruition and it is great to have him with us on the show today.
The podcast can be found on their website
The podcast can be found on their website
Hybrid Hydrogen–PV–e-Mobility Industrial Energy Community Concept—A Technology Feasibility Study
Sep 2021
Publication
As renewable energy sources are spreading the problems of energy usage transport and storage arise more frequently. In order that the performance of energy producing units from renewable sources which have a relatively low efficiency should not be decreased further and to promote sustainable energy consumption solutions a living lab conception was elaborated in this project. At the pilot site the produced energy (by PV panels gas turbines/engines) is stored in numerous ways including hydrogen production. The following uses of hydrogen are explored: (i) feeding it into the national natural gas network; (ii) selling it at a H-CNG (compressed natural gas) filling station; (iii) using it in fuel cells to produce electricity. This article introduces the overall implementation plan which can serve as a model for the hybrid energy communities to be established in the future.
Decentral Production of Green Hydrogen for Energy Systems: An Economically and Environmentally Viable Solution for Surplus Self-Generated Energy in Manufacturing Companies?
Feb 2023
Publication
Power-to-X processes where renewable energy is converted into storable liquids or gases are considered to be one of the key approaches for decarbonizing energy systems and compensating for the volatility involved in generating electricity from renewable sources. In this context the production of “green” hydrogen and hydrogen-based derivatives is being discussed and tested as a possible solution for the energy-intensive industry sector in particular. Given the sharp ongoing increases in electricity and gas prices and the need for sustainable energy supplies in production systems non-energy-intensive companies should also be taken into account when considering possible utilization paths for hydrogen. This work focuses on the following three utilization paths: “hydrogen as an energy storage system that can be reconverted into electricity” “hydrogen mobility” for company vehicles and “direct hydrogen use”. These three paths are developed modeled simulated and subsequently evaluated in terms of economic and environmental viability. Different photovoltaic system configurations are set up for the tests with nominal power ratings ranging from 300 kWp to 1000 kWp. Each system is assigned an electrolyzer with a power output ranging between 200 kW and 700 kW and a fuel cell with a power output ranging between 5 kW and 75 kW. There are also additional variations in relation to the battery storage systems within these basic configurations. Furthermore a reference variant without battery storage and hydrogen technologies is simulated for each photovoltaic system size. This means that there are ultimately 16 variants to be simulated for each utilization path. The results show that these utilization paths already constitute a reasonable alternative to fossil fuels in terms of costs in variants with a suitable energy system design. For the “hydrogen as an energy storage system” path electricity production costs of between 43 and 79 ct/kWh can be achieved with the 750 kWp photovoltaic system. The “hydrogen mobility” is associated with costs of 12 to 15 ct/km while the “direct hydrogen use” path resulted in costs of 8.2 €/kg. Environmental benefits are achieved in all three paths by replacing the German electricity mix with renewable energy sources produced on site or by substituting hydrogen for fossil fuels. The results confirm that using hydrogen as a storage medium in manufacturing companies could be economically and environmentally viable. These results also form the basis for further studies e.g. on detailed operating strategies for hydrogen technologies in scenarios involving a combination of multiple utilization paths. The work also presents the simulation-based method developed in this project which can be transferred to comparable applications in further studies.
Pipeline to 2050 - Building the Foundations for a Harmonised Heat Strategy
Nov 2020
Publication
Following up on our report Uncomfortable Home Truths: why Britain urgently needs a low carbon heat strategy Pipeline to 2050 sets out recommendations for BEIS’ forthcoming Heat and Buildings Strategy. Based on the findings of five roundtables held between January and July 2020 with cross-party parliamentarians policy-makers and experts from industry academia and non-governmental organisations the publication calls for a joined-up approach that simultaneously addresses all aspects of heat decarbonisation.<br/>The report highlights that today there is a patchwork of heat policy initiatives. Although they might incentivise positive development in themselves are nevertheless too dispersed and not enough to drive the level of coordinated action that is needed given the complexity of heat decarbonisation. Setting out propositions to tackle challenges associated with the transition to low carbon heat in the areas of governance funding innovation and public engagement; the publication calls for a Heat and Buildings Strategy that shows a step change in terms of ambition for heat decarbonisation.<br/>The report recommends that the Heat and Buildings Strategy needs to put forward a systematic approach that joins up all policy aspects and principles needed for the transition to low carbon heat. Moreover given the cross-sectoral engagement needed between consumers industry research and various levels of the government it argues that the Strategy has to be constructed in a way that simultaneously catalyses action from all stakeholders that are needed to take part in the process for effective heat decarbonisation.
Design of a Hydrogen Production System Considering Energy Consumption, Water Consumption, CO2 Emissions and Cost
Oct 2022
Publication
CO2 emissions associated with hydrogen production can be reduced replacing steam methane reforming with electrolysis using renewable electricity with a trade-off of increasing energy consumption water consumption and cost. In this research a linear programming optimization model of a hydrogen production system that considers simultaneously energy consumption water consumption CO2 emissions and cost on a cradle-to-gate basis was developed. The model was used to evaluate the impact of CO2 intensity on the optimum design of a hydrogen production system for Japan considering different stakeholders’ priorities. Hydrogen is produced using steam methane reforming and electrolysis. Electricity sources include grid wind solar photovoltaic geothermal and hydro. Independent of the stakeholders’ priorities steam methane reforming dominates hydrogen production for cradle-to-gate CO2 intensities larger than 9 kg CO2/kg H2 while electrolysis using renewable electricity dominates for lower cradle-to-gate CO2 intensities. Reducing the cradle-to-gate CO2 intensity increases energy consumption water consumption and specific cost of hydrogen production. For a cradle-to-gate CO2 intensity of 0 kg CO2/kg H2 the specific cost of hydrogen production varies between 8.81 and 13.6 USD/kg H2; higher than the specific cost of hydrogen production targeted by the Japanese government in 2030 of 30 JPY/Nm3 3.19 USD/kg H2.
Numerical Simulation on Pressure Dynamic Response Characteristics of Hydrogen Systems for Fuel Cell Vehicles
Mar 2022
Publication
A proton exchange membrane fuel cell (PEMFC) is known as one of the most promising energy sources for electric vehicles. A hydrogen system is required to provide hydrogen to the stack in time to meet the flow and pressure requirements according to the power requirements. In this study a 1-D model of a hydrogen system including the fuel cell stack was established. Two modes one with and one without a proportion integration differentiation (PID) control strategy were applied to analyze the pressure characteristics and performance of the PEMFC. The results showed that the established model could be well verified with experimental data. The anode pressure fluctuation with a PID control strategy was more stable which reduced the damage to the fuel cell stack caused by sudden changes of anode pressure. In addition the performance of the stack with the PID control mode was slightly improved. There was an inflection point for hydrogen utilization; the hydrogen utilization rate was higher under the mode without PID control when the current density was greater than 0.4 A/cm2 . What is more a hierarchical control strategy was proposed which made the pressure difference between the anode and cathode meet the stack working requirements and more importantly maintained the high hydrogen utilization of the hydrogen system.
Technical Reliability of Shipboard Technologies for the Application of Alternative Fuels
Jul 2022
Publication
Background: Naval trafc is highly dependent on depleting fossil resources and causes signifcant greenhouse gas emissions. At the same time marine transportation is a major backbone of world trade. Thus alternative fuel concepts are highly needed. Diferent fuels such as ammonia methanol liquefed natural gas and hydrogen have been proposed. For some of them frst prototype vessels have been in operation. However practical experience is still limited. Most studies so far focus on aspects such as efciency and economics. However particularly in marine applications reliability of propulsion systems is of utmost importance because failures on essential ship components at sea pose a huge safety risk. If the respective components lose their functionality repair can be much more challenging due to large distances to dockyards and the complicated transport of spare parts to the ship. Consequently evaluation of reliability should be a core element of system analysis for new marine fuels. Results: In this study reliability was studied for four potential fuels. The analysis involved several steps: estimation of overall failure rates identifcation of most vulnerable components and assessment of criticality by including severity of fault events. On the level of overall failure rate ammonia is shown to be very promising. Extending the view over a pure failure rate-based evaluation shows that other approaches such as LOHC or methanol can be competitive in terms of reliability and risk. As diferent scenarios require diferent weightings of the diferent reliability criteria the conclusion on the best technology can difer. Relevant aspects for this decision can be the availability of technical staf high-sea or coastal operation the presence of non-naval personnel onboard and other factors. Conclusions: The analysis allowed to compare diferent alternative marine fuel concepts regarding reliability. However the analysis is not limited to assessment of overall failure rates but can also help to identify critical elements that deserve attention to avoid fault events. As a last step severity of the individual failure modes was included. For the example of ammonia it is shown that the decomposition unit and the fuel cell should be subject to measures for increasing safety and reducing failure rates.
A Historical Analysis of Hydrogen Economy Research, Development, and Expectations, 1972 to 2020
Jan 2023
Publication
Global climate change concerns have pushed international governmental actions to reduce greenhouse gas emissions by adopting cleaner technologies hoping to transition to a more sustainable society. The hydrogen economy is one potential long-term option for enabling deep decarbonization for the future energy landscape. Progress towards an operating hydrogen economy is discouragingly slow despite global efforts to accelerate it. There are major mismatches between the present situation surrounding the hydrogen economy and previous proposed milestones that are far from being reached. The overall aim of this study is to understand whether there has been significant real progress in the achievement of a hydrogen economy or whether the current interest is overly exaggerated (hype). This study uses bibliometric analysis and content analysis to historically map the hydrogen economy’s development from 1972 to 2020 by quantifying and analyzing three sets of interconnected data. Findings indicate that interest in the hydrogen economy has significantly progressed over the past five decades based on the growing numbers of academic publications media coverage and projects. However various endogenous and exogenous factors have influenced the development of the hydrogen economy and created hype at different points in time. The consolidated results explore the changing trends and how specific events or actors have influenced the development of the hydrogen economy with their agendas the emergence of hype cycles and the expectations of a future hydrogen economy.
A Study into Proton Exchange Membrane Fuel Cell Power and Voltage Prediction using Artificial Neural Network
Sep 2022
Publication
Polymer Electrolyte Membrane fuel cell (PEMFC) uses hydrogen as fuel to generate electricity and by-product water at relatively low operating temperatures which is environmentally friendly. Since PEMFC performance characteristics are inherently nonlinear and related predicting the best performance for the different operating conditions is essential to improve the system’s efficiency. Thus modeling using artificial neural networks (ANN) to predict its performance can significantly improve the capabilities of handling multi-variable nonlinear performance of the PEMFC. This paper predicts the electrical performance of a PEMFC stack under various operating conditions. The four input terms for the 5 W PEMFC include anode and cathode pressures and flow rates. The model performances are based on ANN using two different learning algorithms to estimate the stack voltage and power. The models have shown consistently to be comparable to the experimental data. All models with at least five hidden neurons have coefficients of determination of 0.95 or higher. Meanwhile the PEMFC voltage and power models have mean squared errors of less than 1 × 10−3 V and 1 × 10−3 W respectively. Therefore the model results demonstrate the potential use of ANN into the implementation of such models to predict the steady state behavior of the PEMFC system (not limited to polarization curves) for different operating conditions and help in the optimization process for achieving the best performance of the system.
Coupling Combustion Simulation and Primary Evaluation of an Asymmetric Motion Diesel Pilot Hydrogen Engine
Jul 2022
Publication
The thermal efficiency and combustion of conventional hydrogen engines cannot be optimized and improved by its symmetric reciprocating. This article introduces an asymmetric motion hydrogen engine (AHE) and investigates its combustion characteristics using diesel pilot ignition. A dynamic model is firstly proposed to describe the asymmetric motion of the AHE and then it is coupled into a multidimensional model for combustion simulation. The effect of asymmetric motion on the AHE combustion is also analyzed by comparing with a corresponding conventional symmetric hydrogen engine (SHE). The results show that the AHE moves slower in compression and faster in expansion than the SHE which brings about higher hydrogen-air mixing level for combustion. The asymmetric motion delays diesel injection to ignite the AHE and its combustion appears later than the SHE which leads to lower pressure and temperature for reducing NO formation. However the AHE faster expansion has a more severe post-combustion effect to reduce isovolumetric heat release level and decrease the energy efficiency.
Life Cycle Costing Analysis: Tools and Applications for Determining Hydrogen Production Cost for Fuel Cell Vehicle Technology
Jul 2021
Publication
This work investigates life cycle costing analysis as a tool to estimate the cost of hydrogen to be used as fuel for Hydrogen Fuel Cell vehicles (HFCVs). The method of life cycle costing and economic data are considered to estimate the cost of hydrogen for centralised and decentralised production processes. In the current study two major hydrogen production methods are considered methane reforming and water electrolysis. The costing frameworks are defined for hydrogen production transportation and final application. The results show that hydrogen production via centralised methane reforming is financially viable for future transport applications. The ownership cost of HFCVs shows the highest cost among other costs of life cycle analysis.
Numerical Evaluation of Terrain Landscape Influence on Hydrogen Explosion Consequences
Sep 2021
Publication
The aim of this study is to assess numerically the influence of terrain landscape on the distribution of probable harmful consequences to personnel of hydrogen fueling station caused by an accidentally released and exploded hydrogen. In order to extract damaging factors of the hydrogen explosion wave (maximum overpressure and impulse of pressure phase) a three-dimensional mathematical model of gas mixture dynamics with chemical interaction is used. It allows controlling current pressure in every local point of actual space taking into account complex terrain. This information is used locally in every computational cell to evaluate the conditional probability of such consequences on human beings as ear-drum rupture and lethal ones on the basis of probit analysis. In order to use this technique automatically during the computational process the tabular dependence ""probit-functionimpact probability"" is replaced by a piecewise cubic spline. To evaluate the influence of the landscape profile on the non-stationary three-dimensional overpressure distribution above the earth surface near an epicenter of accidental hydrogen explosion a series of computational experiments with different variants of the terrain is carried out. Each variant differs in the level of mutual arrangement of the explosion epicenter and the places of possible location of personnel. Two control points with different distances from the explosion epicenter are considered. Diagrams of lethal and ear-drum rupture conditional probabilities are build to compare different variants of landscape profile. It is found that the increase or decrease in the level of the location of the control points relative to the level of the epicenter of the explosion significantly changes the scale of the consequences in the actual zone around the working places and should be taken into account by the risk managing experts at the stage of deciding on the level of safety at hydrogen fueling stations.
Solid-State Hydrogen Fuel by PSII–Chitin Composite and Application to Biofuel Cell
Dec 2021
Publication
Biomaterials attract a lot of attention as next-generation materials. Especially in the energy field fuel cells based on biomaterials can further develop clean next-generation energy and are focused on with great interest. In this study solid-state hydrogen fuel (PSII–chitin composite) composed of the photosystem II (PSII) and hydrated chitin composite was successfully created. Moreover a biofuel cell consisting of the electrolyte of chitin and the hydrogen fuel using the PSII– chitin composite was fabricated and its characteristic feature was investigated. We found that proton conductivity in the PSII–chitin composite increases by light irradiation. This result indicates that protons generate in the PSII–chitin composite by light irradiation. It was also found that the biofuel cell using the PSII–chitin composite hydrogen fuel and the chitin electrolyte exhibits the maximum power density of 0.19 mW/cm2 . In addition this biofuel cell can drive an LED lamp. These results indicate that the solid-state biofuel cell based on the bioelectrolyte “chitin” and biofuel “the PSII–chitin composite” can be realized. This novel solid-state fuel cell will be helpful to the fabrication of next-generation energy.
Building Hydrogen Competence, a Technology Aligned Skills and Knowledge Approach
Sep 2021
Publication
There is a pressing need for a framework and strategic approach to be taken to workforce safety training requirements of new hydrogen projects. It is apparent that organisations embarking on projects utilizing or producing green hydrogen need to implement a program of training for their workforce in order to ensure that all personnel within their organisation understand not only the environmental benefits of green hydrogen but also the safety considerations that come with either producing or using hydrogen as a fuel. Energy Transition must be safe to be successful. If such an approach is taken by industry and stakeholders it is also possible to use the high level content as a vehicle and basis to offer public audiences which also require a basic level of understanding in order to fully accept the transition to using hydrogen more widely as a fuel. This will be crucial to the success of national hydrogen strategies. Coeus Energy has developed an innovative framework of training following engagement with operators keen to ensure their duty of care responsibilities have been met. Whilst having highly skilled personnel already employed within their organisations specific hydrogen content is still required for workforce competence. This is where the framework need arises as the knowledge is required at all levels of an organisation.
A Review of Factors Affecting SCC Initiation and Propagation in Pipeline Carbon Steels
Aug 2022
Publication
Pipelines have been installed and operated around the globe to transport oil and gas for decades. They are considered to be an effective economic and safe means of transportation. The major concern in their operation is corrosion. Among the different forms of corrosion stress corrosion cracking (SCC) which is caused by stresses induced by internal fluid flow or other external forces during the pipeline’s operation in combined action with the presence of a corrosive medium can lead to pipeline failure. In this paper an extensive review of different factors affecting SCC of pipeline steels in various environmental conditions is carried out to understand their impact. Several factors such as temperature presence of oxidizers (O2 CO2 H2S etc.) composition and concentration of medium pH applied stress and microstructure of the metal/alloy have been established to affect the SCC of pipeline steels. SCC susceptibility of a steel at a particular temperature strongly depends on the type and composition of the corrosive medium and microstructure. It was observed that pipeline steels with water quenched and quenched and tempered heat treatments such as those that consist of acicular ferrite or bainitic ferrite grains are more susceptible to SCC irrespective of solution type and composition. Applied stress stress concentration and fluctuating stress facilitates SCC initiation and propagation. In general the mechanisms for crack initiation and propagation in near-neutral solutions are anodic dissolution and hydrogen embrittlement.
Energy Transition in Aviation: The Role of Cryogenic Fuels
Dec 2020
Publication
Aviation is the backbone of our modern society. In 2019 around 4.5 billion passengers travelled through the air. However at the same time aviation was also responsible for around 5% of anthropogenic causes of global warming. The impact of the COVID-19 pandemic on the aviation sector in the short term is clearly very high but the long-term effects are still unknown. However with the increase in global GDP the number of travelers is expected to increase between three- to four-fold by the middle of this century. While other sectors of transportation are making steady progress in decarbonizing aviation is falling behind. This paper explores some of the various options for energy carriers in aviation and particularly highlights the possibilities and challenges of using cryogenic fuels/energy carriers such as liquid hydrogen (LH2) and liquefied natural gas (LNG).
Evaluation of Selectivity and Resistance to Poisons of Commercial Hydrogen Sensors
Sep 2013
Publication
The development of reliable hydrogen sensors is crucial for the safe use of hydrogen. One of the main concerns of end-users is sensor reliability in the presence of species other than the target gas which can lead to false alarms or undetected harmful situations. In order to assess the selectivity of commercial of the shelf (COTS) hydrogen sensors a number of sensors of different technology types were exposed to various interferent gas species. Cross-sensitivity tests were performed in accordance to the recommendations of ISO 26142:2010 using the hydrogen sensor testing facilities of NREL and JRC-IET. The results and conclusions arising from this study are presented.
Heating Economics Evaluated Against Emissions: An Analysis of Low-carbon Heating Systems with Spatiotemporal and Dwelling Variations
Oct 2022
Publication
An understanding of heating technologies from the consumers’ perspective is critical to ensure low-carbon technologies are adopted for reducing their current associated emissions. Existing studies from the consumers’ perspective do not compare and optimise the full range and combinations of potential heating systems. There is also little consideration of how spatiotemporal and dwelling variations combined alter the economic and environmental effectiveness of technologies. The novelty of this paper is the creation and use of a new comprehensive framework to capture the range of heating technologies and their viability for any specific dwelling’s traits and climate from customers’ perspective which is missing from current studies. The model optimises combinations of prime heaters energy sources ancillary solar technologies and sizes thermal energy storage sizes and tariffs with hourly heating simulation across a year and compares their operation capital and lifetime costs alongside emissions to realise the true preferential heating systems for customers which could be used by various stakeholders. Using the UK as a case study the results show electrified heating is generally the optimum lifetime cost solution mainly from air source heat pumps coupled with photovoltaics. However direct electrical heating becomes more economically viable as dwelling demands reduce from smaller dwellings or warmer climates as shorter durations of the ownership are considered or with capital cost constraints from lower income households. Understanding this is of high importance as without correctly targeted incentives a larger uptake of direct electrical heating may occur which will burden the electrical network and generation to a greater extent than more efficient heat pumps.
Life Cycle Cost Analysis for Scotland Short-Sea Ferries
Feb 2023
Publication
The pathway to zero carbon emissions passing through carbon emissions reduction is mandatory in the shipping industry. Regarding the various methodologies and technologies reviewed for this purpose Life Cycle Cost Analysis (LCCA) has been used as an excellent tool to determine economic feasibility and sustainability and to present directions. However insufficient commercial applications cause a conflict of opinion on which fuel is the key to decarbonisation. Many LCCA comparison studies about eco-friendly ship propulsion claim different results. In order to overcome this and discover the key factors that affect the overall comparative analysis and results in the maritime field it is necessary to conduct the comparative analysis considering more diverse case ships case routes and various types that combine each system. This study aims to analyse which greener fuels are most economically beneficial for the shipping sector and prove the factors influencing different results in LCCA. This study was conducted on hydrogen ammonia and electric energy which are carbon-free fuels among various alternative fuels that are currently in the limelight. As the power source a PEMFC and battery were used as the main power source and a solar PV system was installed as an auxiliary power source to compare economic feasibility. Several cost data for LCCA were selected from various feasible case studies. As the difficulty caused by the storage and transportation of hydrogen and ammonia should not be underestimated in this study the LCCA considers not only the CapEx and OpEx but also fuel transport costs. As a result fuel cell propulsion systems with hydrogen as fuel proved financial effectiveness for short-distance ferries as they are more inexpensive than ammonia-fuelled PEMFCs and batteries. The fuel cost takes around half of the total life-cycle cost during the life span.
Cost-Economic Analysis of Hydrogen for China’s Fuel Cell Transportation Field
Dec 2020
Publication
China has become a major market for hydrogen used in fuel cells in the transportation field. It is key to control the cost of hydrogen to open up the Chinese market. The development status and trends of China’s hydrogen fuel industry chain were researched. A hydrogen energy cost model was established in this paper from five aspects: raw material cost fixed cost of production hydrogen purification cost carbon trading cost and transportation cost. The economic analysis of hydrogen was applied to hydrogen transported in the form of high-pressure hydrogen gas or cryogenic liquid hydrogen and produced by natural gas coal and electrolysis of water. It was found that the cost of hydrogen from natural gas and coal is currently lower while it is greatly affected by the hydrogen purification cost and the carbon trading price. Considering the impact of future production technologies raw material costs and rising requirements for sustainable energy development on the hydrogen energy cost it is recommended to use renewable energy curtailment as a source of electricity and multi-stack system electrolyzers as large-scale electrolysis equipment in combination with cryogenic liquid hydrogen transportation or on-site hydrogen production. Furthermore participation in electricity market-oriented transactions cross-regional transactions and carbon trading can reduce the cost of hydrogen. These approaches represent the optimal method for obtaining inexpensive hydrogen.
A Novel Framework for Development and Optimisation of Future Electricity Scenarios with High Penetration of Renewables and Storage
May 2019
Publication
Although electricity supply is still dominated by fossil fuels it is expected that renewable sources will have a much larger contribution in the future due to the need to mitigate climate change. Therefore this paper presents a new framework for developing Future Electricity Scenarios (FuturES) with high penetration of renewables. A multi-period linear programming model has been created for power-system expansion planning. This has been coupled with an economic dispatch model PowerGAMA to evaluate the technical and economic feasibility of the developed scenarios while matching supply and demand. Application of FuturES is demonstrated through the case of Chile which has ambitious plans to supply electricity using only renewable sources. Four cost-optimal scenarios have been developed for the year 2050 using FuturES: two Business as usual (BAU) and two Renewable electricity (RE) scenarios. The BAU scenarios are unconstrained in terms of the technology type and can include all 11 options considered. The RE scenarios aim to have only renewables in the mix including storage. The results show that both BAU scenarios have a levelised cost of electricity (LCOE) lower than or equal to today’s costs ($72.7–77.3 vs $77.6/MWh) and include 81–90% of renewables. The RE scenarios are slightly more expensive than today’s costs ($81–87/MWh). The cumulative investment for the BAU scenarios is $123-$145 bn compared to $147-$157 bn for the RE. The annual investment across the scenarios is estimated at $4.0 ± 0.4 bn. Both RE scenarios show sufficient flexibility in matching supply and demand despite solar photovoltaics and wind power contributing around half of the total supply. Therefore the FuturES framework is a powerful tool for aiding the design of cost-efficient power systems with high penetration of renewables.
Design and Development of a Catalytic Fixed-Bed Reactor for Gasification of Banana Biomass in Hydrogen Production
Apr 2022
Publication
Hydrogen produced from biomass is an alternative energy source to fossil fuels. In this study hydrogen production by gasification of the banana plant is proposed. A fixed-bed catalytic reactor was designed considering fluidization conditions and a height/diameter ratio of 3/1. Experimentation was carried out under the following conditions: 368 ◦C atmospheric pressure 11.75 g of residual mass of the banana (pseudo-stem) an average particle diameter of 1.84 mm and superheated water vapor as a gasifying agent. Gasification reactions were performed using a catalyzed and uncatalyzed medium to compare the effectiveness of each case. The catalyst was Ni/Al2O3 synthesized by coprecipitation. The gas mixture produced from the reaction was continuously condensed to form a two-phase liquid–gas system. The synthesis gas was passed through a silica gel filter and analyzed online by gas chromatography. To conclude the results of this study show production of 178 mg of synthesis gas for every 1 g of biomass and the selectivity of hydrogen to be 51.8 mol% when a Ni 2.5% w/w catalyst was used. The amount of CO2 was halved and CO was reduced from 3.87% to 0% in molar percentage. Lastly a simulation of the distribution of temperatures inside the furnace was developed; the modeled behavior is in agreement with experimental observations.
Hydrogen Deep Ocean Link: A Global Sustainable Interconnected Energy Grid
Mar 2022
Publication
The world is undergoing a substantial energy transition with an increasing share of intermittent sources of energy on the grid which is increasing the challenges to operate the power grid reliably. An option that has been receiving much focus after the COVID pandemic is the development of a hydrogen economy. Challenges for a hydrogen economy are the high investment costs involved in compression storage and long-distance transportation. This paper analyses an innovative proposal for the creation of hydrogen ocean links. It intends to fill existing gaps in the creation of a hydrogen economy with the increase in flexibility and viability for hydrogen production consumption compression storage and transportation. The main concept behind the proposals presented in this paper consists of using the fact that the pressure in the deep sea is very high which allows a thin and cheap HDPE tank to store and transport large amounts of pressurized hydrogen in the deep sea. This is performed by replacing seawater with pressurized hydrogen and maintaining the pressure in the pipes similar to the outside pressure. Hydrogen Deep Ocean Link has the potential of increasing the interconnectivity of different regional energy grids into a global sustainable interconnected energy system.
Transition to a Hydrogen-Based Economy: Possibilities and Challenges
Nov 2022
Publication
Across the globe energy production and usage cause the greatest greenhouse gas (GHG) emissions which are the key driver of climate change. Therefore countries around the world are aggressively striving to convert to a clean energy regime by altering the ways and means of energy production. Hydrogen is a frontrunner in the race to net-zero carbon because it can be produced using a diversity of feedstocks has versatile use cases and can help ensure energy security. While most current hydrogen production is highly carbon-intensive advances in carbon capture renewable energy generation and electrolysis technologies could help drive the production of low-carbon hydrogen. However significant challenges such as the high cost of production a relatively small market size and inadequate infrastructure need to be addressed before the transition to a hydrogen-based economy can be made. This review presents the state of hydrogen demand challenges in scaling up low-carbon hydrogen possible solutions for a speedy transition and a potential course of action for nations.
Potential and Challenges of Low-carbon Energy Options: Comparative Assessment of Alternative Fuels for the Transport Sector
Dec 2018
Publication
The deployment of low-emission alternative fuels is crucial to decarbonise the transport sector. A number of alternatives like hydrogen or dimethyl ether/methanol synthesised using CO2 as feedstock for fuel production (hereafter refer to “CO2-based fuels”) have been proposed to combat climate change. However the decarbonisation potential of CO2-based fuels is under debate because CO2 is re-emitted to the atmosphere when the fuel is combusted; and the majority of hydrogen still relies on fossil resources which makes its prospects of being a low-carbon fuel dependent on its manufacturing process. First this paper investigates the relative economic and environmental performance of hydrogen (produced from conventional steam methane reforming and produced via electrolysis using renewable energy) and CO2- based fuels (dimethyl ether and methanol) considering the full carbon cycle. The results reveal that hydrogen produced from steam methane reforming is the most economical option and that hydrogen produced via electrolysis using renewables has the best environmental profile. Whereas the idea of CO2-based fuels has recently gained much interest it has for the foreseeable future rather limited practical relevance since there is no favourable combination of cost and environmental performance. This will only change in the long run and requires that CO2 is of non-fossil origin i.e. from biomass combustion or captured from air. Second this paper address unresolved methodological issues in the assessment of CO2-based fuels such as the possible allocation of emissions to the different sectors involved. The outcomes indicate that implementing different allocation approaches substantially influences the carbon footprint of CO2-based fuels. To avoid allocation issues expanding the boundaries including the entire system and is therefore recommended.
Catalytic Hydrogen Production from Methane: A Review on Recent Progress and Prospect
Aug 2020
Publication
Natural gas (Methane) is currently the primary source of catalytic hydrogen production accounting for three quarters of the annual global dedicated hydrogen production (about 70 M tons). Steam–methane reforming (SMR) is the currently used industrial process for hydrogen production. However the SMR process suffers with insufficient catalytic activity low long-term stability and excessive energy input mostly due to the handling of large amount of CO2 coproduced. With the demand for anticipated hydrogen production to reach 122.5 M tons in 2024 novel and upgraded catalytic processes are desired for more effective utilization of precious natural resources. In this review we summarized the major descriptors of catalyst and reaction engineering of the SMR process and compared the SMR process with its derivative technologies such as dry reforming with CO2 (DRM) partial oxidation with O2 autothermal reforming with H2O and O2. Finally we discussed the new progresses of methane conversion: direct decomposition to hydrogen and solid carbon and selective oxidation in mild conditions to hydrogen containing liquid organics (i.e. methanol formic acid and acetic acid) which serve as alternative hydrogen carriers. We hope this review will help to achieve a whole picture of catalytic hydrogen production from methane.
On-Board Cold Thermal Energy Storage System for Hydrogen Fueling Process
Feb 2019
Publication
The hydrogen storage pressure in fuel cell vehicles has been increased from 35 MPa to 70 MPa in order to accommodate longer driving range. On the downside such pressure increase results in significant temperature rise inside the hydrogen tank during fast filling at a fueling station which may pose safety issues. Installation of a chiller often mitigates this concern because it cools the hydrogen gas before its deposition into the tank. To address both the energy efficiency improvement and safety concerns this paper proposed an on-board cold thermal energy storage (CTES) system cooled by expanded hydrogen. During the driving cycle the proposed system uses an expander instead of a pressure regulator to generate additional power and cold hydrogen gas. Moreover CTES is equipped with phase change materials (PCM) to recover the cold energy of the expanded hydrogen gas which is later used in the next filling to cool the high-pressure hydrogen gas from the fueling station.
Assessing the Life-Cycle Performance of Hydrogen Production via Biofuel Reforming in Europe
Jun 2015
Publication
Currently hydrogen is mainly produced through steam reforming of natural gas. However this conventional process involves environmental and energy security concerns. This has led to the development of alternative technologies for (potentially) green hydrogen production. In this work the environmental and energy performance of biohydrogen produced in Europe via steam reforming of glycerol and bio-oil is evaluated from a life-cycle perspective and contrasted with that of conventional hydrogen from steam methane reforming. Glycerol as a by-product from the production of rapeseed biodiesel and bio-oil from the fast pyrolysis of poplar biomass are considered. The processing plants are simulated in Aspen Plus® to provide inventory data for the life cycle assessment. The environmental impact potentials evaluated include abiotic depletion global warming ozone layer depletion photochemical oxidant formation land competition acidification and eutrophication. Furthermore the cumulative (total and non-renewable) energy demand is calculated as well as the corresponding renewability scores and life-cycle energy balances and efficiencies of the biohydrogen products. In addition to quantitative evidence of the (expected) relevance of the feedstock and impact categories considered results show that poplar-derived bio-oil could be a suitable feedstock for steam reforming in contrast to first-generation bioglycerol.
Deep Reinforcement Learning Based Energy Management Strategy for Fuel Cell/Battery/Supercapacitor Powered Electric Vehicle
Sep 2022
Publication
Vehicles using a single fuel cell as a power source often have problems such as slow response and inability to recover braking energy. Therefore the current automobile market is mainly dominated by fuel cell hybrid vehicles. In this study the fuel cell hybrid commercial vehicle is taken as the research object and a fuel cell/ battery/supercapacitor energy topology is proposed and an energy management strategy based on a doubledelay deep deterministic policy gradient is designed for this topological structure. This strategy takes fuel cell hydrogen consumption fuel cell life loss and battery life loss as the optimization goals in which supercapacitors play the role of coordinating the power output of the fuel cell and the battery providing more optimization ranges for the optimization of fuel cells and batteries. Compared with the deep deterministic policy gradient strategy (DDPG) and the nonlinear programming algorithm strategy this strategy has reduced hydrogen consumption level fuel cell loss level and battery loss level which greatly improves the economy and service life of the power system. The proposed EMS is based on the TD3 algorithm in deep reinforcement learning and simultaneously optimizes a number of indicators which is beneficial to prolong the service life of the power system.
Methane Cracking for Hydrogen Production: A Review of Catalytic and Molten Media Pyrolysis
May 2022
Publication
Currently hydrogen is mainly generated by steam methane reforming with significant CO2 emissions thus exacerbating the greenhouse effect. This environmental concern promotes methane cracking which represents one of the most promising alternatives for hydrogen production with theoretical zero CO/CO2 emissions. Methane cracking has been intensively investigated using metallic and carbonaceous catalysts. Recently research has focused on methane pyrolysis in molten metals/salts to prevent both reactor coking and rapid catalyst deactivation frequently encountered in conventional pyrolysis. Another expected advantage is the heat transfer improvement due to the high heat capacity of molten media. Apart from the reaction itself that produces hydrogen and solid carbon the energy source used in this endothermic process can also contribute to reducing environmental impacts. While most researchers used nonrenewable sources based on fossil fuel combustion or electrical heating concentrated solar energy has not been thoroughly investigated to date for pyrolysis in molten media. However it could be a promising innovative pathway to further improve hydrogen production sustainability from methane cracking. After recalling the basics of conventional catalytic methane cracking and the developed solar cracking reactors this review delves into the most significant results of the state-of-the-art methane pyrolysis in melts (molten metals and salts) to show the advantages and the perspectives of this new path as well as the carbon products’ characteristics and the main factors governing methane conversion.
A Financial Model for Lithium-ion Storage in a Photovoltaic and Biogas Energy System
May 2019
Publication
Electrical energy storage (EES) such as lithium-ion (Li-ion) batteries can reduce curtailment of renewables maximizing renewable utilization by storing surplus electricity. Several techno-economic analyses have been performed on EES but few have investigated the financial performance. This paper presents a state-of-the-art financial model obtaining novel and significative financial and economics results when applied to Li-ion EES. This work is a significant step forward since traditional analysis on EES are based on oversimplified and unrealistic economic models. A discounted cash flow model for the Li-ion EES is introduced and applied to examine the financial performance of three EES operating scenarios. Real-life solar irradiance load and retail electricity price data from Kenya are used to develop a set of case studies. The EES is coupled with photovoltaics and an anaerobic digestion biogas power plant. The results show the impact of capital cost: the Li-ion project is unprofitable in Kenya with a capital cost of 1500 $/kWh but is profitable at 200 $/kWh. The study shows that the EES will generate a higher profit if it is cycled more frequently (hence a higher lifetime electricity output) although the lifetime is reduced due to degradation.
An Overview of the Classification, Production and Utilization of Biofuels for Internal Combustion Engine Applications
Sep 2021
Publication
Biofuel a cost-effective safe and environmentally benign fuel produced from renewable sources has been accepted as a sustainable replacement and a panacea for the damaging effects of the exploration for and consumption of fossil-based fuels. The current work examines the classification generation and utilization of biofuels particularly in internal combustion engine (ICE) applications. Biofuels are classified according to their physical state technology maturity the generation of feedstock and the generation of products. The methods of production and the advantages of the application of biogas bioalcohol and hydrogen in spark ignition engines as well as biodiesel Fischer– Tropsch fuel and dimethyl ether in compression ignition engines in terms of engine performance and emission are highlighted. The generation of biofuels from waste helps in waste minimization proper waste disposal and sanitation. The utilization of biofuels in ICEs improves engine performance and mitigates the emission of poisonous gases. There is a need for appropriate policy frameworks to promote commercial production and seamless deployment of these biofuels for transportation applications with a view to guaranteeing energy security.
Historical Analysis of FCH 2 JU Stationary Fuel Cell Projects
May 2021
Publication
As a part of its knowledge management activities the Fuel Cell and Hydrogen Joint Undertaking 2 (FCH 2 JU) has commissioned the Joint Research Centre (JRC) to perform a series of historical analyses by topic area to assess the impact of funded projects and the progression of its current Multi-Annual Work Plan (MAWP; 2014- 2020) towards its objectives. These historical analyses consider all relevant funded projects since the programme’s inception in 2008. This report considers the performance of projects against the overall FCH 2 JU programme targets for stationary Fuel Cells (FCs) using quantitative values of Key Performance Indicators (KPI) for assessment. The purpose of this exercise is to see whether and how the programme has enhanced the state of the art for stationary fuel cells and to identify potential Research & Innovation (R&I) gaps for the future. Therefore the report includes a review of the current State of the Art (SoA) of fuel cell technologies used in the stationary applications sector. The programme has defined KPIs for three different power output ranges and equivalent applications: (i) micro-scale Combined Heat and Power (mCHP) for single family homes and small buildings (0.3 - 5 kW); (ii) mid-sized installations for commercial and larger buildings (5 - 400 kW); (iii) large scale FC installations converting hydrogen and renewable methane into power in various applications (0.4 - 30 MW). Projects addressing stationary applications in these particular power ranges were identified and values for the achieved KPIs extracted from relevant sources of information such as final reports and the TRUST database (Technology Reporting Using Structured Templates). As much of this data is confidential a broad analysis of performance of the programme against its KPIs has been performed without disclosing confidential information. The results of this analysis are summarised within this report. The information obtained from this study will be used to suggest future modifications to the research programme and associated targets.
Explosive Phase Transition in LH2
Sep 2021
Publication
This paper describes two models for analysing and simulating the physical effects of explosive phase transition of liquid hydrogen (LH2) also known as cold BLEVE. The present work is based on theoretical and experimental work for liquefied CO2. A Rankine Hugoniot analysis for evaporation waves that was previously developed for CO2 is now extended to LH2. A CFD-method for simulating two-phase flow with mass transfer between the phases is presented and compared with the Rankine Hugoniot analysis results. The Rankine Hugoniot method uses real fluid equations of state suited for LH2 while the CFD method uses linear equations of state suited for shock capturing methods. The results show that there will be a blast from a catastrophic rupture of an LH2 vessel and that the blast waves will experience a slow decay due to the large positive pressure phase.
Dynamic Emulation of a PEM Electrolyzer by Time Constant Based Exponential Model
Feb 2019
Publication
The main objective of this paper is to develop a dynamic emulator of a proton exchange membrane (PEM) electrolyzer (EL) through an equivalent electrical model. Experimental investigations have highlighted the capacitive effect of EL when subjecting to dynamic current profiles which so far has not been reported in the literature. Thanks to a thorough experimental study the electrical domain of a PEM EL composed of 3 cells has been modeled under dynamic operating conditions. The dynamic emulator is based on an equivalent electrical scheme that takes into consideration the dynamic behavior of the EL in cases of sudden variation in the supply current. The model parameters were identified for a suitable current interval to consider them as constant and then tested with experimental data. The obtained results through the developed dynamic emulator have demonstrated its ability to accurately replicate the dynamic behavior of a PEM EL.
Nuclear-Renewables Energy System for Hydrogen and Electricity Production
May 2011
Publication
In the future the world may have large stranded resources of low-cost wind and solar electricity. Renewable electricity production does not match demand and production is far from major cities. The coupling of nuclear energy with renewables may enable full utilization of nuclear and renewable facilities to meet local electricity demands and export pipeline hydrogen for liquid fuels fertilizer and metals production. Renewables would produce electricity at full capacity in large quantities. The base-load nuclear plants would match electricity production with demand by varying the steam used for electricity versus hydrogen production. High-temperature electrolysis (HTE) would produce hydrogen from water using (a) steam from nuclear plants and (b) electricity from nuclear plants and renewables. During times of peak electricity demand the HTE cells would operate in reverse fuel cell mode to produce power substituting for gas turbines that are used for very few hours per year and that thus have very high electricity costs. The important net hydrogen production would be shipped by pipeline to customers. Local hydrogen storage would enable full utilization of long-distance pipeline capacity with variable production. The electricity and hydrogen production were simulated with real load and wind data to understand under what conditions such systems are economic. The parametric case study uses a wind-nuclear system in North Dakota with hydrogen exported to the Chicago refinery market. North Dakota has some of the best wind conditions in the United States and thus potentially low-cost wind. The methodology allows assessments with different economic and technical assumptions - including what electrolyzer characteristics are most important for economic viability.
Hydrogen Component Leak Rate Quantification for System Risk and Reliability Assessment through QRA and PHM Frameworks
Sep 2021
Publication
The National Renewable Energy Laboratory’s (NREL) Hydrogen Safety Research and Development (HSR&D) program in collaboration with the University of Maryland’s Systems Risk and Reliability Analysis Laboratory (SyRRA) are working to improve reliability and reduce risk in hydrogen systems. This approach strives to use quantitative data on component leaks and failures together with Prognosis and Health Management (PHM) and Quantitative Risk Assessment (QRA) to identify atrisk components reduce component failures and downtime and predict when components require maintenance. Hydrogen component failures increase facility maintenance cost facility downtime and reduce public acceptance of hydrogen technologies ultimately increasing facility size and cost because of conservative design requirements. Leaks are a predominant failure mode for hydrogen components. However uncertainties in the amount of hydrogen emitted from leaking components and the frequency of those failure events limit the understanding of the risks that they present under real-world operational conditions. NREL has deployed a test fixture the Leak Rate Quantification Apparatus (LRQA) to quantify the mass flow rate of leaking gases from medium and high-pressure components that have failed while in service. Quantitative hydrogen leak rate data from this system could ultimately be used to better inform risk assessment and Regulation Codes and Standards (RCS). Parallel activity explores the use of PHM and QRA techniques to assess and reduce risk thereby improving safety and reliability of hydrogen systems. The results of QRAs could further provide a systematic and science-based foundation for the design and implementation of RCS as in the latest versions of the NFPA 2 code for gaseous hydrogen stations. Alternatively data-driven techniques of PHM could provide new damage diagnosis and health-state prognosis tools. This research will help end users station owners and operators and regulatory bodies move towards risk-informed preventative maintenance versus emergency corrective maintenance reducing cost and improving reliability. Predictive modelling of failures could improve safety and affect RCS requirements such as setback distances at liquid hydrogen fueling sites. The combination of leak rate quantification research PHM and QRA can lead to better informed models enabling data-based decision to be made for hydrogen system safety improvements.
NewGasMet - Flow Metering of Renewable Gases (Biogas, Biomethane, Hydrogen, Syngas and Mixtures with Natural Gas): Criteria and Proposals for EMC Tests on Ultrasonic Meters with Non-conventional Gases
Oct 2022
Publication
The NEWGASMET project has the overall objective to increase knowledge about the accuracy and durability of commercially available gas meters after exposure to renewable gases. This should lead to the improvement of existing meter designs and flow calibration standards. One of the recently released results is a proposal for a set of test gases to represent the range of non-conventional gases in the scope of the revision of the gas meter standards. In details these were proposed to be used in the CEN/TC237 standards and the OIML-R137:2014. During the project meetings concerns have been raised regarding the applicability of such test gases to EMC tests for static meters. Today such tests are performed in air but there is a clear agreement that the behaviour of the meter during EMC tests can be influenced by the renewable gas type. At least this agreement exists for the ultrasonic measurement technology while further discussion might be needed for the mass flow. However it is not simply possible to redesign the current EMC tests by replacing air with the defined gas mixtures as this would be quite impractical especially considering the explosive nature of the test gases.
Fly the Green Deal: Europe's Vision for Sustainable Aviation
Jul 2022
Publication
Europe’s aviation sector continues its resilient and pioneering spirit as it leads the world’s transport system into its new era of great transformation. Surviving the pandemic it is adapting rapidly to satisfy the rising demand for competitive air mobility services while managing a scarcity of resources and embracing the new challenges of climate change and energy transition. Facilitated by ACARE the European Commission its Member States aviation research organisations design and manufacturing industries airlines airports and aviation energy and service providers have all joined together to envision a synchronized transformation path that will ensure that Europe can lead the world towards a climate neutral citizen centric and competitive air mobility system. “Fly the Green Deal” is Europe’s Vision for Sustainable Aviation. It describes the actions and actors necessary towards aviation’s three main strategic goals. It details three time horizons and defines as well the requirement for a proactive and synchronised implementation framework facilitated by the European Commission and EU Member States that includes both the initiating instruments (policies regulations and incentives) and a system of measuring and impact monitoring to ensure the goals are achieved.
Life Cycle Assessment of Alternative Ship Fuels for Coastal Ferry Operating in Republic of Korea
Aug 2020
Publication
In this study the environmental impacts of various alternative ship fuels for a coastal ferry were assessed by the life cycle assessment (LCA) analysis. The comparative study was performed with marine gas oil (MGO) natural gas and hydrogen with various energy sources for a 12000 gross tonne (GT) coastal ferry operating in the Republic of Korea (ROK). Considering the energy imports of ROK i.e. MGO from Saudi Arabia and natural gas from Qatar these countries were chosen to provide the MGO and the natural gas for the LCA. The hydrogen is considered to be produced by steam methane reforming (SMR) from natural gas with hard coal nuclear energy renewable energy and electricity in the ROK model. The lifecycles of the fuels were analyzed in classifications of Well-toTank Tank-to-Wake and Well-to-Wake phases. The environmental impacts were provided in terms of global warming potential (GWP) acidification potential (AP) photochemical potential (POCP) eutrophication potential (EP) and particulate matter (PM). The results showed that MGO and natural gas cannot be used for ships to meet the International Maritime Organization’s (IMO) 2050 GHG regulation. Moreover it was pointed out that the energy sources in SMR are important contributing factors to emission levels. The paper concludes with suggestions for a hydrogen application plan for ships from small nearshore ships in order to truly achieve a ship with zero emissions based on the results of this study.
Modeling and Simulation of an Isolated Hybrid Micro-grid with Hydrogen Production and Storage
Jan 2014
Publication
This work relates the study of system performance in operational conditions for an isolated micro-grid powered by a photovoltaic system and a wind turbine. The electricity produced and not used by the user will be accumulated in two different storage systems: a battery bank and a hydrogen storage system composed of two PEM electrolyzers four pressurized tanks and a PEM fuel cell. One of the main problems to be solved in the development of isolated micro-grids is the management of the various devices and energy flows to optimize their functioning in particular in relation to the load profile and power produced by renewable energy systems depending on weather conditions. For this reason through the development and implementation of a specific simulation program three different energy management systems were studied to evaluate the best strategy for effectively satisfying user requirements and optimizing overall system efficiency.
Gas Goes Green: Hydrogen Blending Capacity Maps
Jan 2022
Publication
Britain's gas networks are ready for hydrogen blending. Learn more about Britain's hydrogen blending capacity in the National Transmission System and Distribution Networks.
A Review of Technical Advances, Barriers, and Solutions in the Power to Hydrogen Roadmap
Oct 2020
Publication
Power to hydrogen (P2H) provides a promising solution to the geographic mismatch between sources of renewable energy and the market due to its technological maturity flexibility and the availability of technical and economic data from a range of active demonstration projects. In this review we aim to provide an overview of the status of P2H analyze its technical barriers and solutions and propose potential opportunities for future research and industrial demonstrations. We specifically focus on the transport of hydrogen via natural gas pipeline networks and end-user purification. Strong evidence shows that an addition of about 10% hydrogen into natural gas pipelines has negligible effects on the pipelines and utilization appliances and may therefore extend the asset value of the pipelines after natural gas is depleted. To obtain pure hydrogen from hydrogen-enriched natural gas (HENG) mixtures end-user separation is inevitable and can be achieved through membranes adsorption and other promising separation technologies. However novel materials with high selectivity and capacity will be the key to the development of industrial processes and an integrated membrane-adsorption process may be considered in order to produce high-purity hydrogen from HENG. It is also worth investigating the feasibility of electrochemical separation (hydrogen pumping) at a large scale and its energy analysis. Cryogenics may only be feasible when liquefied natural gas (LNG) is one of the major products. A range of other technological and operational barriers and opportunities such as water availability byproduct (oxygen) utilization and environmental impacts are also discussed. This review will advance readers’ understanding of P2H and foster the development of the hydrogen economy.
Climate Action: Prospects of Green Hydrogen in Africa
Feb 2022
Publication
Africa is rich with an abundance of renewable energy sources that can help meeting the continent’s demand for electricity to promote economic growth and meet global targets for CO2 reduction. Green Hydrogen is considered one of the most promising technologies for energy generation transportation and storage. In this paper the prospects of green hydrogen production potential in Africa are investigated along with its usage for future implementation. Moreover an overview of the benefits of shifting to green Hydrogen technology is presented. The current African infrastructure and policies are tested against future targets and goals. Furthermore the study embraces a detailed theoretical environmental technological and economic assessment putting the local energy demands into consideration.
Strategic Transport Fleet Analysis of Heavy Goods Vehicle Technology for Net-zero Targets
Jul 2022
Publication
This paper addresses the decarbonisation of the heavy-duty transport sector and develops a strategy towards net-zero greenhouse gas (GHG) emissions in heavy-goods vehicles (HGVs) by 2040. By conducting a literature review and a case study on the vehicle fleet of a large UK food and consumer goods retailer the feasibilities of four alternative vehicle technologies are evaluated from environmental economic and technical perspectives. Socio-political factors and commercial readiness are also examined to capture non-technical criteria that influences decision-makers. Strategic analysis frameworks such as PEST-SWOT models were developed for liquefied natural gas biomethane electricity and hydrogen to allow a holistic comparison and identify their long-term deployment potential. Technology innovation is needed to address range and payload limitations of electric trucks whereas government and industry support are essential for a material deployment of hydrogen in the 2030s. Given the UK government’s plan to phase out new diesel HGVs by 2040 fleet operators should commence new vehicle trials by 2025 and replace a considerable amount of their lighter diesel trucks with zero-emission vehicles by 2030 and the remaining heavier truck fleet by 2035.
Towards a Safe Hydrogen Economy: An Absolute Climate Sustainability Assessment of Hydrogen Production
Jan 2023
Publication
Policymakers and global energy models are increasingly looking towards hydrogen as an enabling energy carrier to decarbonize hard-to-abate sectors (projecting growth in hydrogen consumption in the magnitude of hundreds of megatons). Combining scenarios from global energy models and life cycle impacts of different hydrogen production technologies the results of this work show that the life cycle emissions from proposed configurations of the hydrogen economy would lead to climate overshoot of at least 5.4–8.1x of the defined “safe” space for greenhouse gas emissions by 2050 and the cumulative consumption of 8–12% of the remaining carbon budget. This work suggests a need for a science-based definition of “clean” hydrogen agnostic of technology and compatible with a “safe” development of the hydrogen economy. Such a definition would deem blue hydrogen environmentally unviable by 2025–2035. The prolific use of green hydrogen is also problematic however due to the requirement of a significant amount of renewable energy and the associated embedded energy land and material impacts. These results suggest that demand-side solutions should be further considered as the large-scale transition to hydrogen which represents a “clean” energy shift may still not be sufficient to lead humanity into a “safe” space.
Multi-model Assessment of Heat Decarbonisation Options in the UK Using Electricity and Hydrogen
May 2022
Publication
Delivering low-carbon heat will require the substitution of natural gas with low-carbon alternatives such as electricity and hydrogen. The objective of this paper is to develop a method to soft-link two advanced investment-optimising energy system models RTN (Resource-Technology Network) and WeSIM (Whole-electricity System Investment Model) in order to assess cost-efficient heat decarbonisation pathways for the UK while utilising the respective strengths of the two models. The linking procedure included passing on hourly electricity prices from WeSIM as input to RTN and returning capacities and locations of hydrogen generation and shares of electricity and hydrogen in heat supply from RTN to WeSIM. The outputs demonstrate that soft-linking can improve the quality of the solution while providing useful insights into the cost-efficient pathways for zero-carbon heating. Quantitative results point to the cost-effectiveness of using a mix of electricity and hydrogen technologies for delivering zero-carbon heat also demonstrating a high level of interaction between electricity and hydrogen infrastructure in a zero-carbon system. Hydrogen from gas reforming with carbon capture and storage can play a significant role in the medium term while remaining a cost-efficient option for supplying peak heat demand in the longer term with the bulk of heat demand being supplied by electric heat pumps.
A Thorough Emission-Cost Analysis of the Gradual Replacement of Carbon-Rich Fuels with Carbon-Free Energy Carriers in Modern Power Plants: The Case of Cyprus
Aug 2022
Publication
Global efforts towards de-carbonization give rise to remarkable energy challenges which include renewable energy penetration increase and intermediate energy carriers for a sustainable transition. In order to reduce the dependence on fossil fuels alternative sources are considered by commodities to satisfy their increasing electricity demand as a consequence of a rise in population and the quantity of residential appliances in forthcoming years. The near-term trends appear to be in fuel and emission reduction techniques through the integration of carbon capture and storage and more efficient energy carriers exploiting alternative energy sources such as natural gas and hydrogen. Formulating both the fuel consumption and emission released the obtained experimental results showed that the total production cost can be reduced by making use of natural gas for the transition towards 2035’s targets. Maximum profits will be achieved with hydrogen as the only fuel in modern power plants by 2050. In this way the lowest electricity production can be achieved as well as the elimination of carbon dioxide emissions. Since the integration of renewable energy resources in the sectors of electricity heating/cooling and transportation will continuously be increased alternative feedstocks can serve as primary inputs and contribute to production cost profits improved utilization factors and further environmental achievements.
Hydrogenerally - Episode 7: Hydrogen for Heat
Dec 2022
Publication
In this seventh episode Steffan Eldred Hydrogen Innovation Network Knowledge Transfer Manager and Jenni McDonnell MBE Heating and Cooling Knowledge Transfer Manager from Innovate UK KTN discuss why using hydrogen to generate heat is so important and explore the hydrogen economy opportunities and challenges within this sector alongside their special guest Jeff House Head of External Affairs Baxi Boilers.
The podcast can be found on their website.
The podcast can be found on their website.
Hydrogen Technology Development and Policy Status by Value Chain in South Korea
Nov 2022
Publication
Global transitions from carbon- to hydrogen-based economies are an essential component of curbing greenhouse gas emissions and climate change. This study provides an investigative review of the technological development trends within the overall hydrogen value chain in terms of production storage transportation and application with the aim of identifying patterns in the announcement and execution of hydrogen-based policies both domestically within Korea as well as internationally. The current status of technological trends was analyzed across the three areas of natural hydrogen carbon dioxide capture utilization and storage technology linked to blue hydrogen and green hydrogen production linked to renewable energy (e.g. water electrolysis). In Korea the establishment of underground hydrogen storage facilities is potentially highly advantageous for the storage of domestically produced and imported hydrogen providing the foundations for large-scale application as economic feasibility is the most important national factor for the provision of fuel cells. To realize a hydrogen economy pacing policy and technological development is essential in addition to establishing a roadmap for efficient policy support. In terms of technological development it is important to prioritize that which can connect the value chain all of which will ultimately play a major role in the transformation of human energy consumption.
Introduction of Hydrogen in the Kosovo Transportation Sector
Oct 2022
Publication
Based on the energy strategy of the Republic of Kosovo from 2017–2026 the increase in the integration of renewable energy sources (RES) in the national energy system was aimed at. However the hydrogen potential was not mentioned. In this work a roadmap toward the introduction of hydrogen in the energy system with the main focus on the transportation sector through three phases is proposed. In the first phase (until 2024) the integration of hydrogen in the transportation sector produced via water electrolysis from the grid electricity with the increase of up to a 0.5% share of fuel cell vehicles is intended. In the second phase (2025–2030) the hydrogen integration in the transportation sector is increased by including renewable hydrogen where the share of fuel cell electric vehicles (FCEVs) will be around 4% while in the third phase (2031–2050) around an 8% share of FCEVs in the transportation was planned. The technical and environmental analysis of hydrogen integration is focused on both the impact of hydrogen in the decarbonization of the transportation sector and the energy system. To model the Kosovo energy system the hourly deterministic EnergyPLAN model was used. This research describes the methodology based on EnergyPLAN modeling that can be used for any energy system to provide a clear path of RES and hydrogen implementation needed to achieve a zero-emission goal which was also set by various other countries. The predicted decrease in GHG emissions from 8 Mt in the referent year 2017 amounts to 7 Mt at the end of the first phase 2024 and 4.4 Mt at the end of the second phase 2030 to achieve 0 Mt by 2050. In order to achieve it the required amount of hydrogen by 2030 resulted in 31840 kg/year and by 2050 around 89731 kg/year. The results show the concrete impact of hydrogen on transport system stabilization and its influence on greenhouse gas (GHG) emissions reduction.
Are Sustainable Aviation Fuels a Viable Option for Decarbonizing Air Transport in Europe? An Environmental and Economic Sustainability Assessment
Jan 2022
Publication
The use of drop-in capable alternative fuels in aircraft can support the European aviation sector to achieve its goals for sustainable development. They can be a transitional solution in the short and medium term as their use does not require any structural changes to the aircraft powertrain. However the production of alternative fuels is often energy-intensive and some feedstocks are associated with harmful effects on the environment. In addition alternative fuels are often more expensive to produce than fossil kerosene which can make their use unattractive. Therefore this paper analyzes the environmental and economic impacts of four types of alternative fuels compared to fossil kerosene in a well-to-wake perspective. The fuels investigated are sustainable aviation fuels produced by power-to-liquid and biomass-to-liquid pathways. Life cycle assessment and life cycle costing are used as environmental and economic assessment methods. The results of this well-towake analysis reveal that the use of sustainable aviation fuels can reduce the environmental impacts of aircraft operations. However an electricity mix based on renewable energies is needed to achieve significant reductions. In addition from an economic perspective the use of fossil kerosene ranks best among the alternatives. A scenario analysis confirms this result and shows that the production of sustainable aviation fuels using an electricity mix based solely on renewable energy can lead to significant reductions in environmental impact but economic competitiveness remains problematic.
Thermodynamic and Technical Issues of Hydrogen and Methane-Hydrogen Mixtures Pipeline Transmission
Feb 2019
Publication
The use of hydrogen as a non-emission energy carrier is important for the innovative development of the power-generation industry. Transmission pipelines are the most efficient and economic method of transporting large quantities of hydrogen in a number of variants. A comprehensive hydraulic analysis of hydrogen transmission at a mass flow rate of 0.3 to 3.0 kg/s (volume flow rates from 12000 Nm3/h to 120000 Nm3/h) was performed. The methodology was based on flow simulation in a pipeline for assumed boundary conditions as well as modeling of fluid thermodynamic parameters for pure hydrogen and its mixtures with methane. The assumed outlet pressure was 24 bar (g). The pipeline diameter and required inlet pressure were calculated for these parameters. The change in temperature was analyzed as a function of the pipeline length for a given real heat transfer model; the assumed temperatures were 5 and 25 ◦C. The impact of hydrogen on natural gas transmission is another important issue. The performed analysis revealed that the maximum participation of hydrogen in natural gas should not exceed 15%–20% or it has a negative impact on natural gas quality. In the case of a mixture of 85% methane and 15% hydrogen the required outlet pressure is 10% lower than for pure methane. The obtained results present various possibilities of pipeline transmission of hydrogen at large distances. Moreover the changes in basic thermodynamic parameters have been presented as a function of pipeline length for the adopted assumptions.
Review of the Effects of Fossil Fuels and the Need for a Hydrogen Fuel Cell Policy in Malaysia
Feb 2023
Publication
The world has relied on fossil fuel energy for a long time producing many adverse effects. Long-term fossil fuel dependency has increased carbon emissions and accelerated climate change. In addition fossil fuels are also depleting and will soon be very costly. Moreover the expensive national electricity grid has yet to reach rural areas and will be cut off in inundation areas. As such alternative and carbon-free hydrogen fuel cell energy is highly recommended as it solves these problems. The reviews find that (i) compared to renewable energy such as solar biomass and hydropower a fuel cell does not require expensive transmission through an energy grid and is carbon-free and hence it is a faster agent to decelerate climate change; (ii) fuel cell technologies have reached an optimum level due to the high-efficiency production of energy and they are environmentally friendly; (iii) the absence of a policy on hydrogen fuel cells will hinder investment from private companies as they are not adequately regulated. It is thus recommended that countries embarking on hydrogen fuel cell development have a specific policy in place to allow the government to fund and regulate hydrogen fuel cells in the energy generation mix. This is essential as it provides the basis for alternative energy governance development and management of a country.
Quantifying the Impacts of Heat Decarbonisation Pathways on the Future Electricity and Gas Demand
May 2022
Publication
The decarbonisation of heat supply will play a critical role in meeting the emissions reduction target. There is however great uncertainty associated with the achievable levels of heat decarbonisation and the optimal heat technology mix which can have serious implications for the future electricity and gas demand. This work employs an integrated gas electricity and heat supply model to quantify the impacts of heat decarbonisation pathways on the future electricity and gas demand. A case study in the Great Britain is performed considering two heat decarbonisation scenarios in 2050: one is the predominantly electrified heat supply and the other is the predominantly hydrogen-based heat supply. The electricity demand becomes more volatile in the electrified heat scenario as the peak surges to 107.3 GW compared to 51.1 GW in the 2018 reference scenario while the peak in hydrogen-based heat scenario is 78.4 GW. The peak gas demand declines from 247.6 GW for 2018 to 81.7 GW for electrified heat scenario and to 85.1 GW for hydrogen-based heat scenario confirming that the seasonality associated with heat demand is shifting away from the gas network and towards electricity network. Moreover a sensitivity analysis shows that the future electricity demand is highly sensitive to parameters such as relative heat demand coefficient of performance of air source heat pumps and share of electricity in hydrogen production. Finally the application of a load shifting strategy demonstrates that demand-side flexibility has the potential to maintain the electricity system balance and minimise the generation and network infrastructure requirements arising from heat electrification. While the case study presented in this paper is based on the Great Britain the findings regarding the future electricity and gas demand are relevant for the global energy transition.
Investigation of Emission Characteristics and Lubrication Oil Properties in a Dual Diesel–Hydrogen Internal Combustion Engine
Apr 2022
Publication
Hydrogen is considered one of the main gaseous fuels due to its ability to improve thermal performance in diesel engines. However its influence on the characteristics of lubricating oil is generally ignored. Thus in the present investigation an analysis of the effect on the physical and chemical properties of lubricating oil with mixtures of diesel fuel–hydrogen was carried out and the environmental impacts of this type of mixture were assessed. The development of the research was carried out using a diesel engine under four torque conditions (80 Nm 120 Nm 160 Nm and 200 Nm) and three hydrogen gas flow conditions (0.75 lpm 1.00 lpm and 1.25 lpm). From the results it was possible to demonstrate that the presence of hydrogen caused decreases of 3.50% 6.79% and 4.42% in the emissions of CO HC and smoke opacity respectively. However hydrogen further decreased the viscosity of the lubricating oil by 26%. Additionally hydrogen gas produced increases of 17.7% 29.27% 21.95% and 27.41% in metallic components such as Fe Cu Al and Cr respectively. In general hydrogen favors the contamination and oxidation of lubricating oil which implies a greater wear of the engine components. Due to the significantly negative impact of hydrogen on the lubrication system it should be considered due to its influence on the economic and environmental cost during the engine’s life cycle.
Performance Evaluation of a Hydrogen-fired Combined Cycle with Water Recovery
Mar 2023
Publication
Hydrogen can alleviate the increasing environmental pollution and has good development prospects in power generation due to its high calorific value and low environmental impact. The previously designed hydrogen-fired combined cycle ignored water recycling which led to an inefficient application of hydrogen and the wastage of water. This paper proposes the concept of a hydrogen-fired combined cycle with water recovery to reuse the condensed water as an industrial heat supply. It was applied to an F-class combined cycle power plant. The results demonstrate that the efficiency of hydrogen-fired combined cycles with and without water recovery increased by 1.92% and 1.35% respectively compared to that of the natural-gas-fired combined cycle under full working conditions. In addition an economic comparison of the three cycles was conducted. The levelized cost of energy of the hydrogen-fired combined cycle with water recovery will be 52.22% lower than that of the natural-gas-fired combined cycle in 2050. This comparative study suggested that water recovery supplementation could improve the gas turbine efficiency. The proposed hydrogen-fired combined cycle with water recovery would provide both environmental and economic benefits.
Impacts of Low-Carbon Targets and Hydrogen Production Alternatives on Energy Supply System Transition: An Infrastructure-Based Optimization Approach and a Case Study of China
Jan 2021
Publication
Low-carbon transition pathways oriented from different transition targets would result in a huge variation of energy system deployment and transition costs. Hydrogen is widely considered as an imperative energy carrier to reach carbon neutral targets. However hydrogen production either from non-fossil power or fossil fuels with carbon capture is closely linked with an energy supply system and has great impacts on its structure. Identifying an economically affordable transition pathway is attractive and energy infrastructure is critical due to massive investment and long life-span. In this paper a multi-regional multi-period and infrastructure-based model is proposed to quantify energy supply system transition costs with different low-carbon targets and hydrogen production alternatives and China is taken as a case study. Results show that fulfilling 2-degree and 1.5-degree temperature increase targets would result in 84% and 151% increases in system transition costs 114% and 246% increases in infrastructure investment and 211% and 339% increases in stranded investment compared to fulfilling stated policy targets. Producing hydrogen from coal would be economical when carbon capture and sequestration cost is lower than 437 yuan per tonne and reduce infrastructure investment and stranded coal investment by 16% and 35% respectively than producing hydrogen from renewable power.
Notes on the Development of the Hydrogen Supplement to IGEM/TD13 > 7 bar
Nov 2021
Publication
IGEM/TD/13 Standard applies to the safe design construction inspection testing operation and maintenance of pressure regulating installations (PRIs) in accordance with current knowledge and operational experience.
This Supplement provides additional requirements for new PRIs to be used for the transmission of Hydrogen including Natural Gas/Hydrogen blended mixtures (subsequently referred to as NG/H blends) and for the repurposing of Natural Gas (NG) PRIs for Hydrogen service.
NG/H blends are considered to be equivalent to 100 mol % Hydrogen with respect to limits on design stresses the potential effect on the material properties and damage and defect categories and acceptance levels unless an additional technical evaluation is carried out to qualify the materials.
NG/H blends containing in excess of 10 mol % Hydrogen are considered to be equivalent to 100 mol.% Hydrogen with respect to all other requirements except for hazardous areas.
This Supplement gives additional recommendations for PRIs and installations:
This Supplement provides additional requirements for new PRIs to be used for the transmission of Hydrogen including Natural Gas/Hydrogen blended mixtures (subsequently referred to as NG/H blends) and for the repurposing of Natural Gas (NG) PRIs for Hydrogen service.
NG/H blends are considered to be equivalent to 100 mol % Hydrogen with respect to limits on design stresses the potential effect on the material properties and damage and defect categories and acceptance levels unless an additional technical evaluation is carried out to qualify the materials.
NG/H blends containing in excess of 10 mol % Hydrogen are considered to be equivalent to 100 mol.% Hydrogen with respect to all other requirements except for hazardous areas.
This Supplement gives additional recommendations for PRIs and installations:
- with an upstream maximum operating pressure (MOP) not greater than 100 bar
- with an outlet pressure greater than or equal to 7 bar
- for use with Hydrogen or NG/H blends with a Hydrogen content greater than 10 %
- operating with a temperature range between -20°C and 120°C.
Economic Evaluation of Low-carbon Steelmaking via Coupling of Electrolysis and Direct Reduction
Oct 2021
Publication
The transition from fossil-based primary steel production to a low-emission alternative has gained increasing attention in recent years. Various schemes including Carbon Capture and Utilization (CCU) and Carbon Direct Avoidance (CDA) via hydrogen-based as well as electrochemical routes have been proposed. With multiple technical analyses being available and technical feasibility being proven by first pilot plants pathways towards commercial market entry are of increasing interest. While multiple publications on the economic feasibility of CCU are available data on CDA approaches is scarce. In this work an economic model for the quantification of production cost as well as CO2 emission mitigation cost is presented. The approach is characterized by a seamless integration with a flowsheet-based process model of a direct reduction-based crude steel production plant detailed in a previous work and allows for the investigation of multiple economic aspects. Firstly the gradual transition from the natural gas-based state-of-the-art direct reduction towards a fossil-free hydrogen-based reduction is analyzed. Furthermore a comparison between the more mature technology of low-temperature electrolysis and a potentially more efficient solid oxide electrolysis (SOEL) is given highlighting the potential of SOEL technology. The conducted forecast to 2050 shows that SOEL-based CDA offers lower production cost when technological maturity is reached. Based on the results of the economic assessment possible legislative support mechanisms are studied showing that legislative actions are necessary to allow for market entry as well as for sustainable and economically feasible operation of fossil-free direct reduction plants.
A Comparison of Steam Reforming Concepts in Solid Oxide Fuel Cell Systems
Mar 2020
Publication
Various concepts have been proposed to use hydrocarbon fuels in solid oxide fuel cell (SOFC) systems. A combination of either allothermal or adiabatic pre-reforming and water recirculation (WR) or anode off-gas recirculation (AOGR) is commonly used to convert the fuel into a hydrogen rich mixture before it is electrochemically oxidised in the SOFC. However it is unclear how these reforming concepts affect the electrochemistry and temperature gradients in the SOFC stack. In this study four reforming concepts based on either allothermal or adiabatic pre-reforming and either WR or AOGR are modelled on both stack and system level. The electrochemistry and temperature gradients in the stack are simulated with a one-dimensional SOFC model and the results are used to calculate the corresponding system efficiencies. The highest system efficiencies are obtained with allothermal pre-reforming and WR. Adiabatic pre-reforming and AOGR result in a higher degree of internal reforming which reduces the cell voltage compared to allothermal pre-reforming and WR. Although this lowers the stack efficiency higher degrees of internal reforming reduce the power consumption by the cathode air blower as well leading to higher system efficiencies in some cases. This illustrates that both stack and system operation need to be considered to design an efficient SOFC system and predict potentially deteriorating temperature gradients in the stack.
Solar Power and Energy Storage for Decarbonization of Land Transport in India
Dec 2021
Publication
By considering the weight penalty of batteries on payload and total vehicle weight this paper shows that almost all forms of land-based transport may be served by battery electric vehicles (BEV) with acceptable cost and driving range. Only long-distance road freight is unsuitable for battery electrification. The paper models the future Indian electricity grid supplied entirely by low-carbon forms of generation to quantify the additional solar PV power required to supply energy for transport. Hydrogen produced by water electrolysis for use as a fuel for road freight provides an inter-seasonal energy store that accommodates variations in renewable energy supply. The advantages and disadvantages are considered of midday electric vehicle charging vs. overnight charging considering the temporal variations in supply of renewable energy and demand for transport services. There appears to be little to choose between these two options in terms of total system costs. The result is an energy scenario for decarbonized surface transport in India based on renewable energy that is possible realistically achievable and affordable in a time frame of year 2050.
Everything About Hydrogen Podcast: Financing the Hydrogen Revolution
Aug 2020
Publication
On this week's episode of Everything About Hydrogen the team are catching up with Astrid Behaghel the Energy Transition expert on hydrogen for BNP Paribas. On the show the team discuss how BNP Paribas see the emerging role of hydrogen in the energy transition how the financing of hydrogen projects differs for newer hydrogen initiatives and why BNP Paribas joined the Hydrogen Council. We also dive into the question of what role can (or even should) Banks play in the evolution and development of the emerging hydrogen market and BNPs plans to expand its activities in this sector. All this and more!
The podcast can be found on their website
The podcast can be found on their website
Advanced Catalysts for the Water Gas Shift Reaction
Apr 2022
Publication
The WGS reaction is an exothermic reaction between carbon monoxide and steam to form carbon dioxide and hydrogen. This reaction which has been used industrially for more than 100 years has recently received a great deal of attention from researchers as one of the ways to produce environmentally acceptable hydrogen from fossil fuels in large quantities. For the application of this reaction on an industrial scale the key is choosing the optimal catalysts that can ensure high CO conversion and have a long lifetime under industrial conditions. Therefore new types of catalysts are being developed that meet these requirements better than the Fe- and Cu-based catalysts commonly used in the past. The WGSR on a commercial nickel-based catalyst and a laboratory-prepared copper and cobalt-based catalyst was tested in a laboratory apparatus set up at the University of Chemistry and Technology Prague. The best performance of the laboratory-prepared catalyst was observed for the catalyst with a Cu content of 14.8 wt% and activated in a hydrogen atmosphere. The laboratory-prepared Co-based catalyst showed good WGSR activity in the temperature range of 200–450 ◦C although this was always inferior to that of the Cu-based catalyst. When subjected to the feed gas containing 0.4 mole% H2S the Co-based catalyst showed good resistance to sulphur poisoning. Therefore Co-based catalysts can be considered good sulphur-tolerant intermediate temperature WGSR catalysts.
Hydrogen Emissions from a Hydrogen Economy and their Potential Global Warming Impact
Aug 2022
Publication
Hydrogen (H2) is expected to be a key instrument to meet the European Union (EU) Green Deal main objective: i.e. climate neutrality by 2050. Renewable hydrogen deployment is expected to significantly reduce EU greenhouse gas (GHG) emissions by displacing carbon-intensive sources of energy. However concerns have been raised recently regarding the potential global warming impact caused by hydrogen emissions. Although hydrogen is neither intentionally emitted to the atmosphere when used nor a direct greenhouse gas hydrogen losses affect atmospheric chemistry indirectly contributing to global warming. To better understand the potential environmental impact of a hydrogen economy and to assess the need for action in this respect the Clean Hydrogen Joint Undertaking and the U.S. Department of Energy jointly organised with the support of the European Commission Hydrogen Europe Hydrogen Europe Research the Hydrogen Council and the International Partnership for Hydrogen and Fuel Cells in the Economy a 2-day expert workshop. Experts agreed that a low-carbon and in particular a renewable hydrogen economy would significantly reduce the global warming impact compared to a fossil fuel economy. However hydrogen losses to the atmosphere will impact the lifetime of other greenhouse gases namely methane ozone and water vapour indirectly contributing to the increase of the Earth’s temperature in the near-term. To minimise the climate impact of a hydrogen economy losses should therefore be minimised prevented and monitored. Unfortunately current loss rates along the hydrogen supply chain are not well constrained and are currently estimated to go from few percents for compressed hydrogen (1-4%) up to 10-20% for liquefied hydrogen. Both the global warming impact of hydrogen emissions and the leakage rates from a developed hydrogen economy are subject to a high level of uncertainty. It is therefore of paramount importance to invest in developing the ability to accurately quantify hydrogen emissions as well as engage in more research on hydrogen leakage prevention and monitoring systems. More data from the hydrogen industry and improved observational capacity are needed to improve the accuracy of the global hydrogen budget. Finally it is recommended to always report the amount and location of hydrogen emissions when environmental assessments are performed. There is a range of emission metrics and time scales that are designed to evaluate the climate impacts of short-lived GHG emissions compared to CO2 (i.e. CO2 equivalents). The metric choice must depend on the specific policy goal as they can provide very different perspectives on the relative importance of H2 emissions on the climate depending on the time horizon of concern. These differences need to be viewed in the context of the specific policy objectives.
Potential Global Warming Impact of 1 kW Polymer Electrolyte Membrane Fuel Cell System for Residential Buildings on Operation Phase
Mar 2023
Publication
This study established global warming potential(GWP) emission factors through a life cycle assessment on the operation phases of two different 1 kW polymer electrolyte membrane fuel cell (PEMFC) systems for residential buildings (NG-PEMFC fed with hydrogen from natural gas reforming; WE-PEMFC fed with hydrogen from photovoltaics-powered water electrolyzer). Their effectiveness was also compared with conventional power grid systems in Korea specifically in the area of greenhouse gas emissions. The operation phases of the NG-PEMFC and the WE-PEMFC were divided into burner reformer and stack and into water electrolysis and stack respectively. The functional unit of each fuel cell system was defined as 1 kWh of electricity production. In the case of NG-PEMFC the GWP was 3.72E-01 kg-CO2eq/kWh the embodied carbon emissions due to using city gas during the life cycle process was about 20.87 % the carbon emission ratio according to the reformer's combustion burner was 6.07 % and the direct carbon emission ratio of the air emissions from the reformer was 73.06 % indicating that the carbon emission from the reformer contributed over 80 % of the total GWP. As for the WE-PEMFC the GWP was 1.76E-01 kg-CO2eq/kWh and the embodied carbon emissions from photovoltaic power generation during the life cycle process contributed over 99 % of the total GWP.
Next for Net Zero Podcast: Unlock & Understand, Achieving a More Sustainable Future
Sep 2022
Publication
This episode examines how we are tackling a sustainable future – with Net Zero hurtling towards us at great pace. We’re around a year on from the pledges made at COP26 the UK’s Green Recovery initiative is well under way and by next year Britain is aiming to blend up to 20 per cent hydrogen into its gas networks. So now is the time to continue to unlock new insight and understand further the realities of both the challenges and opportunities ahead.
The podcast can be found here.
The podcast can be found here.
Assessment of Hydrogen Delivery Options: Feasibility of Transport of Green Hydrogen within Europe
Oct 2022
Publication
The RePowerEU plan [1] and the European Hydrogen Strategy [2] recognise the important role that the transport of hydrogen will play in enabling the penetration of renewable hydrogen in Europe. To implement the European Hydrogen Strategy it is important to understand whether the transport of hydrogen is cost effective or whether hydrogen should be produced where it is used. If transporting hydrogen makes sense a second open question is how long the transport route should be for the cost of the hydrogen to still be competitive with locally produced hydrogen. JRC has performed a comprehensive study regarding the transport of hydrogen. To investigate which renewable hydrogen delivery pathways are favourable in terms of energy demand and costs JRC has developed a database and an analytical tool to assess each step of the pathways and used it to assess two case studies. The study reveals that there is no single optimal hydrogen delivery solution across every transport scenario. The most cost effective way to deliver renewable hydrogen depends on distance amount final use and whether there is infrastructure already available. For distances compatible with the European territory compressed and liquefied hydrogen solutions and especially compressed hydrogen pipelines offer lower costs than chemical carriers do. The repurposing of existing natural gas pipelines for hydrogen use is expected to significantly lower the delivery cost making the pipeline option even more competitive in the future. By contrast chemical carriers become more competitive the longer the delivery distance (due to their lower transport costs) and open up import options from suppliers located for example in Chile or Australia.
Environmental and Socio-Economic Analysis of Naphtha Reforming Hydrogen Energy Using Input-Output Tables: A Case Study from Japan
Aug 2017
Publication
Comprehensive risk assessment across multiple fields is required to assess the potential utility of hydrogen energy technology. In this research we analyzed environmental and socio-economic effects during the entire life cycle of a hydrogen energy system using input-output tables. The target system included hydrogen production by naphtha reforming transportation to hydrogen stations and FCV (Fuel Cell Vehicle) refilling. The results indicated that 31% 44% and 9% of the production employment and greenhouse gas (GHG) emission effects respectively during the manufacturing and construction stages were temporary. During the continuous operation and maintenance stages these values were found to be 69% 56% and 91% respectively. The effect of naphtha reforming was dominant in GHG emissions and the effect of electrical power input on the entire system was significant. Production and employment had notable effects in both the direct and indirect sectors including manufacturing (pumps compressors and chemical machinery) and services (equipment maintenance and trade). This study used data to introduce a life cycle perspective to environmental and socio-economic analysis of hydrogen energy systems and the results will contribute to their comprehensive risk assessment in the future.
Economic Analysis of a Zero-carbon Liquefied Hydrogen Tanker Ship
Jun 2022
Publication
The green hydrogen economy is considered one of the sustainable solutions to mitigate climate change. This study provides an economic analysis of a novel liquified hydrogen (LH2) tanker fuelled by hydrogen with a total capacity of ~280000 m3 of liquified hydrogen named ‘JAMILA’. An established economic method was applied to investigate the economic feasibility of the JAMILA ship as a contribution to the future zero-emission target. The systematic economic evaluation determined the net present value of the LH2 tanker internal rate of return payback period and economic value added to support and encourage shipyards and the industrial sector in general. The results indicate that the implementation of the LH2 tanker ship can cover the capital cost of the ship within no more than 2.5 years which represents 8.3% of the assumed 30-year operational life cycle of the project in the best maritime shipping prices conditions and 6 years in the worst-case shipping marine economic conditions. Therefore the assessment of the economic results shows that the LH2 tankers may be a worthwhile contribution to the green hydrogen economy.
The State-of-the-Art Progress on the Forms and Modes of Hydrogen and Ammonia Energy Utilization in Road Transportation
Sep 2022
Publication
The crisscross progress of transportation and energy carries the migrating track of human society development and the evolution of civilization among which the decarbonization strategy is a key issue. Traffic carbon emissions account for 16.2% of total energy carbon emissions while road traffic carbon emissions account for 11.8% of total energy carbon emissions. Therefore road traffic is a vital battlefield in attaining the goal of decarbonization. Employing clean energy as an alternative fuel is of great significance to the transformation of the energy consumption structure in road transportation. Hydrogen and ammonia are renewable energy with the characteristics of being widely distributed and clean. Both exist naturally in nature and the products of complete combustion are substances (water and nitrogen) that do not pollute the atmosphere. Because it can promote agricultural production ammonia has a long history in human society. Both have the potential to replace traditional fossil fuel energy. An overview of the advantages of hydrogen and ammonia as well as their development in different countries such as the United States the European Union Japan and other major development regions is presented in this paper. Related research topics of hydrogen and ammonia’s production storage and transferring technology have also been analyzed and collated to stimulate the energy production chain for road transportation. The current cost of green hydrogen is between $2.70–$8.80 globally which is expected to approach $2–$6 by 2030. Furthermore the technical development of hydrogen and ammonia as a fuel for engines and fuel cells in road transportation is compared in detail and the tests practical applications and commercial popularization of these technologies are summarized respectively. Opportunities and challenges coexist in the era of the renewable energy. Based on the characteristics and development track of hydrogen and ammonia the joint development of these two types of energy is meant to be imperative. The collaborative development mode of hydrogen and ammonia together with the obstacles to their development of them are both compared and discussed. Finally referring to the efforts and experiences of different countries in promoting hydrogen and ammonia in road transportation corresponding constructive suggestions have been put forward for reference. At the end of the paper a framework diagram of hydrogen and ammonia industry chains is provided and the mutual promotion development relationship of the two energy sources is systematically summarized.
Electrocatalytic Properties for the Hydrogen Evolution of the Electrodeposited Ni–Mo/WC Composites
May 2021
Publication
The catalytical activity for the hydrogen evolution reaction (HER) of the electrodeposited Ni–Mo/WC composites is examined in 1 M KOH solution. The structure surface morphology and surface composition is investigated using the scanning electron microscopy X-ray diffraction and X-ray photoelectron spectroscopy. The electrocatalytic properties for the HER is evaluated based on the cathodic polarization electrochemical impedance cyclic voltammetry and chronopotentiometry methods. The obtained results prove the superior catalytic activity for the HER of Ni–Mo/WC composites to Ni–Mo alloy. The catalytic activity of Ni–Mo/WC electrodes is determined by the presence of WC nanoparticles and Mo content in the metallic matrix. The best electrocatalytic properties are identified for Ni–Mo/WC composite with the highest Mo content and the most oxidized surface among the studied coatings. The impedance results reveal that the observed improvement in the catalytic activity is the consequence of high real surface area and high intrinsic catalytic activity of the composite.
From Renewable Energy to Sustainable Protein Sources: Advancement, Challenges, and Future Roadmaps
Jan 2022
Publication
The concerns over food security and protein scarcity driven by population increase and higher standards of living have pushed scientists toward finding new protein sources. A considerable proportion of resources and agricultural lands are currently dedicated to proteinaceous feed production to raise livestock and poultry for human consumption. The 1st generation of microbial protein (MP) came into the market as land-independent proteinaceous feed for livestock and aquaculture. However MP may be a less sustainable alternative to conventional feeds such as soybean meal and fishmeal because this technology currently requires natural gas and synthetic chemicals. These challenges have directed researchers toward the production of 2nd generation MP by integrating renewable energies anaerobic digestion nutrient recovery biogas cleaning and upgrading carbon-capture technologies and fermentation. The fermentation of methane-oxidizing bacteria (MOB) and hydrogen-oxidizing bacteria (HOB) i.e. two protein rich microorganisms has shown a great potential on the one hand to upcycle effluents from anaerobic digestion into protein rich biomass and on the other hand to be coupled to renewable energy systems under the concept of Power-to-X. This work compares various production routes for 2nd generation MP by reviewing the latest studies conducted in this context and introducing the state-of-the-art technologies hoping that the findings can accelerate and facilitate upscaling of MP production. The results show that 2nd generation MP depends on the expansion of renewable energies. In countries with high penetration of renewable electricity such as Nordic countries off-peak surplus electricity can be used within MP-industry by supplying electrolytic H2 which is the driving factor for both MOB and HOB-based MP production. However nutrient recovery technologies are the heart of the 2nd generation MP industry as they determine the process costs and quality of the final product. Although huge attempts have been made to date in this context some bottlenecks such as immature nutrient recovery technologies less efficient fermenters with insufficient gas-to-liquid transfer and costly electrolytic hydrogen production and storage have hindered the scale up of MP production. Furthermore further research into techno-economic feasibility and life cycle assessment (LCA) of coupled technologies is still needed to identify key points for improvement and thereby secure a sustainable production system.
Super Short Term Combined Power Prediction for Wind Power Hydrogen Production
Sep 2022
Publication
A combined ultra-short-term wind power prediction strategy with high robustness based on least squares support vector machine (LSSVM) has been proposed in order to solve the wind abandonment caused by wind power randomness and realize efficient hydrogen production under wide power fluctuation. Firstly the original wind power data is decomposed into sub-modes with different bandwidth by variational modal decomposition (VMD) which reduces the influence of random noise and mode mixing significantly. Then dragonfly algorithm (DA) is introduced to optimize LSSVM kernel function and the combined ultra-short-term wind power prediction strategy which meets the time resolution and accuracy requirements of electrolytic cell control has been established finally. This model is validated by a wind power hydrogen production demonstration project output in the middle east of China. The superior prediction accuracy for high volatility wind power data is verified and the algorithm provides theoretical basis to improve the control of wind power hydrogen production system
Powertrain Design and Energy Management Strategy Optimization for a Fuel Cell Electric Intercity Coach in an Extremely Cold Mountain Area
Sep 2022
Publication
Facing the challenge that the single-motor electric drive powertrain cannot meet the continuous uphill requirements in the cold mountainous area of the 2022 Beijing Winter Olympics the manuscript adopted a dual-motor coupling technology. Then according to the operating characteristics and performance indicators of the fuel cell (FC)–traction battery hybrid power system the structure design and parameter matching of the vehicle power system architecture were carried out to improve the vehicle’s dynamic performance. Furthermore considering the extremely cold conditions in the Winter Olympics competition area and the poor low-temperature tolerance of core components of fuel cell electric vehicles (FCEV) under extremely cold conditions such as the reduced capacity and service life of traction batteries caused by the rapid deterioration of charging and discharging characteristics the manuscript proposed a fuzzy logic control-based energy management strategy (EMS) optimization method for the proton exchange membrane fuel cell (PEMFC) to reduce the power fluctuation hydrogen consumption and battery charging/discharging times and at the same time to ensure the hybrid power system meets the varying demand under different conditions. In addition the performance of the proposed approach was investigated and validated in an intercity coach in real-world driving conditions. The experimental results show that the proposed powertrain with an optimal control strategy successfully alleviated the fluctuation of vehicle power demand reduced the battery charging/discharging times of traction battery and improved the energy efficiency by 20.7%. The research results of this manuscript are of great significance for the future promotion and application of fuel cell electric coaches in all climate environments especially in an extremely cold mountain area.
Pressure Management in Smart Gas Networks for Increasing Hydrogen Blending
Jan 2022
Publication
The injection of hydrogen into existing gas grids is acknowledged as a promising option for decarbonizing gas systems and enhancing the integration among energy sectors. Nevertheless it affects the hydraulics and the quality management of networks. When the network is fed by multiple infeed sites and hydrogen is fed from a single injection point non-homogeneous hydrogen distribution throughout the grid happens to lead to a reduction of the possible amount of hydrogen to be safely injected within the grid. To mitigate these impacts novel operational schemes should therefore be implemented. In the present work the modulation of the outlet pressures of gas infeed sites is proposed as an effective strategy to accommodate larger hydrogen volumes into gas grids extending the area of the network reached by hydrogen while keeping compliance with quality and hydraulic restrictions. A distribution network operated at two cascading pressure tiers interfaced by pressure regulators constitutes the case study which is simulated by a fluid-dynamic and multi-component model for gas networks. Results suggest that higher shares of hydrogen and other green gases can be introduced into existing distribution systems by implementing novel asset management schemes with negligible impact on grid operations.
Hydrogen Supply Chain Scenarios for the Decarbonisation of a German Multi-modal Energy System
Sep 2021
Publication
Analysing hydrogen supply chains is of utmost importance to adequately understand future energy systems with a high degree of sector coupling. Here a multi-modal energy system model is set up as linear programme incorporating electricity natural gas as well as hydrogen transportation options for Germany in 2050. Further different hydrogen import routes and optimised inland electrolysis are included. In a sensitivity analysis hydrogen demands are varied to cover uncertainties and to provide scenarios for future requirements of a hydrogen supply and transportation infrastructure. 80% of the overall hydrogen demand of 150 TWh/a emerge in Northern Germany due to optimised electrolyser locations and imports which subsequently need to be transported southwards. Therefore a central hydrogen pipeline connection from Schleswig-Holstein to the region of Darmstadt evolves already for moderate demands and appears to be a no-regret investment. Furthermore a natural gas pipeline reassignment potential of 46% is identified.
Graphitic Carbon Nitride Heterojunction Photocatalysts for Solar Hydrogen Production
Sep 2021
Publication
Photocatalytic hydrogen production is considered as an ideal approach to solve global energy crisis and environmental pollution. Graphitic carbon nitride (g-C3N4) has received extensive consideration due to its facile synthesis stable physicochemical properties and easy functionalization. However the pristine g-C3N4 usually shows unsatisfactory photocatalytic activity due to the limited separation efficiency of photogenerated charge carriers. Generally introducing semiconductors or co-catalysts to construct g–C3N4–based heterojunction photocatalysts is recognized as an effective method to solve this bottleneck. In this review the advantages and characteristics of various types of g–C3N4–based heterojunction are analyzed. Subsequently the recent progress of highly efficient g–C3N4–based heterojunction photocatalysts in the field of photocatalytic water splitting is emphatically introduced. Finally a vision of future perspectives and challenges of g–C3N4–based heterojunction photocatalysts in hydrogen production are presented. Predictably this timely review will provide valuable reference for the design of efficient heterojunctions towards photocatalytic water splitting and other photoredox reactions.
Solar Hydrogen Production via a Samarium Oxide-Based Thermochemical Water Splitting Cycle
Apr 2016
Publication
The computational thermodynamic analysis of a samarium oxide-based two-step solar thermochemical water splitting cycle is reported. The analysis is performed using HSC chemistry software and databases. The first (solar-based) step drives the thermal reduction of Sm2O3 into Sm and O2. The second (non-solar) step corresponds to the production of H2 via a water splitting reaction and the oxidation of Sm to Sm2O3. The equilibrium thermodynamic compositions related to the thermal reduction and water splitting steps are determined. The effect of oxygen partial pressure in the inert flushing gas on the thermal reduction temperature (TH) is examined. An analysis based on the second law of thermodynamics is performed to determine the cycle efficiency (ηcycle) and solar-to-fuel energy conversion efficiency (ηsolar´to´fuel) attainable with and without heat recuperation. The results indicate that ηcycle and ηsolar´to´fuel both increase with decreasing TH due to the reduction in oxygen partial pressure in the inert flushing gas. Furthermore the recuperation of heat for the operation of the cycle significantly improves the solar reactor efficiency. For instance in the case where TH = 2280 K ηcycle = 24.4% and ηsolar´to´fuel = 29.5% (without heat recuperation) while ηcycle = 31.3% and ηsolar´to´fuel = 37.8% (with 40% heat recuperation).
Aluminium Redox Cycle in Comparison to Pressurized Hydrogen for the Energy Supply of Multi-family Houses
Nov 2022
Publication
Power-to-X technologies that convert renewable electricity to chemically stored energy in “X” may provide a gaseous liquid or solid fuel that can be used in winter to provide both heat and electricity and thus replace fossil fuels that are currently used in many countries with cold winters. This contribution compares two options for power-to-X technologies for providing heat and electricity supply of buildings with high solar photovoltaic coverage at times of low solar availability. The option “compressed hydrogen” is based on water electrolysis that produces hydrogen on-site. This hydrogen is subsequently compressed and stored at high pressure (350 bar) for use in winter by a fuel cell. The option “aluminium redox-cycle” includes an inert electrode high temperature electrolysis process that is carried out at industrial scale. Produced aluminium is subseqeuntly transported to the site of use and converted to hydrogen and heat – and finally to electricity and heat - by aluminium-water reaction in combination with a fuel cell. Results of cost and LCA analysis show that the overall energetic efficiency of the compressed hydrogen process is slightly higher than for the aluminium redox cycle. However the aluminium redox-cycles needs far less on-site storage volume and is likely to become available at lower investment cost for the end user. Total annual cost of ownership and global warming potential of the two options are quite similar.
A Geospatial Method for Estimating the Levelised Cost of Hydrogen Production from Offshore Wind
Jan 2023
Publication
This paper describes the development of a general-purpose geospatial model for assessing the economic viability of hydrogen production from offshore wind power. A key feature of the model is that it uses the offshore project's location characteristics (distance to port water depth distance to gas grid injection point). Learning rates are used to predict the cost of the wind farm's components and electrolyser stack replacement. The notional wind farm used in the paper has a capacity of 510 MW. The model is implemented in a geographic information system which is used to create maps of levelised cost of hydrogen from offshore wind in Irish waters. LCOH values in 2030 spatially vary by over 50% depending on location. The geographically distributed LCOH results are summarised in a multivariate production function which is a simple and rapid tool for generating preliminary LCOH estimates based on simple site input variables.
Numerical Simulation on Heating Effects during Hydrogen Absorption in Metal Hydride Systems for Hydrogen Storage
Apr 2022
Publication
A 2-D numerical simulation model was established based on a small-sized metal hydride storage tank and the model was validated by the existing experiments. An external cooling bath was equipped to simulate the heating effects of hydrogen absorption reactions. Furthermore both the type and the flow rate of the cooling fluids in the cooling bath were altered so that changes in temperature and hydrogen storage capacity in the hydrogen storage model could be analyzed. It is demonstrated that the reaction rate in the center of the hydrogen storage tank gradually becomes lower than that at the wall surface. When the flow rate of the fluid is small significant differences can be found in the cooling liquid temperature at the inlet and the outlet cooling bath. In areas adjacent to its inlet the reaction rate is higher than that at the outlet and a better cooling effect is produced by water. As the flow rate increases the total time consumed by hydrogen adsorption reaction is gradually reduced to a constant value. At the same flow rate the wall surface of the tank shows a reaction rate insignificantly different from that in its center provided that cooling water or oil coolant is replaced with air.
Green Hydrogen Production and Use in Low- and Middle-income Countries: A Least-cost Geospatial Modelling Approach Applied to Kenya
May 2023
Publication
With the rising threat of climate change green hydrogen is increasingly seen as the high-capacity energy storage and transport medium of the future. This creates an opportunity for low- and middle-income countries to leverage their high renewable energy potential to produce use and export low-cost green hydrogen creating environmental and economic development benefits. While identifying ideal locations for green hydrogen production is critical for countries when defining their green hydrogen strategies there has been a paucity of adequate geospatial planning approaches suitable to low- and middle-income countries. It is essential for these countries to identify green hydrogen production sites which match demand to expected use cases such that their strategies are economically sustainable. This paper therefore develops a novel geospatial cost modelling method to optimize the location of green hydrogen production across different use cases with a focus on suitability to low- and middle-income countries. This method is applied in Kenya to investigate the potential hydrogen supply chain for three use cases: ammonia-based fertilizer freight transport and export. We find hydrogen production costs of e3.7–9.9/kgH2 are currently achievable across Kenya depending on the production location chosen. The cheapest production locations are identified to the south and south-east of Lake Turkana. We show that ammonia produced in Kenya can be cost-competitive given the current energy crisis and that Kenya could export hydrogen to Rotterdam with costs of e7/kgH2 undercutting current market prices regardless of the carrier medium. With expected techno-economic improvements hydrogen production costs across Kenya could drop to e1.8–3.0/kgH2 by 2030.
Charting a Course for Decarbonizing Maritime Transport
Apr 2021
Publication
As the backbone of global trade international maritime transport connects the world and facilitates economic growth and development especially in developing countries. However producing around three percent of global greenhouse gas (GHG) emissions and emitting around 15 percent of some of the world’s major air pollutants shipping is a major contributor to climate change and air pollution. To mitigate its negative environmental impact shipping needs to abandon fossil-based bunker fuels and turn to zero-carbon alternatives. This report the “Summary for Policymakers and Industry” summarizes recent World Bank research on decarbonizing the maritime sector. The analysis identifies green ammonia and hydrogen as the most promising zero-carbon bunker fuels within the maritime industry at present. These fuels strike the most advantageous balance of favorable features relating to their lifecycle GHG emissions broader environmental factors scalability economics and technical and safety implications. The analysis also identifies that LNG will likely only play a limited role in shipping’s energy transition due to concerns over methane slip and stranded assets. Crucially the research reveals that decarbonizing maritime transport offers unique business and development opportunities for developing countries. Developing countries with large renewable energy resources could take advantage of the new and emerging future zero-carbon bunker fuel market estimated at over $1 trillion to establish new export markets while also modernizing their own domestic energy and industrial infrastructure. However strategic policy interventions are needed to hasten the sector’s energy transition.
Review on the Status of the Research on Power‐to‐Gas Experimental Activities
Aug 2022
Publication
In recent years power‐to‐gas technologies have been gaining ground and are increasingly proving their reliability. The possibility of implementing long‐term energy storage and that of being able to capture and utilize carbon dioxide are currently too important to be ignored. However sys‐ tems of this type are not yet experiencing extensive realization in practice. In this study an overview of the experimental research projects and the research and development activities that are currently part of the power‐to‐gas research line is presented. By means of a bibliographical and sitographical analysis it was possible to identify the characteristics of these projects and their distinctive points. In addition the main research targets distinguishing these projects are presented. This provides an insight into the research direction in this regard where a certain technological maturity has been achieved and where there is still work to be done. The projects found and analyzed amount to 87 mostly at laboratory scale. From these what is most noticeable is that research is currently focusing heavily on improving system efficiency and integration between components.
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